Crystallography Open Database

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4079665 CIFC29 H31 P TiP -19.5814; 10.8494; 12.35
101.232; 92.962; 110.184
1172Tagne Kuate, Alain C.; Mohapatra, Swagat K.; Daniliuc, Constantin G.; Jones, Peter G.; Tamm, Matthias
Mono- and Dilithiation of [(η7-C7H7)Ti(η5-C5Me5)] (Pentamethyltroticene) for the Synthesis of Troticenyl Monophosphanes and [2]Troticenophanes with C‒P and C‒Si Bridges
Organometallics, 2012, 31, 8544
4079666 CIFC23 H25 P TiP 1 21/n 18.6945; 16.3391; 13.1992
90; 99.481; 90
1849.47Tagne Kuate, Alain C.; Mohapatra, Swagat K.; Daniliuc, Constantin G.; Jones, Peter G.; Tamm, Matthias
Mono- and Dilithiation of [(η7-C7H7)Ti(η5-C5Me5)] (Pentamethyltroticene) for the Synthesis of Troticenyl Monophosphanes and [2]Troticenophanes with C‒P and C‒Si Bridges
Organometallics, 2012, 31, 8544
4079667 CIFC29 H38 P TiP -111.1956; 11.2091; 11.5927
102.585; 99.292; 116.434
1214.5Tagne Kuate, Alain C.; Mohapatra, Swagat K.; Daniliuc, Constantin G.; Jones, Peter G.; Tamm, Matthias
Mono- and Dilithiation of [(η7-C7H7)Ti(η5-C5Me5)] (Pentamethyltroticene) for the Synthesis of Troticenyl Monophosphanes and [2]Troticenophanes with C‒P and C‒Si Bridges
Organometallics, 2012, 31, 8544
4079668 CIFC23 H26 Cl P TiP 21 21 218.8646; 11.268; 20.0673
90; 90; 90
2004.45Tagne Kuate, Alain C.; Mohapatra, Swagat K.; Daniliuc, Constantin G.; Jones, Peter G.; Tamm, Matthias
Mono- and Dilithiation of [(η7-C7H7)Ti(η5-C5Me5)] (Pentamethyltroticene) for the Synthesis of Troticenyl Monophosphanes and [2]Troticenophanes with C‒P and C‒Si Bridges
Organometallics, 2012, 31, 8544
4079669 CIFC19 H26 Si TiP 1 21/c 114.2913; 11.3559; 10.8545
90; 98.416; 90
1742.61Tagne Kuate, Alain C.; Mohapatra, Swagat K.; Daniliuc, Constantin G.; Jones, Peter G.; Tamm, Matthias
Mono- and Dilithiation of [(η7-C7H7)Ti(η5-C5Me5)] (Pentamethyltroticene) for the Synthesis of Troticenyl Monophosphanes and [2]Troticenophanes with C‒P and C‒Si Bridges
Organometallics, 2012, 31, 8544
4079670 CIFC34 H31 Mo O5 P TiP 1 21/n 117.731; 9.0707; 20.6103
90; 111.788; 90
3078Tagne Kuate, Alain C.; Mohapatra, Swagat K.; Daniliuc, Constantin G.; Jones, Peter G.; Tamm, Matthias
Mono- and Dilithiation of [(η7-C7H7)Ti(η5-C5Me5)] (Pentamethyltroticene) for the Synthesis of Troticenyl Monophosphanes and [2]Troticenophanes with C‒P and C‒Si Bridges
Organometallics, 2012, 31, 8544
4079671 CIFC29 H31 Au Cl P TiP -19.8908; 10.7751; 14.1037
71.701; 73.907; 65.681
1281.31Tagne Kuate, Alain C.; Mohapatra, Swagat K.; Daniliuc, Constantin G.; Jones, Peter G.; Tamm, Matthias
Mono- and Dilithiation of [(η7-C7H7)Ti(η5-C5Me5)] (Pentamethyltroticene) for the Synthesis of Troticenyl Monophosphanes and [2]Troticenophanes with C‒P and C‒Si Bridges
Organometallics, 2012, 31, 8544
4079672 CIFC23 H26 TiP 1 21/n 116.4511; 9.0162; 24.5164
90; 91.091; 90
3635.77Tagne Kuate, Alain C.; Mohapatra, Swagat K.; Daniliuc, Constantin G.; Jones, Peter G.; Tamm, Matthias
Mono- and Dilithiation of [(η7-C7H7)Ti(η5-C5Me5)] (Pentamethyltroticene) for the Synthesis of Troticenyl Monophosphanes and [2]Troticenophanes with C‒P and C‒Si Bridges
Organometallics, 2012, 31, 8544
4079673 CIFC29 H32 Ti2P 21 21 2111.1827; 14.1389; 14.6759
90; 90; 90
2320.42Tagne Kuate, Alain C.; Mohapatra, Swagat K.; Daniliuc, Constantin G.; Jones, Peter G.; Tamm, Matthias
Mono- and Dilithiation of [(η7-C7H7)Ti(η5-C5Me5)] (Pentamethyltroticene) for the Synthesis of Troticenyl Monophosphanes and [2]Troticenophanes with C‒P and C‒Si Bridges
Organometallics, 2012, 31, 8544
4079674 CIFC13 H18 Br NP 1 21 113.1828; 7.6142; 13.2748
90; 107.163; 90
1273.14García-López, José-Antonio; Saura-Llamas, Isabel; McGrady, John E.; Bautista, Delia; Vicente, José
Insertion of Allenes into the Pd‒C Bond of Ortho-Palladated Primary Arylamines of Biological Relevance: Phenethylamine, Phentermine, (l)-Phenylalanine Methyl Ester, and (l)-Tryptophan Methyl Ester. Synthesis of Tetrahydro-3-benzazepines and Their Salts
