Information card for entry 7704222

Structure parameters

• Common name: (Clip)OsCl2 . EtOAc
• Chemical name: 2,2'-biphenylenediamido-N,N'-bis(2-oxy-3,5-di-tertbutylphenyl)-dichloroosmium(VI) ethyl acetate solvate
• Formula: C44 H56 Cl2 N2 O4 Os
• Calculated formula: C44 H56 Cl2 N2 O4 Os
• Title of publication: Highly covalent metal-ligand π bonding in chelated bis- and tris(iminoxolene) complexes of osmium and ruthenium.
• Authors of publication: Gianino, Jacqueline; Brown, Seth N.
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2020
• Journal volume: 49
• Journal issue: 21
• Pages of publication: 7015 - 7027
• a: 11.5267 ± 0.0006 Å
• b: 10.329 ± 0.0005 Å
• c: 36.2615 ± 0.0019 Å
• α: 90°
• β: 98.4471 ± 0.0018°
• γ: 90°
• Cell volume: 4270.4 ± 0.4 ų
• Cell temperature: 120 ± 2 K
• Ambient diffraction temperature: 120 ± 2 K
• Number of distinct elements: 6
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for all reflections: 0.0416
• Residual factor for significantly intense reflections: 0.028
• Weighted residual factors for significantly intense reflections: 0.0557
• Weighted residual factors for all reflections included in the refinement: 0.0605
• Goodness-of-fit parameter for all reflections included in the refinement: 1.009
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No