Information card for entry 7716781

Structure parameters

• Formula: C15 H103 N10 Na2 Ni13 O117.5 P2 Sb2 W23
• Calculated formula: C15 H50 N10 Na2 Ni13 O109 P2 Sb2 W23
• Title of publication: Two nickel-added poly(polyoxometalate)s built of Keggin-type {Ni₆PW₉} and Anderson-type NiW₆O₂₄<i>via</i> WO₄/Sb₂O bridges and Ni-O-W linkages with efficient hydrogen evolution activity.
• Authors of publication: Zhang, Peng-Yun; Lian, Chen; Wang, Zhen-Wen; Chen, Juan; Lv, Hongjin; Yang, Guo-Yu
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2024
• Journal volume: 53
• Journal issue: 32
• Pages of publication: 13409 - 13415
• a: 14.1447 ± 0.0007 Å
• b: 19.4035 ± 0.0009 Å
• c: 22.8651 ± 0.001 Å
• α: 90.197 ± 0.001°
• β: 106.129 ± 0.001°
• γ: 98.544 ± 0.001°
• Cell volume: 5955 ± 0.5 ų
• Cell temperature: 296 ± 2 K
• Ambient diffraction temperature: 296.15 K
• Number of distinct elements: 9
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0624
• Residual factor for significantly intense reflections: 0.0456
• Weighted residual factors for significantly intense reflections: 0.0951
• Weighted residual factors for all reflections included in the refinement: 0.1009
• Goodness-of-fit parameter for all reflections included in the refinement: 1.034
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No