Organometallics, 2012, 31, 8333
4079675 CIFC16 H22 F3 N O3 SP -18.8614; 8.8975; 11.555
106.489; 90.801; 102.59
849.77García-López, José-Antonio; Saura-Llamas, Isabel; McGrady, John E.; Bautista, Delia; Vicente, José
Insertion of Allenes into the Pd‒C Bond of Ortho-Palladated Primary Arylamines of Biological Relevance: Phenethylamine, Phentermine, (l)-Phenylalanine Methyl Ester, and (l)-Tryptophan Methyl Ester. Synthesis of Tetrahydro-3-benzazepines and Their Salts
Organometallics, 2012, 31, 8333
4079676 CIFC16 H24 F3 N O3 S SiC 1 2/c 118.0459; 8.6262; 24.7215
90; 92.086; 90
3845.8García-López, José-Antonio; Saura-Llamas, Isabel; McGrady, John E.; Bautista, Delia; Vicente, José
Insertion of Allenes into the Pd‒C Bond of Ortho-Palladated Primary Arylamines of Biological Relevance: Phenethylamine, Phentermine, (l)-Phenylalanine Methyl Ester, and (l)-Tryptophan Methyl Ester. Synthesis of Tetrahydro-3-benzazepines and Their Salts
Organometallics, 2012, 31, 8333
4079677 CIFC18 H30 Cl3 N SiP 1 21/n 112.6524; 9.421; 18.1857
90; 90.093; 90
2167.7García-López, José-Antonio; Saura-Llamas, Isabel; McGrady, John E.; Bautista, Delia; Vicente, José
Insertion of Allenes into the Pd‒C Bond of Ortho-Palladated Primary Arylamines of Biological Relevance: Phenethylamine, Phentermine, (l)-Phenylalanine Methyl Ester, and (l)-Tryptophan Methyl Ester. Synthesis of Tetrahydro-3-benzazepines and Their Salts
Organometallics, 2012, 31, 8333
4079678 CIFC26 H26 F3 N O3 SP -19.7698; 10.8203; 12.2565
110.776; 91.712; 98.572
1193.07García-López, José-Antonio; Saura-Llamas, Isabel; McGrady, John E.; Bautista, Delia; Vicente, José
Insertion of Allenes into the Pd‒C Bond of Ortho-Palladated Primary Arylamines of Biological Relevance: Phenethylamine, Phentermine, (l)-Phenylalanine Methyl Ester, and (l)-Tryptophan Methyl Ester. Synthesis of Tetrahydro-3-benzazepines and Their Salts
Organometallics, 2012, 31, 8333
4079679 CIFC13 H18 Br N OP 21 21 216.2731; 7.8393; 27.5628
90; 90; 90
1355.45García-López, José-Antonio; Saura-Llamas, Isabel; McGrady, John E.; Bautista, Delia; Vicente, José
Insertion of Allenes into the Pd‒C Bond of Ortho-Palladated Primary Arylamines of Biological Relevance: Phenethylamine, Phentermine, (l)-Phenylalanine Methyl Ester, and (l)-Tryptophan Methyl Ester. Synthesis of Tetrahydro-3-benzazepines and Their Salts
Organometallics, 2012, 31, 8333
4079680 CIFC53 H38 Cl2 N8 O20 Ru6P 1 21/n 118.1595; 16.0778; 21.4623
90; 108.734; 90
5934.25Cabeza, Javier A.; Damonte, Marina; Pérez-Carreño, Enrique
Reactivity of a Bis(N-heterocyclic carbene) with Ruthenium Carbonyl. Synthesis of Mono- and Trinuclear Derivatives and Ligand Modification via C‒H Bond Activation
Organometallics, 2012, 31, 8355
4079681 CIFC24 H18 N4 O8 Ru3P 1 21/c 113.7947; 8.3567; 22.6665
90; 97.733; 90
2589.19Cabeza, Javier A.; Damonte, Marina; Pérez-Carreño, Enrique
Reactivity of a Bis(N-heterocyclic carbene) with Ruthenium Carbonyl. Synthesis of Mono- and Trinuclear Derivatives and Ligand Modification via C‒H Bond Activation
Organometallics, 2012, 31, 8355
4079682 CIFC68 H82 Cr2P c a 2117.0108; 19.7941; 16.8614
90; 90; 90
5677.5Boynton, Jessica N.; Summerscales, Owen T.; Grandjean, Fernande; Long, Gary J.; Fettinger, James C.; Power, Philip P.
Structural and Magnetic Studies of a Quasi-Inverse Sandwich Cyclooctatetraene Complex with Two High-Spin Chromium(II) Ions Bound Anti-Facially
Organometallics, 2012, 31, 8556
4079683 CIFC12 H Cl3 Fe2 O6 S2P -17.5788; 8.8191; 14.7063
88.938; 80.939; 64.881
877.59Donovan, Elizabeth S.; McCormick, Joseph J.; Nichol, Gary S.; Felton, Greg A. N.
Cyclic Voltammetric Studies of Chlorine-Substituted Diiron Benzenedithiolato Hexacarbonyl Electrocatalysts Inspired by the [FeFe]-Hydrogenase Active Site
Organometallics, 2012, 31, 8067
4079684 CIFC12 Cl4 Fe2 O6 S2P -17.6077; 8.8047; 14.9168
82.808; 80.371; 65.763
896.49Donovan, Elizabeth S.; McCormick, Joseph J.; Nichol, Gary S.; Felton, Greg A. N.
