Information card for entry 4335187

Structure parameters

• Formula: C24 H27 F12 N7 Ru Sb2
• Calculated formula: C24 H27 F12 N7 Ru Sb2
• SMILES: [Ru]123([N](Cc4[n]1cccc4)(Cc1[n]2cccc1)Cc1[n]3cccc1)([N]#CC)[N]#CC.[Sb](F)(F)(F)([F-])(F)F.[Sb](F)(F)(F)(F)(F)[F-].N#CC
• Title of publication: Tri(pyridylmethyl)phosphine: The Elusive Congener of TPA Shows Surprisingly Different Coordination Behavior
• Authors of publication: Christopher J. Whiteoak; James D. Nobbs; Evgeny Kiryushchenkov; Sandro Pagano; Andrew J.P. White; George J.P. Britovsek
• Journal of publication: Inorganic Chemistry
• Year of publication: 2013
• Journal volume: 52
• Pages of publication: 7000 - 7009
• a: 8.71065 ± 0.00014 Å
• b: 9.04339 ± 0.00016 Å
• c: 20.2295 ± 0.0003 Å
• α: 93.6493 ± 0.0014°
• β: 93.6436 ± 0.0014°
• γ: 92.6472 ± 0.0014°
• Cell volume: 1585.09 ± 0.04 ų
• Cell temperature: 173 ± 2 K
• Ambient diffraction temperature: 173 ± 2 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0452
• Residual factor for significantly intense reflections: 0.0284
• Weighted residual factors for significantly intense reflections: 0.0552
• Weighted residual factors for all reflections included in the refinement: 0.0575
• Goodness-of-fit parameter for all reflections included in the refinement: 0.936
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No