Information card for entry 7711110

Structure parameters

• Formula: C29 H50 N O3 P2 Rh Si
• Calculated formula: C29 H50 N O3 P2 Rh Si
• Title of publication: Distinct modes of Si–H binding to Rh in complexes of a phosphine-diarylamido-silane (SiNP) pincer ligand
• Authors of publication: Rain Talosig, A.; Cosio, Mario N.; Morse, Benjamin; Nguyen, Vinh T.; Kosanovich, Alex J.; Pell, Christopher J.; Li, Chun; Bhuvanesh, Nattamai; Zhou, Jia; Larsen, Anna S.; Ozerov, Oleg. V.
• Journal of publication: Dalton Transactions
• Year of publication: 2022
• a: 12.957 ± 0.004 Å
• b: 14.254 ± 0.004 Å
• c: 19.296 ± 0.005 Å
• α: 103.562 ± 0.007°
• β: 105.146 ± 0.008°
• γ: 100.236 ± 0.008°
• Cell volume: 3233.8 ± 1.6 ų
• Cell temperature: 110 K
• Ambient diffraction temperature: 110 K
• Number of distinct elements: 7
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0721
• Residual factor for significantly intense reflections: 0.0445
• Weighted residual factors for significantly intense reflections: 0.0756
• Weighted residual factors for all reflections included in the refinement: 0.083
• Goodness-of-fit parameter for all reflections included in the refinement: 1.029
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No