Cyclic Voltammetric Studies of Chlorine-Substituted Diiron Benzenedithiolato Hexacarbonyl Electrocatalysts Inspired by the [FeFe]-Hydrogenase Active Site
Organometallics, 2012, 31, 8067
4079685 CIFC82.5 H104 Br4 N12 Zr2P -19.572; 17.2005; 26.67
103.345; 93.393; 95.516
4237.6Fernández-Galán, Rafael; Antiñolo, Antonio; Carrillo-Hermosilla, Fernando; López-Solera, Isabel; Otero, Antonio; Serrano-Laguna, Amparo; Villaseñor, Elena
Migratory Insertion Reactions in Asymmetrical Guanidinate-Supported Zirconium Complexes
Organometallics, 2012, 31, 8360
4079686 CIFC18 H40 Cl2 N6 ZrP 1 21/n 114.4783; 12.1346; 15.9903
90; 116.397; 90
2516.4Fernández-Galán, Rafael; Antiñolo, Antonio; Carrillo-Hermosilla, Fernando; López-Solera, Isabel; Otero, Antonio; Serrano-Laguna, Amparo; Villaseñor, Elena
Migratory Insertion Reactions in Asymmetrical Guanidinate-Supported Zirconium Complexes
Organometallics, 2012, 31, 8360
4079687 CIFC64 H88 N8 ZrP -111.8113; 16.1538; 16.9957
72.863; 79.891; 75.84
2985.8Fernández-Galán, Rafael; Antiñolo, Antonio; Carrillo-Hermosilla, Fernando; López-Solera, Isabel; Otero, Antonio; Serrano-Laguna, Amparo; Villaseñor, Elena
Migratory Insertion Reactions in Asymmetrical Guanidinate-Supported Zirconium Complexes
Organometallics, 2012, 31, 8360
4079688 CIFC54 H51 N3 Si ZrP -111.241; 13.366; 18.174
93.24; 104.97; 109.65
2453.3Zhao, Jing; Zhang, Shaoguang; Zhang, Wen-Xiong; Xi, Zhenfeng
Reactivity of Seven-Membered Azazirconacycloallenes and Four-Membered Zirconacycles toward Diphenylacetonitrile
Organometallics, 2012, 31, 8370
4079689 CIFC40 H41 Br N2 Si ZrC 1 2/c 136.131; 10.712; 19.949
90; 100; 90
7604Zhao, Jing; Zhang, Shaoguang; Zhang, Wen-Xiong; Xi, Zhenfeng
Reactivity of Seven-Membered Azazirconacycloallenes and Four-Membered Zirconacycles toward Diphenylacetonitrile
Organometallics, 2012, 31, 8370
4079690 CIFC40 H41 Cl N2 Si ZrC 1 2/c 136.3; 10.477; 20.048
90; 101.69; 90
7466Zhao, Jing; Zhang, Shaoguang; Zhang, Wen-Xiong; Xi, Zhenfeng
Reactivity of Seven-Membered Azazirconacycloallenes and Four-Membered Zirconacycles toward Diphenylacetonitrile
Organometallics, 2012, 31, 8370
4079691 CIFC56 H48 N2 Si ZrC 1 2/c 128.747; 14.691; 22.158
90; 102.019; 90
9153Zhao, Jing; Zhang, Shaoguang; Zhang, Wen-Xiong; Xi, Zhenfeng
Reactivity of Seven-Membered Azazirconacycloallenes and Four-Membered Zirconacycles toward Diphenylacetonitrile
Organometallics, 2012, 31, 8370
4079692 CIFC24 H22 O2 TiP 1 21/n 113.325; 9.454; 14.545
90; 92.884; 90
1830Desnoyer, Addison N.; Fartel, Beata; MacLeod, K. Cory; Patrick, Brian O.; Smith, Kevin M.
Ambient-Temperature Carbon‒Oxygen Bond Cleavage of an α-Aryloxy Ketone with Cp2Ti(BTMSA) and Selective Protonolysis of the Resulting Ti‒OR Bonds
Organometallics, 2012, 31, 7625
4079693 CIFC24 H23 Cl O2 TiP -19.132; 13.5283; 16.404
88.597; 83.995; 85.32
2008.5Desnoyer, Addison N.; Fartel, Beata; MacLeod, K. Cory; Patrick, Brian O.; Smith, Kevin M.
Ambient-Temperature Carbon‒Oxygen Bond Cleavage of an α-Aryloxy Ketone with Cp2Ti(BTMSA) and Selective Protonolysis of the Resulting Ti‒OR Bonds
Organometallics, 2012, 31, 7625
4079694 CIFC30 H28 Cl2 ZrP -18.738; 9.139; 17.4282
97.261; 103.816; 96.412
1326.03Bader, Manuela; Marquet, Nicolas; Kirillov, Evgeny; Roisnel, Thierry; Razavi, Abbas; Lhost, Olivier; Carpentier, Jean-François
Old and NewC1-Symmetric Group 4 Metallocenes {(R1R2C)-(R2′R3′R6′R7′-Flu)(3-R3-5-R4-C5H2)}ZrCl2: From Highly Isotactic Polypropylenes to Vinyl End-Capped Isotactic-Enriched Oligomers
Organometallics, 2012, 31, 8375
4079695 CIFC39 H46 Cl2 ZrP 1 21/n 111.8432; 16.4959; 17.1659
90; 92.766; 90
3349.7Bader, Manuela; Marquet, Nicolas; Kirillov, Evgeny; Roisnel, Thierry; Razavi, Abbas; Lhost, Olivier; Carpentier, Jean-François
Old and NewC1-Symmetric Group 4 Metallocenes {(R1R2C)-(R2′R3′R6′R7′-Flu)(3-R3-5-R4-C5H2)}ZrCl2: From Highly Isotactic Polypropylenes to Vinyl End-Capped Isotactic-Enriched Oligomers
Organometallics, 2012, 31, 8375
4079696 CIFC43 H46 Cl2 ZrP -110.9477; 11.8652; 15.2718
77; 75.093; 78.461
1846.45Bader, Manuela; Marquet, Nicolas; Kirillov, Evgeny; Roisnel, Thierry; Razavi, Abbas; Lhost, Olivier; Carpentier, Jean-François
Old and NewC1-Symmetric Group 4 Metallocenes {(R1R2C)-(R2′R3′R6′R7′-Flu)(3-R3-5-R4-C5H2)}ZrCl2: From Highly Isotactic Polypropylenes to Vinyl End-Capped Isotactic-Enriched Oligomers
Organometallics, 2012, 31, 8375
4079697 CIFC44 H58 Cl2 ZrP b c a11.551; 24.178; 28.816
90; 90; 90
8048Bader, Manuela; Marquet, Nicolas; Kirillov, Evgeny; Roisnel, Thierry; Razavi, Abbas; Lhost, Olivier; Carpentier, Jean-François
Old and NewC1-Symmetric Group 4 Metallocenes {(R1R2C)-(R2′R3′R6′R7′-Flu)(3-R3-5-R4-C5H2)}ZrCl2: From Highly Isotactic Polypropylenes to Vinyl End-Capped Isotactic-Enriched Oligomers
Organometallics, 2012, 31, 8375
4079698 CIFC46 H56 Cl2 ZrP -111.8504; 13.2311; 25.354
93.974; 92.762; 96.535
3933.7Bader, Manuela; Marquet, Nicolas; Kirillov, Evgeny; Roisnel, Thierry; Razavi, Abbas; Lhost, Olivier; Carpentier, Jean-François
