Information card for entry 4314684

Structure parameters

• Formula: C53 H68 B2 F24 N P2 Rh
• Calculated formula: C53 H68 B2 F24 N P2 Rh
• Title of publication: Amine- and Dimeric Amino-Borane Complexes of the {Rh(PiPr3)2}+ Fragment and Their Relevance to the Transition-Metal-Mediated Dehydrocoupling of Amine-Boranes
• Authors of publication: Adrian B. Chaplin; Andrew S. Weller
• Journal of publication: Inorganic Chemistry
• Year of publication: 2010
• Journal volume: 49
• Pages of publication: 1111 - 1121
• a: 12.4135 ± 0.0002 Å
• b: 13.8862 ± 0.0003 Å
• c: 19.2604 ± 0.0004 Å
• α: 105.426 ± 0.001°
• β: 104.275 ± 0.001°
• γ: 90.278 ± 0.0008°
• Cell volume: 3092.79 ± 0.11 ų
• Cell temperature: 150 ± 2 K
• Ambient diffraction temperature: 150 ± 2 K
• Number of distinct elements: 7
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0635
• Residual factor for significantly intense reflections: 0.0443
• Weighted residual factors for significantly intense reflections: 0.1039
• Weighted residual factors for all reflections included in the refinement: 0.1142
• Goodness-of-fit parameter for all reflections included in the refinement: 1.02
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No