Crystallography Open Database

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1567143 CIFC24 H18 Br2 O2P 1 21/c 110.087; 24.117; 10.137
90; 119.385; 90
2148.7Samultceva, Sofia O.; Dvorko, Marina Yu.; Shabalin, Dmitrii A.; Ushakov, Igor’ A.; Vashchenko, Alexander V.; Schmidt, Elena Yu.; Trofimov, Boris A.
Regio- and stereoselective base-catalyzed assembly of 6-methylene-5-oxaspiro[2.4]heptanones from alkynyl cyclopropyl ketones
Organic & Biomolecular Chemistry, 2022, 20, 5325-5333
7158397 CIFC20 H18 F2 O7 S2P 21 21 215.4744; 17.602; 21.4574
90; 90; 90
2067.6Guinan, Mieke; Huang, Ningwu; Hawes, Chris S.; Lima, Marcelo A.; Smith, Mark; Miller, Gavin J.
Chemical synthesis of 4'-thio and 4'-sulfinyl pyrimidine nucleoside analogues.
Organic & biomolecular chemistry, 2022, 20, 1401-1406
7158398 CIFC76 H70 N2 O12P -114.238; 14.993; 15.638
70.194; 85.592; 77.672
3068.3Spatola, Emanuele; Rispoli, Francesco; Del Giudice, Daniele; Cacciapaglia, Roberta; Casnati, Alessandro; Marchiò, Luciano; Baldini, Laura; Di Stefano, Stefano
Dissipative control of the fluorescence of a 1,3-dipyrenyl calix[4]arene in the cone conformation.
Organic & biomolecular chemistry, 2021, 20, 132-138
7158415 CIFC26 H26 N2 O5P 1 21/c 19.084; 17.37; 14.777
90; 95.273; 90
2321.8Wu, Chaofei; Wan, Junlin; Song, Chao; He, Lingchen; Liu, Hongxin; Li, Xinhua; Li, Juan; Hu, Xin-Gen; Xiao, Hong-Ping; Jiang, Jun
Yb(OTf)<sub>3</sub> catalyzed [1,3]-rearrangement of 3-alkenyl oxindoles.
Organic & biomolecular chemistry, 2021, 20, 122-126
7158416 CIFC27 H26 N2 O6P 1 21/c 19.3272; 13.2464; 18.7695
90; 95.372; 90
2308.8Wu, Chaofei; Wan, Junlin; Song, Chao; He, Lingchen; Liu, Hongxin; Li, Xinhua; Li, Juan; Hu, Xin-Gen; Xiao, Hong-Ping; Jiang, Jun
Yb(OTf)<sub>3</sub> catalyzed [1,3]-rearrangement of 3-alkenyl oxindoles.
Organic & biomolecular chemistry, 2021, 20, 122-126
7158417 CIFC18 H22 Br4 Cu2 F2 N4P -17.8883; 8.1714; 10.3538
71.537; 79.335; 70.634
594.83Camats, Marc; Favier, Isabelle; Mallet-Ladeira, Sonia; Pla, Daniel; Gómez, Montserrat
Understanding Cu(II)-based systems for C(sp<sup>3</sup>)-H bond functionalization: insights into the synthesis of aza-heterocycles.
Organic & biomolecular chemistry, 2021, 20, 219-227
7158418 CIFC9 H7 F N2P 1 21/c 19.9462; 11.8055; 7.1741
90; 109.811; 90
792.53Camats, Marc; Favier, Isabelle; Mallet-Ladeira, Sonia; Pla, Daniel; Gómez, Montserrat
Understanding Cu(II)-based systems for C(sp<sup>3</sup>)-H bond functionalization: insights into the synthesis of aza-heterocycles.
Organic & biomolecular chemistry, 2021, 20, 219-227
7158419 CIFC72 H108 Cl6 Cu4 F4 N8 OI -411.5858; 11.5858; 29.2335
90; 90; 90
3924Camats, Marc; Favier, Isabelle; Mallet-Ladeira, Sonia; Pla, Daniel; Gómez, Montserrat
Understanding Cu(II)-based systems for C(sp<sup>3</sup>)-H bond functionalization: insights into the synthesis of aza-heterocycles.