Old and NewC1-Symmetric Group 4 Metallocenes {(R1R2C)-(R2′R3′R6′R7′-Flu)(3-R3-5-R4-C5H2)}ZrCl2: From Highly Isotactic Polypropylenes to Vinyl End-Capped Isotactic-Enriched Oligomers
Organometallics, 2012, 31, 8375
4079699 CIFC47 H56 Cl2 ZrP 1 21/c 19.8463; 14.0657; 29.101
90; 91.551; 90
4028.9Bader, Manuela; Marquet, Nicolas; Kirillov, Evgeny; Roisnel, Thierry; Razavi, Abbas; Lhost, Olivier; Carpentier, Jean-François
Old and NewC1-Symmetric Group 4 Metallocenes {(R1R2C)-(R2′R3′R6′R7′-Flu)(3-R3-5-R4-C5H2)}ZrCl2: From Highly Isotactic Polypropylenes to Vinyl End-Capped Isotactic-Enriched Oligomers
Organometallics, 2012, 31, 8375
4079700 CIFC30 H36 Cl2 ZrP -18.9402; 12.2725; 13.4389
117.094; 91.79; 90.006
1311.9Bader, Manuela; Marquet, Nicolas; Kirillov, Evgeny; Roisnel, Thierry; Razavi, Abbas; Lhost, Olivier; Carpentier, Jean-François
Old and NewC1-Symmetric Group 4 Metallocenes {(R1R2C)-(R2′R3′R6′R7′-Flu)(3-R3-5-R4-C5H2)}ZrCl2: From Highly Isotactic Polypropylenes to Vinyl End-Capped Isotactic-Enriched Oligomers
Organometallics, 2012, 31, 8375
4079701 CIFC42 H42 F12 N12 P2 RuP -111.887; 14.052; 14.801
78.24; 78.94; 84.63
2371.6Yang, Wen-Wen; Yao, Jiannian; Zhong, Yu-Wu
Redox-Asymmetric Bisruthenium Complex Bridged by a Pyridin-4-yl Moiety: Synthesis, Characterization, and Electronic Coupling Studies
Organometallics, 2012, 31, 8577
4079702 CIFC34 H32 O9 P2 Pd S2P 1 21/c 112.1796; 15.548; 21.1054
90; 117.902; 90
3532.1R Thomas; Tritschler, Ulrich; Roesle, Philipp; Göttker-Schnetmann, Inigo; Müller, Heiko M.; Caporaso, Lucia; Poater, Albert; Cavallo, Luigi; Mecking, Stefan
Activation and Deactivation of Neutral Palladium(II) Phosphinesulfonato Polymerization Catalysts
Organometallics, 2012, 31, 8388
4079703 CIFC48 H44 Cl16 O10 P2 Pd S2C 1 2/c 125.0992; 11.8473; 21.5097
90; 99.928; 90
6300.3R Thomas; Tritschler, Ulrich; Roesle, Philipp; Göttker-Schnetmann, Inigo; Müller, Heiko M.; Caporaso, Lucia; Poater, Albert; Cavallo, Luigi; Mecking, Stefan
Activation and Deactivation of Neutral Palladium(II) Phosphinesulfonato Polymerization Catalysts
Organometallics, 2012, 31, 8388
4079704 CIFC36 H36 O9 P2 Pd S2C 1 2/c 118.1536; 11.6821; 34.931
90; 99.484; 90
7306.6R Thomas; Tritschler, Ulrich; Roesle, Philipp; Göttker-Schnetmann, Inigo; Müller, Heiko M.; Caporaso, Lucia; Poater, Albert; Cavallo, Luigi; Mecking, Stefan
Activation and Deactivation of Neutral Palladium(II) Phosphinesulfonato Polymerization Catalysts
Organometallics, 2012, 31, 8388
4079705 CIFC35 H49 O5 P2 Pd SP -19.5966; 12.0664; 15.6496
92.336; 100.896; 96.725
1763.6R Thomas; Tritschler, Ulrich; Roesle, Philipp; Göttker-Schnetmann, Inigo; Müller, Heiko M.; Caporaso, Lucia; Poater, Albert; Cavallo, Luigi; Mecking, Stefan
Activation and Deactivation of Neutral Palladium(II) Phosphinesulfonato Polymerization Catalysts
Organometallics, 2012, 31, 8388
4079706 CIFC30.25 H29.5 Cl1.5 N P PtP 1 21 113.1277; 13.6566; 15.6227
90; 106.332; 90
2687.82Tan, Kien-Wee; Yang, Xiang-Yuan; Li, Yongxin; Huang, Yinhua; Pullarkat, Sumod A.; Leung, Pak-Hing
Reactivity of Cycloplatinated Amine Complexes: Intramolecular C‒C Bond Formation, C‒H Activation, and PPh2Migration in Coordinated Alkynylphosphines
Organometallics, 2012, 31, 8407
4079707 CIFC30 H29 Cl N P PtP 19.5284; 10.4146; 14.4364
81.314; 74.581; 66.956
1269.05Tan, Kien-Wee; Yang, Xiang-Yuan; Li, Yongxin; Huang, Yinhua; Pullarkat, Sumod A.; Leung, Pak-Hing
Reactivity of Cycloplatinated Amine Complexes: Intramolecular C‒C Bond Formation, C‒H Activation, and PPh2Migration in Coordinated Alkynylphosphines
Organometallics, 2012, 31, 8407
4079708 CIFC25 H26 Cl N3 RuP 1 21/n 17.8961; 23.6603; 11.7411
90; 94.654; 90
2186.29Donnelly, Kate F.; Lalrempuia, Ralte; Müller-Bunz, Helge; Albrecht, Martin
Regioselective Electrophilic C‒H Bond Activation in Triazolylidene Metal Complexes Containing a N-Bound Phenyl Substituent
Organometallics, 2012, 31, 8414
4079709 CIFC25 H27 Cl0.878 I0.122 Ir N3P 1 21/c 114.2329; 11.8731; 13.7233
90; 93.932; 90
2313.62Donnelly, Kate F.; Lalrempuia, Ralte; Müller-Bunz, Helge; Albrecht, Martin
Regioselective Electrophilic C‒H Bond Activation in Triazolylidene Metal Complexes Containing a N-Bound Phenyl Substituent
Organometallics, 2012, 31, 8414
4079710 CIFC47 H51 Cl5 F12 N6 P2 Pt2C 1 2/c 113.9629; 14.5367; 26.3152
90; 97.6443; 90
5293.85Donnelly, Kate F.; Lalrempuia, Ralte; Müller-Bunz, Helge; Albrecht, Martin
Regioselective Electrophilic C‒H Bond Activation in Triazolylidene Metal Complexes Containing a N-Bound Phenyl Substituent
Organometallics, 2012, 31, 8414
4079711 CIFC23 H25 Cl N3 RhP -17.6878; 9.0852; 15.2939
104.585; 93.0047; 100.758
1010.05Donnelly, Kate F.; Lalrempuia, Ralte; Müller-Bunz, Helge; Albrecht, Martin
Regioselective Electrophilic C‒H Bond Activation in Triazolylidene Metal Complexes Containing a N-Bound Phenyl Substituent
Organometallics, 2012, 31, 8414
4079712 CIFC46 H51 N2 P2 RhP 1 21/n 112.259; 18.413; 18.183
90; 99.087; 90
4052.85Segarra, Candela; Mas-Marz Elena; Lowe, John P.; Mahon, Mary F.; Poulten, Rebecca C.; Whittlesey, Michael K.
