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Information card for entry 4089397
Preview
Coordinates | 4089397.cif |
---|---|
Original paper (by DOI) | HTML |
Chemical name | (υ^2-Hydroxo)-(carbonyl)-(trimethylsilyl- ν^5-cyclopentadienyl)-tetrakis(t-butyl)- iron-di-tin(ii) |
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Formula | C32 H60 Fe N2 O2 Si Sn2 |
Calculated formula | C32 H60 Fe N2 O2 Si Sn2 |
SMILES | [Sn]1([OH][Sn]([Fe]23451([c]1([cH]3[cH]4[cH]5[cH]21)[Si](C)(C)C)C#[O])(C(C)(C)C)C(C)(C)C)(C(C)(C)C)C(C)(C)C.n1ccc(N(C)C)cc1 |
Title of publication | Reactions of an Iron Chlorodistannane with Hydroxide: Isolation and Structural Characterization of {(η5-Me3SiC5H4)Fe(CO)[(SntBu2)2(μ-OH)]···DMAP}, DMAP = 4-(N,N-Dimethylamino)pyridine, a μ-OH-Stannyl(stannylene)‒Iron Complex |
Authors of publication | Sharma, Hemant K.; Metta-Magaña, Alejandro J.; Pannell, Keith H. |
Journal of publication | Organometallics |
Year of publication | 2013 |
Journal volume | 32 |
Journal issue | 21 |
Pages of publication | 6218 |
a | 9.812 ± 0.0011 Å |
b | 11.7799 ± 0.0017 Å |
c | 18.284 ± 0.002 Å |
α | 93.114 ± 0.002° |
β | 100.116 ± 0.002° |
γ | 114.472 ± 0.002° |
Cell volume | 1874.4 ± 0.4 Å3 |
Cell temperature | 100 ± 2 K |
Ambient diffraction temperature | 100 ± 2 K |
Number of distinct elements | 7 |
Space group number | 2 |
Hermann-Mauguin space group symbol | P -1 |
Hall space group symbol | -P 1 |
Residual factor for all reflections | 0.0207 |
Residual factor for significantly intense reflections | 0.0185 |
Weighted residual factors for significantly intense reflections | 0.0837 |
Weighted residual factors for all reflections included in the refinement | 0.0865 |
Goodness-of-fit parameter for all reflections included in the refinement | 0.755 |
Diffraction radiation wavelength | 0.71073 Å |
Diffraction radiation type | MoKα |
Has coordinates | Yes |
Has disorder | No |
Has Fobs | No |
For the version history of this entry, please navigate to main COD server.
The link is: https://www.crystallography.net/4089397.html
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