Information card for entry 7705988

Structure parameters

• Formula: C24 H45 N2 P2 Rh Si4
• Calculated formula: C24 H45 N2 P2 Rh Si4
• SMILES: [RhH2]123[P]4(c5ccccc5)C[Si]([NH]3[Si](C[P]1(c1ccccc1)C[Si](N2[Si](C4)(C)C)(C)C)(C)C)(C)C
• Title of publication: Forays into rhodium macrocyclic chemistry stabilized by a P₂N₂ donor set. Activation of dihydrogen and benzene.
• Authors of publication: Yeo, Alyssa; Sanz, Corey A.; Fryzuk, Michael D.
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2021
• Journal volume: 50
• Journal issue: 3
• Pages of publication: 899 - 907
• a: 15.1347 ± 0.0008 Å
• b: 10.0758 ± 0.0005 Å
• c: 20.3672 ± 0.001 Å
• α: 90°
• β: 95.293 ± 0.002°
• γ: 90°
• Cell volume: 3092.6 ± 0.3 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100.15 K
• Number of distinct elements: 6
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.0268
• Residual factor for significantly intense reflections: 0.0231
• Weighted residual factors for significantly intense reflections: 0.0649
• Weighted residual factors for all reflections included in the refinement: 0.0667
• Goodness-of-fit parameter for all reflections included in the refinement: 1.134
• Diffraction radiation probe: x-ray
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No