Ring-Expanded N-Heterocyclic Carbene Complexes of Rhodium with Bifluoride, Fluoride, and Fluoroaryl Ligands
Organometallics, 2012, 31, 8584
4079713 CIFC49 H58 F2 N2 P2 RhP -110.7914; 11.689; 18.7289
75.783; 86.843; 70.878
2162.93Segarra, Candela; Mas-Marz Elena; Lowe, John P.; Mahon, Mary F.; Poulten, Rebecca C.; Whittlesey, Michael K.
Ring-Expanded N-Heterocyclic Carbene Complexes of Rhodium with Bifluoride, Fluoride, and Fluoroaryl Ligands
Organometallics, 2012, 31, 8584
4079714 CIFC49 H53 F N2 P2 RhP -110.741; 11.606; 18.813
74.523; 88.812; 69.969
2116.98Segarra, Candela; Mas-Marz Elena; Lowe, John P.; Mahon, Mary F.; Poulten, Rebecca C.; Whittlesey, Michael K.
Ring-Expanded N-Heterocyclic Carbene Complexes of Rhodium with Bifluoride, Fluoride, and Fluoroaryl Ligands
Organometallics, 2012, 31, 8584
4079715 CIFC58 H56 F5 N2 P2 RhP 1 21/c 110.498; 20.74; 23.255
90; 99.073; 90
4999.93Segarra, Candela; Mas-Marz Elena; Lowe, John P.; Mahon, Mary F.; Poulten, Rebecca C.; Whittlesey, Michael K.
Ring-Expanded N-Heterocyclic Carbene Complexes of Rhodium with Bifluoride, Fluoride, and Fluoroaryl Ligands
Organometallics, 2012, 31, 8584
4079716 CIFC41 H43.96 Br0.04 N2 O P RhC 1 2/c 138.65; 9.329; 20.091
90; 99.36; 90
7147.7Segarra, Candela; Mas-Marz Elena; Lowe, John P.; Mahon, Mary F.; Poulten, Rebecca C.; Whittlesey, Michael K.
Ring-Expanded N-Heterocyclic Carbene Complexes of Rhodium with Bifluoride, Fluoride, and Fluoroaryl Ligands
Organometallics, 2012, 31, 8584
4079717 CIFC68 H70.5 N8 O1.25 Ru2 S12P -110.74; 17.988; 18.789
92.293; 92.391; 90.34
3623.7Cai, Xu-Min; Zhang, Xiang-Yi; Savchenko, Julia; Cao, Zhi; Ren, Tong; Zuo, Jing-Lin
New Linear π-Conjugated Diruthenium Compounds Containing Axial Tetrathiafulvalene-acetylide Ligands
Organometallics, 2012, 31, 8591
4079718 CIFC22 H20 Br2P 1 21/c 18.9815; 7.5601; 14.071
90; 106.058; 90
918.16Januszewski, Estera; Bolte, Michael; Lerner, Hans-Wolfram; Wagner, Matthias
Influence of the Bridging Elements on the Optical Properties of Linked 9,10-Dihydro-9,10-diboraanthracenes
Organometallics, 2012, 31, 8420
4079719 CIFC28 H24 Br2C 1 2/c 121.0472; 9.0583; 24.9332
90; 104.727; 90
4597.4Januszewski, Estera; Bolte, Michael; Lerner, Hans-Wolfram; Wagner, Matthias
Influence of the Bridging Elements on the Optical Properties of Linked 9,10-Dihydro-9,10-diboraanthracenes
Organometallics, 2012, 31, 8420
4079720 CIFC34 H52 Cl N3 Si2P -110.115; 16.201; 22.21
93.009; 90.754; 97.067
3606Cui, Haiyan; Ma, Bing; Cui, Chunming
Metal-Free, Stereospecific Bis-Silylation of Functionalized Alkynes with NHC-Supported Silylaminosilylene
Organometallics, 2012, 31, 7339
4079721 CIFC34 H52 Cl N3 Si2P 1 21/c 19.011; 20.22; 19.411
90; 96.957; 90
3511Cui, Haiyan; Ma, Bing; Cui, Chunming
Metal-Free, Stereospecific Bis-Silylation of Functionalized Alkynes with NHC-Supported Silylaminosilylene
Organometallics, 2012, 31, 7339
4079722 CIFC40 H56 Cl N3 Si2P -110.483; 10.8; 19.839
91.576; 90.342; 109.762
2112.7Cui, Haiyan; Ma, Bing; Cui, Chunming
Metal-Free, Stereospecific Bis-Silylation of Functionalized Alkynes with NHC-Supported Silylaminosilylene
Organometallics, 2012, 31, 7339
4079723 CIFC36 H54 Cl N3 O2 Si2P -110.588; 10.827; 19.271
77.452; 82.016; 70.643
2029.1Cui, Haiyan; Ma, Bing; Cui, Chunming
Metal-Free, Stereospecific Bis-Silylation of Functionalized Alkynes with NHC-Supported Silylaminosilylene
Organometallics, 2012, 31, 7339
4079724 CIFC30 H50 Cl N3 O2 Si2P n a 2116.981; 15.637; 12.337
90; 90; 90
3275.9Cui, Haiyan; Ma, Bing; Cui, Chunming
Metal-Free, Stereospecific Bis-Silylation of Functionalized Alkynes with NHC-Supported Silylaminosilylene
Organometallics, 2012, 31, 7339
4079725 CIFC33 H51 Cl N4 Si2P -19.6398; 18.262; 21.578
75.184; 78.245; 84.203
3590.5Cui, Haiyan; Ma, Bing; Cui, Chunming
Metal-Free, Stereospecific Bis-Silylation of Functionalized Alkynes with NHC-Supported Silylaminosilylene