Organic & biomolecular chemistry, 2021, 20, 219-227
7158420 CIFC10 H8 F N3I b a m15.8734; 17.3509; 6.6216
90; 90; 90
1823.71Camats, Marc; Favier, Isabelle; Mallet-Ladeira, Sonia; Pla, Daniel; Gómez, Montserrat
Understanding Cu(II)-based systems for C(sp<sup>3</sup>)-H bond functionalization: insights into the synthesis of aza-heterocycles.
Organic & biomolecular chemistry, 2021, 20, 219-227
7158425 CIFC50 H54 S4P -19.185; 12.053; 19.519
76.378; 89.717; 89.993
2100Sartucci, Jenna L.; Maity, Arindam; Mohanan, Manikandan; Bertke, Jeffery; Kertesz, Miklos; Gavvalapalli, Nagarjuna
Molecular tetrominoes: selective masking of the donor π-face to control the configuration of donor-acceptor complexes.
Organic & biomolecular chemistry, 2022, 20, 375-386
7158426 CIFC38 H14 Cl4 N4 O4P -16.4871; 7.1989; 17.9
92.211; 97.288; 102.06
809Sartucci, Jenna L.; Maity, Arindam; Mohanan, Manikandan; Bertke, Jeffery; Kertesz, Miklos; Gavvalapalli, Nagarjuna
Molecular tetrominoes: selective masking of the donor π-face to control the configuration of donor-acceptor complexes.
Organic & biomolecular chemistry, 2022, 20, 375-386
7158427 CIFC36 H34 S2P 21 21 2111.8779; 14.0953; 16.4691
90; 90; 90
2757.3Sartucci, Jenna L.; Maity, Arindam; Mohanan, Manikandan; Bertke, Jeffery; Kertesz, Miklos; Gavvalapalli, Nagarjuna
Molecular tetrominoes: selective masking of the donor π-face to control the configuration of donor-acceptor complexes.
Organic & biomolecular chemistry, 2022, 20, 375-386
7158428 CIFC30 H28 O2P -18.9341; 10.7311; 12.8284
73.101; 82.359; 83.312
1162.4Baire, Beeraiah; Santhi, Jampani
Ag(I)-Promoted homo-dimerization of 2-(alk-2-yn-1-onyl)-1-alkynylbenzenes <i>via</i> a [4 + 2] cycloaddition of benzopyrylium ions: access to structurally unique naphthalenes.
Organic & biomolecular chemistry, 2021, 20, 247-251
7158429 CIFC33 H18 Br2 OC 1 c 113.5539; 17.8625; 12.4649
90; 122.657; 90
2540.8Baire, Beeraiah; Santhi, Jampani
Ag(I)-Promoted homo-dimerization of 2-(alk-2-yn-1-onyl)-1-alkynylbenzenes <i>via</i> a [4 + 2] cycloaddition of benzopyrylium ions: access to structurally unique naphthalenes.
Organic & biomolecular chemistry, 2021, 20, 247-251
7158430 CIFC34 H20 O2C 1 2/c 131.9258; 18.7977; 8.245
90; 96.472; 90
4916.6Baire, Beeraiah; Santhi, Jampani
Ag(I)-Promoted homo-dimerization of 2-(alk-2-yn-1-onyl)-1-alkynylbenzenes <i>via</i> a [4 + 2] cycloaddition of benzopyrylium ions: access to structurally unique naphthalenes.
Organic & biomolecular chemistry, 2021, 20, 247-251
7158434 CIFC20 H18 N2 O4P -18.9944; 10.698; 11.488
116.186; 111.602; 90.504
902.6Kolla, Sai Teja; Rayala, Nageswara Rao; Sridhar, Balasubramanian; Bhimapaka, China Raju
Unexpected ring opening of pyrazolines with activated alkynes: synthesis of 1<i>H</i>-pyrazole-4,5-dicarboxylates and chromenopyrazolecarboxylates.
Organic & biomolecular chemistry, 2022, 20, 334-338
7158435 CIFC17 H20 N2 O5P 1 21/c 15.6344; 34.671; 8.8274
90; 92.1715; 90
1723.2Kolla, Sai Teja; Rayala, Nageswara Rao; Sridhar, Balasubramanian; Bhimapaka, China Raju
Unexpected ring opening of pyrazolines with activated alkynes: synthesis of 1<i>H</i>-pyrazole-4,5-dicarboxylates and chromenopyrazolecarboxylates.
