Information card for entry 7010780

Structure parameters

• Formula: C25 H40 Li N3 Si
• Calculated formula: C25 H40 Li N3 Si
• SMILES: [Li]1(N(C(=Cc2ccccc2)[Si](C)(C)C)c2c(cccc2C)C)[N](CC[N]1(C)C)(C)C
• Title of publication: The reactions of lithium trimethysilylmethyls with isocyanides; structures and reactions of the derived lithium 1-azaallyls, β-diketiminates and a 1-azabuta-1,3-dienyl-3-amide
• Authors of publication: Hitchcock, Peter B.; Lappert, Michael F.; Layh, Marcus
• Journal of publication: Journal of the Chemical Society, Dalton Transactions
• Year of publication: 2001
• Journal issue: 16
• Pages of publication: 2409
• a: 32.9 ± 0.007 Å
• b: 8.553 ± 0.002 Å
• c: 19.852 ± 0.005 Å
• α: 90°
• β: 113.77 ± 0.02°
• γ: 90°
• Cell volume: 5112 ± 2 ų
• Cell temperature: 173 ± 2 K
• Ambient diffraction temperature: 173 ± 2 K
• Number of distinct elements: 5
• Space group number: 15
• Hermann-Mauguin space group symbol: C 1 2/c 1
• Hall space group symbol: -C 2yc
• Residual factor for all reflections: 0.1941
• Residual factor for significantly intense reflections: 0.0884
• Weighted residual factors for all reflections: 0.2225
• Weighted residual factors for significantly intense reflections: 0.1695
• Goodness-of-fit parameter for all reflections: 1.011
• Goodness-of-fit parameter for significantly intense reflections: 1.134
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No