Information card for entry 7703837

Structure parameters

• Formula: C57 H44 B Cl4 F24 Rh S2 Si
• Calculated formula: C57 H44 B Cl4 F24 Rh S2 Si
• Title of publication: Si-C(sp³) bond activation through oxidative addition at a Rh(i) centre.
• Authors of publication: Azpeitia, S.; Martínez-Martínez, A J; Garralda, M. A.; Weller, A. S.; Huertos, M. A.
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2020
• Journal volume: 49
• Journal issue: 17
• Pages of publication: 5416 - 5419
• a: 26.2033 ± 0.0002 Å
• b: 12.75 ± 0.0001 Å
• c: 38.5848 ± 0.0003 Å
• α: 90°
• β: 105.003 ± 0.001°
• γ: 90°
• Cell volume: 12451.5 ± 0.18 ų
• Cell temperature: 150.01 ± 0.14 K
• Ambient diffraction temperature: 150.01 ± 0.14 K
• Number of distinct elements: 8
• Space group number: 15
• Hermann-Mauguin space group symbol: I 1 2/a 1
• Hall space group symbol: -I 2ya
• Residual factor for all reflections: 0.0326
• Residual factor for significantly intense reflections: 0.0306
• Weighted residual factors for significantly intense reflections: 0.0811
• Weighted residual factors for all reflections included in the refinement: 0.0829
• Goodness-of-fit parameter for all reflections included in the refinement: 1.025
• Diffraction radiation probe: x-ray
• Diffraction radiation wavelength: 1.54184 Å
• Diffraction radiation type: CuKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No