Information card for entry 7038692

Structure parameters

• Formula: C38 H92 P8 Re2 Si2
• Calculated formula: C38 H92 P8 Re2 Si2
• SMILES: C(=[Re](C#C[Si](C)(C)C)([P](C)(C)C)([P](C)(C)C)([P](C)(C)C)[P](C)(C)C)=CC=C=[Re](C#C[Si](C)(C)C)([P](C)(C)C)([P](C)(C)C)([P](C)(C)C)[P](C)(C)C
• Title of publication: Electronic communication in phosphine substituted bridged dirhenium complexes - clarifying ambiguities raised by the redox non-innocence of the C4H2- and C4-bridges.
• Authors of publication: Li, Yan; Blacque, Olivier; Fox, Thomas; Luber, Sandra; Polit, Walther; Winter, Rainer F.; Venkatesan, Koushik; Berke, Heinz
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2016
• Journal volume: 45
• Journal issue: 13
• Pages of publication: 5783 - 5799
• a: 15.5085 ± 0.0011 Å
• b: 9.9898 ± 0.0004 Å
• c: 18.9014 ± 0.0008 Å
• α: 90°
• β: 93.969 ± 0.005°
• γ: 90°
• Cell volume: 2921.3 ± 0.3 ų
• Cell temperature: 183 ± 2 K
• Ambient diffraction temperature: 183 ± 2 K
• Number of distinct elements: 5
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.0375
• Residual factor for significantly intense reflections: 0.028
• Weighted residual factors for significantly intense reflections: 0.06
• Weighted residual factors for all reflections included in the refinement: 0.0623
• Goodness-of-fit parameter for all reflections included in the refinement: 1.018
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No