Information card for entry 7700757

Structure parameters

• Common name: [Tl(N3Dmp2)]
• Formula: C51.5 H54 N3 Tl
• Calculated formula: C51.5 H54 N3 Tl
• Title of publication: Kinetic stabilization of low-oxidation state and terminal hydrido main group metal complexes by a sterically demanding N,N'-bis(2,6-terphenyl)triazenide.
• Authors of publication: Leverett, Anthony R.; Diachenko, Vera; Cole, Marcus L.; McKay, Alasdair I.
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2019
• Journal volume: 48
• Journal issue: 35
• Pages of publication: 13197 - 13204
• a: 10.558 ± 0.002 Å
• b: 11.47 ± 0.002 Å
• c: 20.162 ± 0.003 Å
• α: 102.694 ± 0.007°
• β: 95.73 ± 0.007°
• γ: 110.677 ± 0.008°
• Cell volume: 2186 ± 0.7 ų
• Cell temperature: 183 ± 2 K
• Ambient diffraction temperature: 183.01 K
• Number of distinct elements: 4
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0559
• Residual factor for significantly intense reflections: 0.0351
• Weighted residual factors for significantly intense reflections: 0.0938
• Weighted residual factors for all reflections included in the refinement: 0.1022
• Goodness-of-fit parameter for all reflections included in the refinement: 1.025
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No