Information card for entry 7709340

Structure parameters

• Chemical name: Cyano(triphenylsilyl)phosphanido[1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene]copper(I)
• Formula: C9.68 H10.74 Cu0.21 N0.63 P0.21 Si0.21
• Calculated formula: C9.68421 H10.7368 Cu0.210526 N0.631579 P0.210526 Si0.210526
• Title of publication: Simple conversion of trisodium phosphide, Na3P, into silyl- and cyanophosphides and structure of a terminal silver phosphide
• Authors of publication: Grützmacher, Hansjörg; Le Corre, Grégoire
• Journal of publication: Dalton Transactions
• Year of publication: 2022
• a: 21.5909 ± 0.0006 Å
• b: 10.7125 ± 0.0003 Å
• c: 18.4005 ± 0.0004 Å
• α: 90°
• β: 90°
• γ: 90°
• Cell volume: 4255.9 ± 0.19 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 K
• Number of distinct elements: 6
• Space group number: 29
• Hermann-Mauguin space group symbol: P c a 21
• Hall space group symbol: P 2c -2ac
• Residual factor for all reflections: 0.0311
• Residual factor for significantly intense reflections: 0.0242
• Weighted residual factors for significantly intense reflections: 0.05
• Weighted residual factors for all reflections included in the refinement: 0.0547
• Goodness-of-fit parameter for all reflections included in the refinement: 1.049
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No