Organic & biomolecular chemistry, 2022, 20, 334-338
7158436 CIFC30 H30 N6 O2P 21 21 217.2949; 11.9167; 14.4321
90; 90; 90
1254.6Goud, S. Banuprakash; Guin, Soumitra; Prakash, Meher; Samanta, Sampak
Cu(OAc)<sub>2</sub>/DABCO-mediated domino reaction of vinyl malononitriles with cyclic sulfamidate imines: access to 6-hydroxyaryl-2-aminonicotinonitriles.
Organic & biomolecular chemistry, 2022, 20, 352-357
7158437 CIFC25 H19 N O2P 1 21/c 111.6459; 18.2738; 8.8614
90; 98.757; 90
1863.85Jiang, Jinyuan; Liu, Jidan; Yang, Zhenke; Zheng, Jieying; Tian, Xin; Zheng, Liyao; Liu, Zhao-Qing
Rhodium(III)-catalyzed oxidative annulation of isoquinolones with allyl alcohols: synthesis of isoindolo[2,1-<i>b</i>]isoquinolin-5(7<i>H</i>)-ones.
Organic & biomolecular chemistry, 2022, 20, 339-344
7158438 CIFC37 H28 N2 O9P 1 21 18.37408; 26.0423; 13.33213
90; 94.8115; 90
2897.23Lv, Jie; Li, Zhi-Hong; Deng, An-Jun; Qin, Hai-Lin
A unified total synthesis of benzo[<i>d</i>][1,3]dioxole-type benzylisoquinoline alkaloids of aporphines, coptisines, and dibenzopyrrocolines.
Organic & biomolecular chemistry, 2022, 20, 658-666
7158439 CIFC21 H20 Cl N O6C 2 2 2111.6413; 12.8726; 25.5684
90; 90; 90
3831.52Lv, Jie; Li, Zhi-Hong; Deng, An-Jun; Qin, Hai-Lin
A unified total synthesis of benzo[<i>d</i>][1,3]dioxole-type benzylisoquinoline alkaloids of aporphines, coptisines, and dibenzopyrrocolines.
Organic & biomolecular chemistry, 2022, 20, 658-666
7158440 CIFC17 H17 Cl N2 O2P 1 21/c 110.291; 19.2325; 8.6155
90; 113.623; 90
1562.3Wang, Huai-Wei; Wu, Jia-Xue; Li, Da-Cheng; Qiao, Yu-Han; Yao, Qing-Xia; Sun, Wen-Can; Dou, Jian-Min
The synthesis of aryl-heteroaryl derivatives <i>via</i> the Rh<sup>III</sup>-catalyzed heteroarylation of arenes and heteroaromatic boronates.
Organic & biomolecular chemistry, 2022, 20, 686-693
7158441 CIFC19 H15 N3 O2 SP 1 21/n 18.5191; 10.3297; 18.8853
90; 96.6638; 90
1650.67Aggarwal, Ranjana; Hooda, Mona; Kumar, Prince; Torralba, Mari Carmen
Visible-light-mediated regioselective synthesis of novel thiazolo[3,2-<i>b</i>][1,2,4]triazoles: advantageous synthetic application of aqueous conditions.
Organic & biomolecular chemistry, 2022, 20, 584-595
7158442 CIFC29 H32 N3 OP -110.3376; 11.2041; 11.6795
80.99; 68.532; 81.497
1237.33Rai, Vishakha; P, Kavyashree; Harmalkar, Sarvesh S.; Dhuri, Sundar N.; Maddani, Mahagundappa R.
1,6-Addition of 1,2,3-NH triazoles to <i>para</i>-quinone methides: Facile access to highly selective N<sup>1</sup> and N<sup>2</sup> substituted triazoles.
Organic & biomolecular chemistry, 2022, 20, 345-351
7158443 CIFC29 H32 N3 OP 1 21/n 111.0143; 15.747; 15.541
90; 104.578; 90
2608.7Rai, Vishakha; P, Kavyashree; Harmalkar, Sarvesh S.; Dhuri, Sundar N.; Maddani, Mahagundappa R.
1,6-Addition of 1,2,3-NH triazoles to <i>para</i>-quinone methides: Facile access to highly selective N<sup>1</sup> and N<sup>2</sup> substituted triazoles.
