Information card for entry 7715662

Structure parameters

• Formula: C63 H94 Mo2 O6 P2 Si4
• Calculated formula: C63 H94 Mo2 O6 P2 Si4
• Title of publication: Reactions of (mesityl)_<i>n</i>(methyl)_2-<i>n</i>silylene complexes with pyridine-<i>N</i>-oxide (<i>n</i> = 1 and 0): formation of silanone complexes and a disiloxanyloxy complex.
• Authors of publication: Muraoka, Takako; Ishita, Taichi; Kawachi, Kosuke; Nishio, Takuya; Ishihara, Hiroto; Ueno, Keiji
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2024
• Journal volume: 53
• Journal issue: 16
• Pages of publication: 7105 - 7114
• a: 36.982 ± 0.007 Å
• b: 11.547 ± 0.002 Å
• c: 16.211 ± 0.003 Å
• α: 90°
• β: 100.183 ± 0.004°
• γ: 90°
• Cell volume: 6814 ± 2 ų
• Cell temperature: 130 ± 2 K
• Ambient diffraction temperature: 130 ± 2 K
• Number of distinct elements: 6
• Space group number: 15
• Hermann-Mauguin space group symbol: C 1 2/c 1
• Hall space group symbol: -C 2yc
• Residual factor for all reflections: 0.0744
• Residual factor for significantly intense reflections: 0.0483
• Weighted residual factors for significantly intense reflections: 0.1256
• Weighted residual factors for all reflections included in the refinement: 0.1328
• Goodness-of-fit parameter for all reflections included in the refinement: 1.058
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No