Information card for entry 4113976

Structure parameters

• Formula: C15 H47 P3 Ru Si2
• Calculated formula: C15 H47 P3 Ru Si2
• SMILES: [RuH3]([P](C)(C)C)([P](C)(C)C)([P](C)(C)C)[Si](C)(C)C[Si](C)(C)C
• Title of publication: Structure and Reactivity of Bis(silyl) Dihydride Complexes (PMe3)3Ru(SiR3)2(H)2: Model Compounds and Real Intermediates in a Dehydrogenative C-Si Bond Forming Reaction
• Authors of publication: Vladimir K. Dioumaev; Bok R. Yoo; Leo J. Procopio; Patrick J. Carroll; Donald H. Berry
• Journal of publication: Journal of the American Chemical Society
• Year of publication: 2003
• Journal volume: 125
• Pages of publication: 8936 - 8948
• a: 14.1488 ± 0.0001 Å
• b: 18.5561 ± 0.0003 Å
• c: 9.9845 ± 0.0001 Å
• α: 90°
• β: 93.059 ± 0.001°
• γ: 90°
• Cell volume: 2617.66 ± 0.05 ų
• Cell temperature: 200 ± 2 K
• Ambient diffraction temperature: 200 ± 2 K
• Number of distinct elements: 5
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for all reflections: 0.0456
• Residual factor for significantly intense reflections: 0.0426
• Weighted residual factors for all reflections: 0.1127
• Weighted residual factors for significantly intense reflections: 0.1103
• Goodness-of-fit parameter for all reflections: 1.127
• Goodness-of-fit parameter for significantly intense reflections: 1.134
• Diffraction radiation wavelength: 0.71069 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No