Organic & biomolecular chemistry, 2022, 20, 345-351
7158444 CIFC18 H14 N2 O2C 1 2/c 116.6926; 6.6723; 26.1236
90; 99.22; 90
2872Zhang, Yuan; Liu, Zhiqi; Zhu, Tingyu; Huang, Ying; Fan, Weibin; Huang, Deguang
Synthesis of methylene-bridged α,β-unsaturated ketones: α-C<sub>sp<sup>3</sup></sub>-H methylenation of aromatic ketones using Selectfluor as a mild oxidant.
Organic & biomolecular chemistry, 2022, 20, 415-419
7158445 CIFC19 H16 N2 O3P 1 21/c 19.9698; 14.9389; 21.1714
90; 91.459; 90
3152.2Zhang, Yuan; Liu, Zhiqi; Zhu, Tingyu; Huang, Ying; Fan, Weibin; Huang, Deguang
Synthesis of methylene-bridged α,β-unsaturated ketones: α-C<sub>sp<sup>3</sup></sub>-H methylenation of aromatic ketones using Selectfluor as a mild oxidant.
Organic & biomolecular chemistry, 2022, 20, 415-419
7158446 CIFC17 H14 Br N O3 SeP 1 21/n 112.5541; 6.665; 20.2899
90; 103.002; 90
1654.19Zhou, Chen-Fan; Zhang, Yun-Qian; Ling, Yong; Ming, Liang; Xi, Xia; Liu, Gong-Qing; Zhang, Yanan
Time-economical synthesis of selenofunctionalized heterocycles <i>via</i> I<sub>2</sub>O<sub>5</sub>-mediated selenylative heterocyclization.
Organic & biomolecular chemistry, 2022, 20, 420-426
7158447 CIFC15 H17 N O2 S2 SeP 21 21 218.0638; 8.215; 24.112
90; 90; 90
1597.3Zhou, Chen-Fan; Zhang, Yun-Qian; Ling, Yong; Ming, Liang; Xi, Xia; Liu, Gong-Qing; Zhang, Yanan
Time-economical synthesis of selenofunctionalized heterocycles <i>via</i> I<sub>2</sub>O<sub>5</sub>-mediated selenylative heterocyclization.
Organic & biomolecular chemistry, 2022, 20, 420-426
7158448 CIFS8F d d d :210.4753; 12.8737; 24.51
90; 90; 90
3305.3Chen, Wei; Zhou, Hui; Ren, Bai-Hao; Ren, Wei-Min; Lu, Xiao-Bing
COS-triggered oxygen/sulfur exchange of isatins: chemoselective synthesis of functionalized isoindigos and spirothiopyrans <i>via</i> self-condensation and the thio-Diels-Alder reaction.
Organic & biomolecular chemistry, 2022, 20, 678-685
7158449 CIFC24 H30 N2 O2 Si2P 1 21/c 112.0825; 6.2924; 15.8782
90; 90.701; 90
1207.1Chen, Wei; Zhou, Hui; Ren, Bai-Hao; Ren, Wei-Min; Lu, Xiao-Bing
COS-triggered oxygen/sulfur exchange of isatins: chemoselective synthesis of functionalized isoindigos and spirothiopyrans <i>via</i> self-condensation and the thio-Diels-Alder reaction.
Organic & biomolecular chemistry, 2022, 20, 678-685
7158450 CIFC16 H12 N4 O2C 1 2/c 122.659; 8.6862; 15.721
90; 121.417; 90
2640.6Chen, Wei; Zhou, Hui; Ren, Bai-Hao; Ren, Wei-Min; Lu, Xiao-Bing
COS-triggered oxygen/sulfur exchange of isatins: chemoselective synthesis of functionalized isoindigos and spirothiopyrans <i>via</i> self-condensation and the thio-Diels-Alder reaction.
Organic & biomolecular chemistry, 2022, 20, 678-685
7158451 CIFC38 H56 N4 O12 S2P 1 21 111.3198; 16.1408; 12.8871
90; 112.596; 90
2173.86Choi, Sunglim; Shim, Jihyun; Kang, Philjae; Choi, Soo Hyuk
Effect of a <i>cis</i>-4-aminopiperidine-3-carboxylic acid (<i>cis</i>-APiC) residue on mixed-helical folding of unnatural peptides.