Organometallics, 2012, 31, 7339
4079726 CIFC46 H51 N5 SiP 1 21/n 111.129; 16.631; 21.272
90; 98.68; 90
3892Azhakar, Ramachandran; Roesky, Herbert W.; Wolf, Hilke; Stalke, Dietmar
Reactivity of Stable Heteroleptic Silylene PhC(NtBu)2SiNPh2toward Diazobenzene andN-Benzylidineaniline
Organometallics, 2012, 31, 8608
4079727 CIFC40 H44 N4 SiP 1 21/c 111.486; 15.541; 19.133
90; 97.84; 90
3383.4Azhakar, Ramachandran; Roesky, Herbert W.; Wolf, Hilke; Stalke, Dietmar
Reactivity of Stable Heteroleptic Silylene PhC(NtBu)2SiNPh2toward Diazobenzene andN-Benzylidineaniline
Organometallics, 2012, 31, 8608
4079728 CIFC52 H92 Pd2 Si4C 1 2 121.374; 13.3834; 21.1553
90; 96.549; 90
6012.1Summerscales, Owen T.; Rivers, Christopher J.; Taylor, Morgan J.; Hitchcock, Peter B.; Green, Jennifer C.; Cloke, F. Geoffrey N.
Double-Sandwich Pentalene Complexes M2(pent†)2(M = Rh, Pd; pent†= 1,4-Bis(triisopropylsilyl)pentalene): Synthesis, Structure, and Bonding
Organometallics, 2012, 31, 8613
4079729 CIFC52 H92 Rh2 Si4C 1 2/c 122.188; 13.183; 21.397
90; 120.37; 90
5400Summerscales, Owen T.; Rivers, Christopher J.; Taylor, Morgan J.; Hitchcock, Peter B.; Green, Jennifer C.; Cloke, F. Geoffrey N.
Double-Sandwich Pentalene Complexes M2(pent†)2(M = Rh, Pd; pent†= 1,4-Bis(triisopropylsilyl)pentalene): Synthesis, Structure, and Bonding
Organometallics, 2012, 31, 8613
4079730 CIFC17 H19 Cl Ir N O4P 21 21 217.475; 14.0637; 15.9427
90; 90; 90
1676Bucci, Alberto; Savini, Arianna; Rocchigiani, Luca; Zuccaccia, Cristiano; Rizzato, Silvia; Albinati, Alberto; Llobet, Antoni; Macchioni, Alceo
Organometallic Iridium Catalysts Based on Pyridinecarboxylate Ligands for the Oxidative Splitting of Water
Organometallics, 2012, 31, 8071
4079731 CIFC27 H35 Cl3 Mo N P2P b c a16.484; 18.1198; 19.0049
90; 90; 90
5676.5Kinoshita, Eriko; Arashiba, Kazuya; Kuriyama, Shogo; Miyake, Yoshihiro; Shimazaki, Ryuji; Nakanishi, Haruyuki; Nishibayashi, Yoshiaki
Synthesis and Catalytic Activity of Molybdenum‒Dinitrogen Complexes Bearing Unsymmetric PNP-Type Pincer Ligands
Organometallics, 2012, 31, 8437
4079732 CIFC27 H47 Cl3 Mo N P2P b c a16.1351; 18.2992; 20.8235
90; 90; 90
6148.3Kinoshita, Eriko; Arashiba, Kazuya; Kuriyama, Shogo; Miyake, Yoshihiro; Shimazaki, Ryuji; Nakanishi, Haruyuki; Nishibayashi, Yoshiaki
Synthesis and Catalytic Activity of Molybdenum‒Dinitrogen Complexes Bearing Unsymmetric PNP-Type Pincer Ligands
Organometallics, 2012, 31, 8437
4079733 CIFC72 H88 Mo2 N12 P4C 1 2/c 119.8028; 14.0359; 26.7018
90; 105.015; 90
7168.4Kinoshita, Eriko; Arashiba, Kazuya; Kuriyama, Shogo; Miyake, Yoshihiro; Shimazaki, Ryuji; Nakanishi, Haruyuki; Nishibayashi, Yoshiaki
Synthesis and Catalytic Activity of Molybdenum‒Dinitrogen Complexes Bearing Unsymmetric PNP-Type Pincer Ligands
Organometallics, 2012, 31, 8437
4079734 CIFC42 H78 Mo2 N12 P4P 1 21/n 112.4475; 22.2321; 19.5339
90; 91.406; 90
5404.1Kinoshita, Eriko; Arashiba, Kazuya; Kuriyama, Shogo; Miyake, Yoshihiro; Shimazaki, Ryuji; Nakanishi, Haruyuki; Nishibayashi, Yoshiaki
Synthesis and Catalytic Activity of Molybdenum‒Dinitrogen Complexes Bearing Unsymmetric PNP-Type Pincer Ligands
Organometallics, 2012, 31, 8437
4079735 CIFC41 H28 B F20 Ir N2P 1 21/c 113.9124; 15.2581; 18.9291
90; 104.785; 90
3885.2Meredith, Joseph M.; Goldberg, Karen I.; Kaminsky, Werner; Heinekey, D. Michael
η6-Tetramethylfulvene and μ-η3:η3-Benzene Complexes of Iridium
Organometallics, 2012, 31, 8459
4079736 CIFC76 H62 B2 Cl4 F30 Ir2 N4P -111.2424; 13.1663; 14.8575
109.904; 104.465; 104.612
1859.81Meredith, Joseph M.; Goldberg, Karen I.; Kaminsky, Werner; Heinekey, D. Michael
η6-Tetramethylfulvene and μ-η3:η3-Benzene Complexes of Iridium
Organometallics, 2012, 31, 8459
4079737 CIFC37 H29 B F15 Ir N2P -111.9815; 12.0906; 13.5037
108.418; 101.066; 102.707
