Information card for entry 7715663

Structure parameters

• Formula: C25 H38 Mo O2 Si2
• Calculated formula: C25 H38 Mo O2 Si2
• SMILES: [Mo]1234(=[Si](C)c5c(cc(cc5C)C)C)([Si](C)(C)C)(C#[O])(C#[O])[c]5([c]1([c]2([c]3([c]45C)C)C)C)C
• Title of publication: Reactions of (mesityl)_<i>n</i>(methyl)_2-<i>n</i>silylene complexes with pyridine-<i>N</i>-oxide (<i>n</i> = 1 and 0): formation of silanone complexes and a disiloxanyloxy complex.
• Authors of publication: Muraoka, Takako; Ishita, Taichi; Kawachi, Kosuke; Nishio, Takuya; Ishihara, Hiroto; Ueno, Keiji
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2024
• Journal volume: 53
• Journal issue: 16
• Pages of publication: 7105 - 7114
• a: 15.221 ± 0.002 Å
• b: 16.815 ± 0.002 Å
• c: 20.546 ± 0.003 Å
• α: 90°
• β: 90°
• γ: 90°
• Cell volume: 5258.6 ± 1.2 ų
• Cell temperature: 130 ± 2 K
• Ambient diffraction temperature: 130 ± 2 K
• Number of distinct elements: 5
• Space group number: 61
• Hermann-Mauguin space group symbol: P c a b
• Hall space group symbol: -P 2bc 2ac
• Residual factor for all reflections: 0.0356
• Residual factor for significantly intense reflections: 0.0297
• Weighted residual factors for significantly intense reflections: 0.0732
• Weighted residual factors for all reflections included in the refinement: 0.0774
• Goodness-of-fit parameter for all reflections included in the refinement: 1.081
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No