Information card for entry 7702936

Structure parameters

• Formula: C13 H21 Cl2 O P Ru
• Calculated formula: C13 H21 Cl2 O P Ru
• Title of publication: Half-sandwich ruthenium(ii) complexes with tethered arene-phosphinite ligands: synthesis, structure and application in catalytic cross dehydrogenative coupling reactions of silanes and alcohols.
• Authors of publication: González-Fernández, Rebeca; Crochet, Pascale; Cadierno, Victorio
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2020
• Journal volume: 49
• Journal issue: 1
• Pages of publication: 210 - 222
• a: 7.2966 ± 0.0003 Å
• b: 7.6884 ± 0.0003 Å
• c: 15.4349 ± 0.0006 Å
• α: 85.087 ± 0.003°
• β: 81.257 ± 0.004°
• γ: 62.338 ± 0.004°
• Cell volume: 757.89 ± 0.06 ų
• Cell temperature: 150 ± 2 K
• Ambient diffraction temperature: 150 ± 2 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0517
• Residual factor for significantly intense reflections: 0.0504
• Weighted residual factors for significantly intense reflections: 0.1375
• Weighted residual factors for all reflections included in the refinement: 0.1403
• Goodness-of-fit parameter for all reflections included in the refinement: 1.064
• Diffraction radiation wavelength: 1.54184 Å
• Diffraction radiation type: CuKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No