Information card for entry 4329822

Structure parameters

• Formula: C41.5 H61 Cl2 Ge N3 P Rh
• Calculated formula: C41 H60 Cl Ge N3 P Rh
• SMILES: [Rh]123([Ge]4([P]5(N(CCN5C(C)C)C(C)C)C5=C(N4c4c(cccc4C(C)C)C(C)C)[C@@H]4CC[C@H]5C4)c4ccccc4)(Cl)[CH]4=[CH]1CC[CH]2=[CH]3CC4.[Rh]123([Ge]4([P]5(N(CCN5C(C)C)C(C)C)C5=C(N4c4c(cccc4C(C)C)C(C)C)[C@H]4CC[C@@H]5C4)c4ccccc4)(Cl)[CH]4=[CH]1CC[CH]2=[CH]3CC4
• Title of publication: Synthesis and Characterization of Rhodium Complexes with Phosphine-Stabilized Germylenes
• Authors of publication: Juan Manuel García; Edgar Ocando Mavárez; Tsuyoshi Kato; David Santiago Coll; Alexander Briceño; Nathalie Saffon-Merceron; Antoine Bacereido
• Journal of publication: Inorganic Chemistry
• Year of publication: 2012
• Journal volume: 51
• Pages of publication: 8187 - 8193
• a: 40.324 ± 0.01 Å
• b: 10.852 ± 0.002 Å
• c: 20.025 ± 0.005 Å
• α: 90°
• β: 105.206 ± 0.006°
• γ: 90°
• Cell volume: 8456 ± 3 ų
• Cell temperature: 293 ± 2 K
• Ambient diffraction temperature: 293 ± 2 K
• Number of distinct elements: 7
• Space group number: 15
• Hermann-Mauguin space group symbol: C 1 2/c 1
• Hall space group symbol: -C 2yc
• Residual factor for all reflections: 0.0824
• Residual factor for significantly intense reflections: 0.0595
• Weighted residual factors for significantly intense reflections: 0.1229
• Weighted residual factors for all reflections included in the refinement: 0.1353
• Goodness-of-fit parameter for all reflections included in the refinement: 1.077
• Diffraction radiation wavelength: 0.7107 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No