Information card for entry 7716444

Structure parameters

• Formula: C21 H29 B2 N12 O Si Sm
• Calculated formula: C21 H29 B2 N12 O Si Sm
• Title of publication: Activation and functionalisation of carbon dioxide by bis-tris(pyrazolyl)borate-supported divalent samarium and trivalent lanthanide silylamide complexes
• Authors of publication: Chowdhury, Tajrian; Wilson, Claire; Farnaby, Joy
• Journal of publication: Dalton Transactions
• Year of publication: 2024
• a: 17.2101 ± 0.0009 Å
• b: 7.7251 ± 0.0003 Å
• c: 21.3419 ± 0.001 Å
• α: 90°
• β: 104.927 ± 0.002°
• γ: 90°
• Cell volume: 2741.7 ± 0.2 ų
• Cell temperature: 150 K
• Ambient diffraction temperature: 150 K
• Number of distinct elements: 7
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.048
• Residual factor for significantly intense reflections: 0.0325
• Weighted residual factors for significantly intense reflections: 0.0656
• Weighted residual factors for all reflections included in the refinement: 0.0716
• Goodness-of-fit parameter for all reflections included in the refinement: 1.029
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No