Information card for entry 7709338

Structure parameters

• Chemical name: Cyano(triphenylsilyl)phosphanido[1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene]silver(I)
• Formula: C10.22 H11.33 Ag0.22 N0.67 P0.22 Si0.22
• Calculated formula: C10.2222 H11.3333 Ag0.222222 N0.666667 P0.222222 Si0.222222
• Title of publication: Simple conversion of trisodium phosphide, Na3P, into silyl- and cyanophosphides and structure of a terminal silver phosphide
• Authors of publication: Grützmacher, Hansjörg; Le Corre, Grégoire
• Journal of publication: Dalton Transactions
• Year of publication: 2022
• a: 9.5649 ± 0.0002 Å
• b: 20.049 ± 0.0003 Å
• c: 21.8272 ± 0.0003 Å
• α: 90°
• β: 90°
• γ: 90°
• Cell volume: 4185.73 ± 0.12 ų
• Cell temperature: 100.01 ± 0.1 K
• Ambient diffraction temperature: 100.01 ± 0.1 K
• Number of distinct elements: 6
• Space group number: 19
• Hermann-Mauguin space group symbol: P 21 21 21
• Hall space group symbol: P 2ac 2ab
• Residual factor for all reflections: 0.0316
• Residual factor for significantly intense reflections: 0.0278
• Weighted residual factors for significantly intense reflections: 0.0574
• Weighted residual factors for all reflections included in the refinement: 0.059
• Goodness-of-fit parameter for all reflections included in the refinement: 1.037
• Diffraction radiation probe: x-ray
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No