1736.8Meredith, Joseph M.; Goldberg, Karen I.; Kaminsky, Werner; Heinekey, D. Michael
η6-Tetramethylfulvene and μ-η3:η3-Benzene Complexes of Iridium
Organometallics, 2012, 31, 8459
4079738 CIFC35.5 H51.4 B N7 Os PP 1 21/c 116.5362; 15.2844; 15.755
90; 107.34; 90
3801Bajo, Sonia; Esteruelas, Miguel A.; López, Ana M.; Oñate, Enrique
Alkenylation of 2-Methylpyridine via Pyridylidene‒Osmium Complexes
Organometallics, 2012, 31, 8618
4079739 CIFC37 H61 B N7 Os PP 1 21/c 116.9932; 15.2993; 15.7064
90; 107.738; 90
3889.3Bajo, Sonia; Esteruelas, Miguel A.; López, Ana M.; Oñate, Enrique
Alkenylation of 2-Methylpyridine via Pyridylidene‒Osmium Complexes
Organometallics, 2012, 31, 8618
4079740 CIFC32 H43 B N7 Os PP 1 21/n 110.5349; 20.4383; 14.8765
90; 93.238; 90
3198Bajo, Sonia; Esteruelas, Miguel A.; López, Ana M.; Oñate, Enrique
Alkenylation of 2-Methylpyridine via Pyridylidene‒Osmium Complexes
Organometallics, 2012, 31, 8618
4079741 CIFC44 H55 Ir N4C 1 2/c 133.2496; 20.4868; 19.4945
90; 121.472; 90
11325.7Phillips, Nicholas; Rowles, Johnny; Kelly, Michael J.; Riddlestone, Ian; Rees, Nicholas H.; Dervisi, Athanasia; Fallis, Ian A.; Aldridge, Simon
Sterically Encumbered Iridium Bis(N-heterocyclic carbene) Complexes: Air-Stable 14-Electron Cations and Facile Degenerate C‒H Activation
Organometallics, 2012, 31, 8075
4079742 CIFC46 H59 Ir N4C 1 2/c 132.1355; 20.8001; 20.6871
90; 120.27; 90
11942.5Phillips, Nicholas; Rowles, Johnny; Kelly, Michael J.; Riddlestone, Ian; Rees, Nicholas H.; Dervisi, Athanasia; Fallis, Ian A.; Aldridge, Simon
Sterically Encumbered Iridium Bis(N-heterocyclic carbene) Complexes: Air-Stable 14-Electron Cations and Facile Degenerate C‒H Activation
Organometallics, 2012, 31, 8075
4079743 CIFC76 H68 B F24 Ir N4P -115.11; 17.1158; 17.3974
63.004; 66.1775; 75.0989
3652.43Phillips, Nicholas; Rowles, Johnny; Kelly, Michael J.; Riddlestone, Ian; Rees, Nicholas H.; Dervisi, Athanasia; Fallis, Ian A.; Aldridge, Simon
Sterically Encumbered Iridium Bis(N-heterocyclic carbene) Complexes: Air-Stable 14-Electron Cations and Facile Degenerate C‒H Activation
Organometallics, 2012, 31, 8075
4079744 CIFC78.5 H73 B Cl F24 Ir N4P -112.623; 16.379; 19.2977
100.917; 104.042; 94.8383
3764.84Phillips, Nicholas; Rowles, Johnny; Kelly, Michael J.; Riddlestone, Ian; Rees, Nicholas H.; Dervisi, Athanasia; Fallis, Ian A.; Aldridge, Simon
Sterically Encumbered Iridium Bis(N-heterocyclic carbene) Complexes: Air-Stable 14-Electron Cations and Facile Degenerate C‒H Activation
Organometallics, 2012, 31, 8075
4079745 CIFC76 H70 B F24 Ir N4P -113.8329; 16.2697; 17.7359
91.7424; 110.893; 90.7674
3726.17Phillips, Nicholas; Rowles, Johnny; Kelly, Michael J.; Riddlestone, Ian; Rees, Nicholas H.; Dervisi, Athanasia; Fallis, Ian A.; Aldridge, Simon
Sterically Encumbered Iridium Bis(N-heterocyclic carbene) Complexes: Air-Stable 14-Electron Cations and Facile Degenerate C‒H Activation
Organometallics, 2012, 31, 8075
4079746 CIFC78 H74 B F24 Ir N4P -113.031; 14.956; 19.9381
99.3037; 104.818; 91.3768
3698.41Phillips, Nicholas; Rowles, Johnny; Kelly, Michael J.; Riddlestone, Ian; Rees, Nicholas H.; Dervisi, Athanasia; Fallis, Ian A.; Aldridge, Simon
Sterically Encumbered Iridium Bis(N-heterocyclic carbene) Complexes: Air-Stable 14-Electron Cations and Facile Degenerate C‒H Activation
Organometallics, 2012, 31, 8075
4079747 CIFC27.5 H34.25 B F4 N O0.63P 1 21/c 114.6348; 25.776; 13.8
90; 90.064; 90
5205.7Kashiwame, Yohei; Kuwata, Shigeki; Ikariya, Takao
Catalytic Intramolecular Hydroamination with a Bifunctional Iridium Pyrazolato Complex: Substrate Scope and Mechanistic Elucidation
Organometallics, 2012, 31, 8444
4079748 CIFC31 H39 Ir N2 OP 1 21/n 113.306; 14.366; 14.874
90; 106.669; 90
2723.7Kashiwame, Yohei; Kuwata, Shigeki; Ikariya, Takao
