Information card for entry 7700759

Structure parameters

• Common name: [Tl(N3Dmp2)]
• Formula: C51 H57 N3 Tl
• Calculated formula: C51 H57 N3 Tl
• Title of publication: Kinetic stabilization of low-oxidation state and terminal hydrido main group metal complexes by a sterically demanding N,N'-bis(2,6-terphenyl)triazenide.
• Authors of publication: Leverett, Anthony R.; Diachenko, Vera; Cole, Marcus L.; McKay, Alasdair I.
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2019
• Journal volume: 48
• Journal issue: 35
• Pages of publication: 13197 - 13204
• a: 10.5807 ± 0.0004 Å
• b: 11.4067 ± 0.0004 Å
• c: 20.4425 ± 0.0008 Å
• α: 98.589 ± 0.002°
• β: 100.822 ± 0.002°
• γ: 111.879 ± 0.002°
• Cell volume: 2182.73 ± 0.15 ų
• Cell temperature: 150 ± 2 K
• Ambient diffraction temperature: 150 ± 2 K
• Number of distinct elements: 4
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0765
• Residual factor for significantly intense reflections: 0.0378
• Weighted residual factors for significantly intense reflections: 0.0737
• Weighted residual factors for all reflections included in the refinement: 0.0836
• Goodness-of-fit parameter for all reflections included in the refinement: 0.993
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No