Information card for entry 7712338

Structure parameters

• Formula: C39 H59 B F N8 O Si3 Y
• Calculated formula: C39 H59 B F N8 O Si3 Y
• SMILES: [Y]12345(N([Si](C)(C)C)[Si]([CH]1=[C]5(N4[SiH2]c1ccccc1)Cc1ccc(F)cc1)(C)C)([O]1CCCC1)[n]1n(c(cc1C)C)[BH](n1[n]3c(cc1C)C)n1[n]2c(cc1C)C
• Title of publication: Selective Si−C(sp3) Bond Cleavage of Silyl−Bridged Amido Alkyl Ligand in an Yttrium Complex
• Authors of publication: Cai, Jiamin; Zhang, Jie; Zhou, Xigeng
• Journal of publication: Dalton Transactions
• Year of publication: 2023
• a: 9.714 ± 0.0003 Å
• b: 10.5154 ± 0.0003 Å
• c: 21.874 ± 0.0007 Å
• α: 98.518 ± 0.001°
• β: 93.937 ± 0.001°
• γ: 94.128 ± 0.001°
• Cell volume: 2196.84 ± 0.12 ų
• Cell temperature: 173 K
• Ambient diffraction temperature: 173 K
• Number of distinct elements: 8
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0393
• Residual factor for significantly intense reflections: 0.0379
• Weighted residual factors for significantly intense reflections: 0.104
• Weighted residual factors for all reflections included in the refinement: 0.1053
• Goodness-of-fit parameter for all reflections included in the refinement: 1.039
• Diffraction radiation probe: x-ray
• Diffraction radiation wavelength: 1.34138 Å
• Diffraction radiation type: GaKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No