Information card for entry 7100139

Structure parameters

• Formula: C40 H38 Mn4 N4 O16 P2
• Calculated formula: C20 H19 Mn2 N2 O8 P
• SMILES: [P]12(N(C(C)C)C(C)C)N([Mn]1([Mn]2(C#[O])(C#[O])(C#[O])C#[O])(C#[O])(C#[O])(C#[O])C#[O])c1ccccc1
• Title of publication: Reactivity of Electrophilic m2-Phosphinidene Complexes with Heterocumulenes: Formation of the First s-p-Aminophosphaimine Complexes [Mn2(CO)8{m-h1,h2-P(NiPr2)=NR}] and Diazoalkane Insertions into Metal-Phosphorus Bonds.
• Authors of publication: A. Carty; Todd Graham; Konstantin A. Udachin
• Journal of publication: Chemical Communications
• Year of publication: 2005
• a: 8.8228 ± 0.0011 Å
• b: 9.7766 ± 0.0012 Å
• c: 28.072 ± 0.003 Å
• α: 90°
• β: 97.045 ± 0.002°
• γ: 90°
• Cell volume: 2403.1 ± 0.5 ų
• Cell temperature: 125 ± 2 K
• Ambient diffraction temperature: 125 ± 2 K
• Number of distinct elements: 6
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No