Information card for entry 7703836

Structure parameters

• Formula: C16 H20 S2 Si
• Calculated formula: C16 H20 S2 Si
• Title of publication: Si-C(sp³) bond activation through oxidative addition at a Rh(i) centre.
• Authors of publication: Azpeitia, S.; Martínez-Martínez, A J; Garralda, M. A.; Weller, A. S.; Huertos, M. A.
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2020
• Journal volume: 49
• Journal issue: 17
• Pages of publication: 5416 - 5419
• a: 8.5576 ± 0.0001 Å
• b: 14.0902 ± 0.0001 Å
• c: 13.4262 ± 0.0001 Å
• α: 90°
• β: 99.307 ± 0.001°
• γ: 90°
• Cell volume: 1597.6 ± 0.03 ų
• Cell temperature: 150 ± 0.1 K
• Ambient diffraction temperature: 150 ± 2 K
• Number of distinct elements: 4
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for all reflections: 0.0257
• Residual factor for significantly intense reflections: 0.0243
• Weighted residual factors for significantly intense reflections: 0.0625
• Weighted residual factors for all reflections included in the refinement: 0.0636
• Goodness-of-fit parameter for all reflections included in the refinement: 1.044
• Diffraction radiation wavelength: 1.54184 Å
• Diffraction radiation type: CuKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No