Organic & biomolecular chemistry, 2022, 20, 613-618
7158452 CIFC36 H55 Cl3 N6 O10 SP 21 21 219.6129; 16.6129; 27.4345
90; 90; 90
4381.2Choi, Sunglim; Shim, Jihyun; Kang, Philjae; Choi, Soo Hyuk
Effect of a <i>cis</i>-4-aminopiperidine-3-carboxylic acid (<i>cis</i>-APiC) residue on mixed-helical folding of unnatural peptides.
Organic & biomolecular chemistry, 2022, 20, 613-618
7158453 CIFC48 H73 N7 O9C 1 2 143.685; 10.18; 12.884
90; 103.5; 90
5571Choi, Sunglim; Shim, Jihyun; Kang, Philjae; Choi, Soo Hyuk
Effect of a <i>cis</i>-4-aminopiperidine-3-carboxylic acid (<i>cis</i>-APiC) residue on mixed-helical folding of unnatural peptides.
Organic & biomolecular chemistry, 2022, 20, 613-618
7158454 CIFC7 H0 N16 O6P 1 21/c 112.2643; 7.5844; 21.7321
90; 95.637; 90
2011.7Bakthadoss, Manickam; Mushaf, Mohammad; Agarwal, Vishal; Reddy, Tadiparthi Thirupathi; Sharada, Duddu S.
Azomethine ylide cycloaddition of 1,3-dienyl esters: highly regio- and diastereoselective synthesis of functionalized pyrrolidinochromenes.
Organic & biomolecular chemistry, 2022, 20, 778-782
7158455 CIFC56 H46 O6P -19.6823; 10.4434; 11.6367
82.076; 78.416; 65.109
1043.73Araujo Dias, Antônio Junio; Takahashi, Hiroto; Nogami, Juntaro; Nagashima, Yuki; Tanaka, Ken
Oxidative [4 + 2] annulation of 1-naphthols with alkynes accelerated by an electron-deficient rhodium(III) catalysts.
Organic & biomolecular chemistry, 2022, 20, 1008-1012
7158456 CIFC25 H23 F3 N O3.5 S2P -19.1139; 11.7059; 12.6851
109.356; 100.318; 106.611
1166.1Santiago, Carlos; Jiménez-Aberasturi, Xabier; Leicea, Eztizen; Lete, Marta G.; Sotomayor, Nuria; Lete, Esther
Microwave-assisted palladium catalysed C-H acylation with aldehydes: synthesis and diversification of 3-acylthiophenes.
Organic & biomolecular chemistry, 2022, 20, 852-861
7158457 CIFC20 H20 Cl N SiP -18.4528; 10.0726; 11.6966
77.56; 75.781; 68.597
890.01Cembellín, Sara; Maisuls, Iván; Daniliuc, Constantin G.; Osthues, Helena; Doltsinis, Nikos L.; Strassert, Cristian A.; Glorius, Frank
One-step synthesis of indolizino[3,4,5-<i>ab</i>]isoindoles by manganese(I)-catalyzed C-H activation: structural studies and photophysical properties.
Organic & biomolecular chemistry, 2022, 20, 796-800
7158458 CIFC37 H27 Br F3 N5 O5P 21 21 219.7153; 14.2963; 24.322
90; 90; 90
3378.2Li, Tong-Hao; Du, Da-Ming
Asymmetric synthesis of isoxazole and trifluoromethyl-containing 3,2'-pyrrolidinyl dispirooxindoles <i>via</i> squaramide-catalysed [3 + 2] cycloaddition reactions.
Organic & biomolecular chemistry, 2022, 20, 817-823
7158459 CIFC20 H22 O8P 1 21 114.1584; 4.6034; 14.9562
90; 113.249; 90
895.64Peng, Xiaogang; Zhou, Shuang; Liu, Junjun; Gao, Ying; Chang, Jinling; Ruan, Hanli
(±)-Usphenethylones A-C, three pairs of heterodimeric polyketide enantiomers from <i>Aspergillus ustus</i> 3.3904.
Organic & biomolecular chemistry, 2022, 20, 694-700
7158460 CIFC21 H22 O8P 21 21 214.5507; 17.161; 48.011
90; 90; 90
3749.4Peng, Xiaogang; Zhou, Shuang; Liu, Junjun; Gao, Ying; Chang, Jinling; Ruan, Hanli
(±)-Usphenethylones A-C, three pairs of heterodimeric polyketide enantiomers from <i>Aspergillus ustus</i> 3.3904.
