Information card for entry 4127550

Structure parameters

• Chemical name: [[BP2iPr](PhSiH2)CoH2]Si[H2Co[BP3iPr]]
• Formula: C53 H101 B2 Co2 P5 Si2
• Calculated formula: C53 H101 B2 Co2 P5 Si2
• Title of publication: Activations of all Bonds to Silicon (Si-H, Si-C) in a Silane with Extrusion of [CoSiCo] Silicide Cores.
• Authors of publication: Handford, Rex C.; Smith, Patrick W.; Tilley, T. Don
• Journal of publication: Journal of the American Chemical Society
• Year of publication: 2019
• Journal volume: 141
• Journal issue: 22
• Pages of publication: 8769 - 8772
• a: 11.5244 ± 0.0004 Å
• b: 12.7658 ± 0.0004 Å
• c: 21.215 ± 0.0007 Å
• α: 95.296 ± 0.001°
• β: 96.883 ± 0.001°
• γ: 107.287 ± 0.001°
• Cell volume: 2931.59 ± 0.17 ų
• Cell temperature: 100 K
• Ambient diffraction temperature: 100 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0749
• Residual factor for significantly intense reflections: 0.0504
• Weighted residual factors for significantly intense reflections: 0.105
• Weighted residual factors for all reflections included in the refinement: 0.1152
• Goodness-of-fit parameter for all reflections included in the refinement: 1.034
• Diffraction radiation probe: x-ray
• Diffraction radiation wavelength: 0.7288 Å
• Diffraction radiation type: synchrotron
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No