Information card for entry 7709321

Structure parameters

• Chemical name: tBu-PBP-Pt-SPh
• Formula: C30 H45 B N2 P2 Pt S
• Calculated formula: C30 H45 B N2 P2 Pt S
• Title of publication: Platinum thiolate complexes supported by PBP and POCOP pincer ligands as efficient catalysts for the hydrosilylation of carbonyl compounds
• Authors of publication: Xue, Man-Man; Chang, Jiarui; Zhang, Jie; Chen, Xuenian
• Journal of publication: Dalton Transactions
• Year of publication: 2022
• a: 12.8734 ± 0.0001 Å
• b: 17.4918 ± 0.0002 Å
• c: 14.8878 ± 0.0002 Å
• α: 90°
• β: 103.578 ± 0.001°
• γ: 90°
• Cell volume: 3258.72 ± 0.06 ų
• Cell temperature: 293 ± 2 K
• Ambient diffraction temperature: 293 ± 2 K
• Number of distinct elements: 7
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for all reflections: 0.0632
• Residual factor for significantly intense reflections: 0.0567
• Weighted residual factors for significantly intense reflections: 0.1682
• Weighted residual factors for all reflections included in the refinement: 0.1732
• Goodness-of-fit parameter for all reflections included in the refinement: 1.158
• Diffraction radiation probe: x-ray
• Diffraction radiation wavelength: 1.54184 Å
• Diffraction radiation type: CuKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No