Information card for entry 7703928

Structure parameters

• Formula: C156 H240 N6 Ni21.37 O52 Pd20.63
• Calculated formula: C156 H240 N6 Ni21.382 O52 Pd20.618
• Title of publication: Redox active Ni-Pd carbonyl alloy nanoclusters: syntheses, molecular structures and electrochemistry of [Ni_22-xPd_20+x(CO)₄₈]^6- (x = 0.62), [Ni_29-xPd_6+x(CO)₄₂]^6- (x = 0.09) and [Ni_29+xPd_6-x(CO)₄₂]^6- (x = 0.27).
• Authors of publication: Berti, Beatrice; Cesari, Cristiana; Femoni, Cristina; Funaioli, Tiziana; Iapalucci, Maria Carmela; Zacchini, Stefano
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2020
• Journal volume: 49
• Journal issue: 17
• Pages of publication: 5513 - 5522
• a: 38.6411 ± 0.0012 Å
• b: 17.6379 ± 0.0006 Å
• c: 33.0067 ± 0.0017 Å
• α: 90°
• β: 119.314 ± 0.001°
• γ: 90°
• Cell volume: 19615.1 ± 1.4 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 6
• Space group number: 15
• Hermann-Mauguin space group symbol: C 1 2/c 1
• Hall space group symbol: -C 2yc
• Residual factor for all reflections: 0.0567
• Residual factor for significantly intense reflections: 0.0452
• Weighted residual factors for significantly intense reflections: 0.0981
• Weighted residual factors for all reflections included in the refinement: 0.1033
• Goodness-of-fit parameter for all reflections included in the refinement: 1.061
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No