Information card for entry 1575459

Structure parameters

• Chemical name: Ni(Cy-allene)(iPrIM)2
• Formula: C27 H46 N4 Ni
• Calculated formula: C27 H46 N4 Ni
• Title of publication: Reactivity of a <i>cis</i>-(silyl)(boryl) moiety with a nickel center involving the oxidative addition and reductive elimination of a silylborane.
• Authors of publication: Suga, Yuto; Sunada, Yusuke
• Journal of publication: Chemical communications (Cambridge, England)
• Year of publication: 2025
• Journal volume: 61
• Journal issue: 75
• Pages of publication: 14370 - 14373
• a: 15.0604 ± 0.0005 Å
• b: 9.9004 ± 0.0003 Å
• c: 19.0001 ± 0.0006 Å
• α: 90°
• β: 93.959 ± 0.003°
• γ: 90°
• Cell volume: 2826.23 ± 0.16 ų
• Cell temperature: 173 K
• Ambient diffraction temperature: 173 K
• Number of distinct elements: 4
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.053
• Residual factor for significantly intense reflections: 0.035
• Weighted residual factors for significantly intense reflections: 0.0777
• Weighted residual factors for all reflections included in the refinement: 0.0831
• Goodness-of-fit parameter for all reflections included in the refinement: 1.039
• Diffraction radiation probe: x-ray
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No