Information card for entry 8100878

Structure parameters

• Formula: C38.25 H44.5 B Cl0.5 F4 O3 P2 Rh
• Calculated formula: C38.25 H36 B Cl0.5 F4 O3 P2 Rh
• Title of publication: Crystal structure of 1,2-bis(diphenylphosphinoxy)-ethane rhodium(I)- norborna-2,5-diene tetrafluoroborate, C~33~H~32~BF~4~O~2~P~2~Rh, and of 1,2-bis(diphenylphosphinoxy)-ethane rhodium(I)-(Z,Z)-cycloocta- 1,5-diene tetrafluoroborate, C~34~H~36~BF~4~O~2~P~2~Rh · C~4~H~8~O · 1/4CH~2~Cl~2~
• Authors of publication: Kempe, Rhett; Spannenberg, Anke; Heller, Detlef; Kadyrov, Renat; Fehring, Volker
• Journal of publication: Zeitschrift für Kristallographie - New Crystal Structures
• Year of publication: 2001
• Journal volume: 216
• Journal issue: 1
• Pages of publication: 157 - 160
• a: 9.629 ± 0.002 Å
• b: 24.925 ± 0.005 Å
• c: 16.639 ± 0.003 Å
• α: 90°
• β: 92.31 ± 0.03°
• γ: 90°
• Cell volume: 3990.2 ± 1.4 ų
• Cell temperature: 200 ± 2 K
• Ambient diffraction temperature: 200 ± 2 K
• Number of distinct elements: 8
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for significantly intense reflections: 0.0603
• Weighted residual factors for significantly intense reflections: 0.1695
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No