Information card for entry 7713294

Structure parameters

• Chemical name: tris-carborane_triphenylphosphine_triethylsilane
• Formula: C30 H64 B31 P Si
• Calculated formula: C30 H64 B31 P Si
• Title of publication: Examining the reactivity of tris(<i>ortho</i>-carboranyl)borane with Lewis bases and application in frustrated Lewis pair Si-H bond cleavage.
• Authors of publication: Vashisth, Kanika; Dutta, Sanjay; Akram, Manjur O.; Martin, Caleb D.
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2023
• a: 15.5559 ± 0.0007 Å
• b: 15.5559 ± 0.0007 Å
• c: 36.209 ± 0.003 Å
• α: 90°
• β: 90°
• γ: 120°
• Cell volume: 7588.2 ± 0.8 ų
• Cell temperature: 193 ± 2 K
• Ambient diffraction temperature: 193 ± 2 K
• Number of distinct elements: 5
• Space group number: 148
• Hermann-Mauguin space group symbol: R -3 :H
• Hall space group symbol: -R 3
• Residual factor for all reflections: 0.0815
• Residual factor for significantly intense reflections: 0.0677
• Weighted residual factors for significantly intense reflections: 0.1691
• Weighted residual factors for all reflections included in the refinement: 0.1802
• Goodness-of-fit parameter for all reflections included in the refinement: 1.116
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No