Organic & biomolecular chemistry, 2022, 20, 694-700
7158461 CIFC20 H22 O8P 1 21 114.126; 4.5761; 14.955
90; 113.28; 90
888Peng, Xiaogang; Zhou, Shuang; Liu, Junjun; Gao, Ying; Chang, Jinling; Ruan, Hanli
(±)-Usphenethylones A-C, three pairs of heterodimeric polyketide enantiomers from <i>Aspergillus ustus</i> 3.3904.
Organic & biomolecular chemistry, 2022, 20, 694-700
7158462 CIFC20 H24 O6P 1 21 18.5427; 15.2194; 14.1219
90; 91.418; 90
1835.49Peng, Xiaogang; Zhou, Shuang; Liu, Junjun; Gao, Ying; Chang, Jinling; Ruan, Hanli
(±)-Usphenethylones A-C, three pairs of heterodimeric polyketide enantiomers from <i>Aspergillus ustus</i> 3.3904.
Organic & biomolecular chemistry, 2022, 20, 694-700
7158463 CIFC42 H44 O16P 21 21 214.5505; 17.1723; 48.042
90; 90; 90
3754.1Peng, Xiaogang; Zhou, Shuang; Liu, Junjun; Gao, Ying; Chang, Jinling; Ruan, Hanli
(±)-Usphenethylones A-C, three pairs of heterodimeric polyketide enantiomers from <i>Aspergillus ustus</i> 3.3904.
Organic & biomolecular chemistry, 2022, 20, 694-700
7158464 CIFC20 H20 O7P 1 21/c 113.66489; 15.50084; 8.21733
90; 102.58; 90
1698.79Peng, Xiaogang; Zhou, Shuang; Liu, Junjun; Gao, Ying; Chang, Jinling; Ruan, Hanli
(±)-Usphenethylones A-C, three pairs of heterodimeric polyketide enantiomers from <i>Aspergillus ustus</i> 3.3904.
Organic & biomolecular chemistry, 2022, 20, 694-700
7158465 CIFC20 H24 O6P 21 21 218.6051; 14.1919; 15.2989
90; 90; 90
1868.34Peng, Xiaogang; Zhou, Shuang; Liu, Junjun; Gao, Ying; Chang, Jinling; Ruan, Hanli
(±)-Usphenethylones A-C, three pairs of heterodimeric polyketide enantiomers from <i>Aspergillus ustus</i> 3.3904.
Organic & biomolecular chemistry, 2022, 20, 694-700
7158466 CIFC21 H22 O8P -14.53147; 14.6487; 28.5217
85.4988; 85.95; 88.2776
1882.15Peng, Xiaogang; Zhou, Shuang; Liu, Junjun; Gao, Ying; Chang, Jinling; Ruan, Hanli
(±)-Usphenethylones A-C, three pairs of heterodimeric polyketide enantiomers from <i>Aspergillus ustus</i> 3.3904.
Organic & biomolecular chemistry, 2022, 20, 694-700
7158467 CIFC48.8 H99.2 N12 O33.4 S6.2P 21 21 2114.793; 17.86; 26.56
90; 90; 90
7017Fedorowicz, Dominika; Banach, Sylwia; Koza, Patrycja; Frydrych, Rafał; Ślepokura, Katarzyna; Gregoliński, Janusz
Controlling chirality in the synthesis of 4 + 4 diastereomeric amine macrocycles derived from <i>trans</i>-1,2-diaminocyclopentane and 2,6-diformylpyridine.
Organic & biomolecular chemistry, 2022, 20, 1080-1094
7158468 CIFC48 H94 Cl8 N12 O9P 112.441; 12.772; 20.693
75.36; 79.83; 89.7
3128.6Fedorowicz, Dominika; Banach, Sylwia; Koza, Patrycja; Frydrych, Rafał; Ślepokura, Katarzyna; Gregoliński, Janusz
Controlling chirality in the synthesis of 4 + 4 diastereomeric amine macrocycles derived from <i>trans</i>-1,2-diaminocyclopentane and 2,6-diformylpyridine.
Organic & biomolecular chemistry, 2022, 20, 1080-1094

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