Information card for entry 7012285

Structure parameters

• Formula: C70 H69 Mo N P4 Si
• Calculated formula: C70 H60 Mo N P4 Si
• SMILES: [Mo]1234([P](c5c([Si]4(c4ccccc4)c4c([P]3(CC[P]2(c2ccccc2)c2ccccc2)c2ccccc2)cccc4)cccc5)(c2ccccc2)CC[P]1(c1ccccc1)c1ccccc1)C#[N]C(C)(C)C.c1(ccccc1)C
• Title of publication: Reactions of quadruply chelated silyl- and germyl-molybdenum hydrido complexes with isocyanides: observation of the trans-influence on the silyl ligand
• Authors of publication: Minato, Makoto; Nishiuchi, Jun-ya; Kakeya, Masaki; Matsumoto, Takaomi; Yamaguchi, Yoshitaka; Ito, Takashi
• Journal of publication: Dalton Transactions
• Year of publication: 2003
• Journal issue: 3
• Pages of publication: 483
• a: 14.42 ± 0.02 Å
• b: 17.611 ± 0.005 Å
• c: 13.275 ± 0.004 Å
• α: 90.5 ± 0.02°
• β: 109.72 ± 0.05°
• γ: 76.78 ± 0.07°
• Cell volume: 3081 ± 5 ų
• Cell temperature: 218.2 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for significantly intense reflections: 0.1316
• Weighted residual factors for all reflections included in the refinement: 0.3214
• Goodness-of-fit parameter for all reflections included in the refinement: 3.384
• Diffraction radiation wavelength: 0.7107 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No