Information card for entry 7711933

Structure parameters

• Chemical name: [{κP,κC-(i-Pr)2PO-C6H4}{NH2OBn}Ni(Cl/Br)]
• Formula: C19 H27 Br0.26 Cl0.74 N Ni O2 P
• Calculated formula: C19 H27 Br0.2655 Cl0.7345 N Ni O2 P
• Title of publication: Reactivities of cyclonickellated complexes with hydroxylamines: formation of κ^O-hydroxylamine and κ^N-imine adducts and a κ^O, κ^N-aminoxide derivative.
• Authors of publication: Sarker, Rajib K.; Mangin, Loïc P; Zargarian, Davit
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2023
• Journal volume: 52
• Journal issue: 2
• Pages of publication: 366 - 375
• a: 9.2167 ± 0.0003 Å
• b: 10.7893 ± 0.0003 Å
• c: 11.1469 ± 0.0003 Å
• α: 108.309 ± 0.001°
• β: 99.259 ± 0.001°
• γ: 99.244 ± 0.001°
• Cell volume: 1011.92 ± 0.05 ų
• Cell temperature: 100 K
• Ambient diffraction temperature: 100 K
• Number of distinct elements: 8
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0237
• Residual factor for significantly intense reflections: 0.0236
• Weighted residual factors for significantly intense reflections: 0.0639
• Weighted residual factors for all reflections included in the refinement: 0.064
• Goodness-of-fit parameter for all reflections included in the refinement: 1.063
• Diffraction radiation wavelength: 1.54178 Å
• Diffraction radiation type: CuKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No