Information card for entry 4324726

Structure parameters

• Chemical name: N,N'-bis(trimethylsilyl)-N'-(dimethylchlorosilyl)hydrazinomethylphenyl phosphane galliumtrichloride adduct
• Formula: C15 H32 Cl4 Ga N2 P Si3
• Calculated formula: C15 H32 Cl4 Ga N2 P Si3
• SMILES: [P]([Ga](Cl)(Cl)Cl)(N([Si](C)(C)C)N([Si](C)(C)C)[Si](Cl)(C)C)(c1ccccc1)C
• Title of publication: Lewis Acid Assisted Methyl/Chlorine Exchange in Silylated Hydrazinochlorophosphanes
• Authors of publication: Andrea Westenkirchner; Alexander Villinger; Konstantin Karaghiosoff; Ronald Wustrack; Dirk Michalik; Axel Schulz
• Journal of publication: Inorganic Chemistry
• Year of publication: 2011
• Journal volume: 50
• Pages of publication: 2691 - 2702
• a: 9.709 ± 0.0019 Å
• b: 15.819 ± 0.003 Å
• c: 18.523 ± 0.005 Å
• α: 90°
• β: 110.96 ± 0.03°
• γ: 90°
• Cell volume: 2656.6 ± 1.1 ų
• Cell temperature: 173 ± 2 K
• Ambient diffraction temperature: 173 ± 2 K
• Number of distinct elements: 7
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.0384
• Residual factor for significantly intense reflections: 0.033
• Weighted residual factors for significantly intense reflections: 0.0959
• Weighted residual factors for all reflections included in the refinement: 0.0995
• Goodness-of-fit parameter for all reflections included in the refinement: 1.059
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No