Information card for entry 4071263

Structure parameters

• Common name: UCI15
• Formula: C27 H45 N2 Si Y
• Calculated formula: C27 H45 N2 Si Y
• SMILES: [c]12([c]3([c]4([c]5([c]1(C)[Y]167892345([c]2([c]8([c]7([c]6([c]12C)C)C)C)C)[N](=C\[Si](C)(C)C)/N9CC=C)C)C)C)C
• Title of publication: Diazomethane Insertion into Lanthanide− and Yttrium−C(allyl) Bonds To Form the η2-Hydrazonato Complexes (C5Me5)2Ln[η2(N,N′)-RNNCHSiMe3] (R = C3H5)
• Authors of publication: Evans, William J.; Montalvo, Elizabeth; Champagne, Timothy M.; Ziller, Joseph W.; DiPasquale, Antonio G.; Rheingold, Arnold L.
• Journal of publication: Organometallics
• Year of publication: 2008
• Journal volume: 27
• Journal issue: 14
• Pages of publication: 3582
• a: 11.509 ± 0.0015 Å
• b: 13.9781 ± 0.0019 Å
• c: 18.573 ± 0.003 Å
• α: 90°
• β: 106.132 ± 0.002°
• γ: 90°
• Cell volume: 2870.3 ± 0.7 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 5
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.0663
• Residual factor for significantly intense reflections: 0.0443
• Weighted residual factors for significantly intense reflections: 0.1075
• Weighted residual factors for all reflections included in the refinement: 0.1168
• Goodness-of-fit parameter for all reflections included in the refinement: 1.032
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No