Information card for entry 7709339

Structure parameters

• Chemical name: Bis(trichlorosilyl)phoshanide tetraphenylphosphonium salt
• Formula: C1.81 H1.51 Cl0.45 P0.15 Si0.15
• Calculated formula: C1.81132 H1.50943 Cl0.45283 P0.150943 Si0.150943
• Title of publication: Simple conversion of trisodium phosphide, Na3P, into silyl- and cyanophosphides and structure of a terminal silver phosphide
• Authors of publication: Grützmacher, Hansjörg; Le Corre, Grégoire
• Journal of publication: Dalton Transactions
• Year of publication: 2022
• a: 13.2251 ± 0.0005 Å
• b: 14.2041 ± 0.0005 Å
• c: 15.3777 ± 0.0005 Å
• α: 90°
• β: 100.501 ± 0.001°
• γ: 90°
• Cell volume: 2840.33 ± 0.17 ų
• Cell temperature: 100 K
• Ambient diffraction temperature: 100.02 K
• Number of distinct elements: 5
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for all reflections: 0.0631
• Residual factor for significantly intense reflections: 0.0366
• Weighted residual factors for significantly intense reflections: 0.07
• Weighted residual factors for all reflections included in the refinement: 0.0811
• Goodness-of-fit parameter for all reflections included in the refinement: 1.076
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No