Crystallography Open Database

Information card for entry 7706960

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Coordinates	7706960.cif
Original paper (by DOI)	HTML

Structure parameters

Formula	C383 H319 Ag26 Br17 Cu4 F18 P18
Calculated formula	C382.999 H318.998 Ag26 Br16.9984 Cu4 F18.006 P18.001
Title of publication	The [Ag<sub>25</sub>Cu<sub>4</sub>H<sub>8</sub>Br<sub>6</sub>(CCPh)<sub>12</sub>(PPh<sub>3</sub>)<sub>12</sub>]<sup>3+</sup> : Ag<sub>13</sub>H<sub>8</sub> silver hydride core protected by [CuAg<sub>3</sub>(CCPh)<sub>3</sub>(PPh<sub>3</sub>)<sub>3</sub>]<sup>+</sup> motifs.
Authors of publication	Mikami, Kaiyu; Hui, Shen; Kubo, Kazuyuki; Kume, Shoko; Mizuta, Tsutomu
Journal of publication	Dalton transactions (Cambridge, England : 2003)
Year of publication	2021
Journal volume	50
Journal issue	16
Pages of publication	5659 - 5665
a	26.548 ± 0.013 Å
b	26.548 Å
c	48.43 ± 0.02 Å
α	90°
β	90°
γ	120°
Cell volume	29560 ± 19 Å³
Cell temperature	173 ± 2 K
Ambient diffraction temperature	173 ± 2 K
Number of distinct elements	7
Space group number	146
Hermann-Mauguin space group symbol	R 3 :H
Hall space group symbol	R 3
Residual factor for all reflections	0.0742
Residual factor for significantly intense reflections	0.0592
Weighted residual factors for significantly intense reflections	0.1715
Weighted residual factors for all reflections included in the refinement	0.1814
Goodness-of-fit parameter for all reflections included in the refinement	1.005
Diffraction radiation wavelength	0.71073 Å
Diffraction radiation type	MoKa
Has coordinates	Yes
Has disorder	Yes
Has F_obs	No

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