Information card for entry 7701078

Structure parameters

• Formula: C44 H52 Cu2 Gd2 N6 O22
• Calculated formula: C44 H52 Cu2 Gd2 N6 O22
• Title of publication: The role of 3d-4f exchange interaction in SMM behaviour and magnetic refrigeration of carbonato bridged CuLn (Ln = Dy, Tb and Gd) complexes of an unsymmetrical N₂O₄ donor ligand.
• Authors of publication: Maity, Souvik; Mondal, Arpan; Konar, Sanjit; Ghosh, Ashutosh
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2019
• Journal volume: 48
• Journal issue: 40
• Pages of publication: 15170 - 15183
• a: 14.1519 ± 0.0007 Å
• b: 12.4217 ± 0.0006 Å
• c: 14.2822 ± 0.0007 Å
• α: 90°
• β: 92.931 ± 0.001°
• γ: 90°
• Cell volume: 2507.4 ± 0.2 ų
• Cell temperature: 296 ± 2 K
• Ambient diffraction temperature: 296.15 K
• Number of distinct elements: 6
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for all reflections: 0.0642
• Residual factor for significantly intense reflections: 0.0449
• Weighted residual factors for significantly intense reflections: 0.0963
• Weighted residual factors for all reflections included in the refinement: 0.1182
• Goodness-of-fit parameter for all reflections included in the refinement: 1.153
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No