Catalytic Intramolecular Hydroamination with a Bifunctional Iridium Pyrazolato Complex: Substrate Scope and Mechanistic Elucidation
Organometallics, 2012, 31, 8444
4079749 CIFC31 H33 Ir N3 O0.5P 1 21/c 114.278; 19.086; 19.509
90; 95.591; 90
5291Kashiwame, Yohei; Kuwata, Shigeki; Ikariya, Takao
Catalytic Intramolecular Hydroamination with a Bifunctional Iridium Pyrazolato Complex: Substrate Scope and Mechanistic Elucidation
Organometallics, 2012, 31, 8444
4079750 CIFC32 H35 Ir N3 O0.5C 1 2/c 123.246; 11.251; 21.322
90; 99.203; 90
5505Kashiwame, Yohei; Kuwata, Shigeki; Ikariya, Takao
Catalytic Intramolecular Hydroamination with a Bifunctional Iridium Pyrazolato Complex: Substrate Scope and Mechanistic Elucidation
Organometallics, 2012, 31, 8444
4079751 CIFC32 H34 Ir N3 O2 SP 1 21/n 122.6347; 10.1885; 26.0061
90; 109.959; 90
5637.1Kashiwame, Yohei; Kuwata, Shigeki; Ikariya, Takao
Catalytic Intramolecular Hydroamination with a Bifunctional Iridium Pyrazolato Complex: Substrate Scope and Mechanistic Elucidation
Organometallics, 2012, 31, 8444
4079752 CIFC43 H46 Ir N3P 1 21/n 114.519; 14.841; 15.945
90; 98.164; 90
3401Kashiwame, Yohei; Kuwata, Shigeki; Ikariya, Takao
Catalytic Intramolecular Hydroamination with a Bifunctional Iridium Pyrazolato Complex: Substrate Scope and Mechanistic Elucidation
Organometallics, 2012, 31, 8444
4079753 CIFC76 H80 B Li O5P -112.8039; 14.2107; 17.4436
92.171; 90.824; 102.053
3100.9Braunschweig, Holger; Hörl, Christian; Hupp, Florian; Radacki, Krzysztof; Wahler, Johannes
Borole-Derived Spirocyclic Tetraorganoborate
Organometallics, 2012, 31, 8463
4079754 CIFC64 H86 B Br P2 PtC 1 2/c 122.942; 15.907; 36.271
90; 90.922; 90
13235Braunschweig, Holger; Hörl, Christian; Hupp, Florian; Radacki, Krzysztof; Wahler, Johannes
Borole-Derived Spirocyclic Tetraorganoborate
Organometallics, 2012, 31, 8463
4079755 CIFC122 H130 B2 Cl4 P2 PtP 1 21/c 114.0647; 29.0442; 24.8349
90; 97.855; 90
10049.8Braunschweig, Holger; Hörl, Christian; Hupp, Florian; Radacki, Krzysztof; Wahler, Johannes
Borole-Derived Spirocyclic Tetraorganoborate
Organometallics, 2012, 31, 8463
4079756 CIFC7 H10 Cl4 O4 SnP 1 21/c 17.3546; 12.4212; 14.965
90; 103.296; 90
1330.5Novikov, Roman A.; Balakirev, Dmitry O.; Timofeev, Vladimir P.; Tomilov, Yury V.
Complexes of Donor‒Acceptor Cyclopropanes with Tin, Titanium, and Gallium Chlorides — Mechanism Studies
Organometallics, 2012, 31, 8627
4079757 CIFC36 H25 Ge N O10 Os3P -111.1548; 13.7581; 14.1494
65.73; 71.569; 85.375
1874.97Adams, Richard D.; Kan, Yuwei; Zhang, Qiang
Osmium‒Germanium and Osmium‒Germanium‒Gold Carbonyl Cluster Complexes: Syntheses, Structures, Bonding, and Reactivity
Organometallics, 2012, 31, 8639
4079758 CIFC46 H32 Ge2 O10 Os3P b c a18.223; 17.1315; 28.6054
90; 90; 90
8930.2Adams, Richard D.; Kan, Yuwei; Zhang, Qiang
Osmium‒Germanium and Osmium‒Germanium‒Gold Carbonyl Cluster Complexes: Syntheses, Structures, Bonding, and Reactivity
Organometallics, 2012, 31, 8639
4079759 CIFC29 H10 Ge O17 Os5P -110.0493; 10.1132; 18.3249
83.704; 86.876; 73.42
1773.65Adams, Richard D.; Kan, Yuwei; Zhang, Qiang
Osmium‒Germanium and Osmium‒Germanium‒Gold Carbonyl Cluster Complexes: Syntheses, Structures, Bonding, and Reactivity
Organometallics, 2012, 31, 8639
4079760 CIFC49 H37 Au Ge O10 Os3 PC 1 2/c 125.6478; 13.3284; 31.3682
90; 105.299; 90
10343Adams, Richard D.; Kan, Yuwei; Zhang, Qiang
Osmium‒Germanium and Osmium‒Germanium‒Gold Carbonyl Cluster Complexes: Syntheses, Structures, Bonding, and Reactivity
Organometallics, 2012, 31, 8639
4079761 CIFC40 H30 Au Ge O4 Os PP 1 21/n 112.6744; 10.9674; 27.57
90; 101.452; 90
3756.1Adams, Richard D.; Kan, Yuwei; Zhang, Qiang
Osmium‒Germanium and Osmium‒Germanium‒Gold Carbonyl Cluster Complexes: Syntheses, Structures, Bonding, and Reactivity
Organometallics, 2012, 31, 8639
4079762 CIFC59 H42 Au Cl2 Ge O8 Os3 PP -112.1758; 14.985; 17.474
107.19; 108.865; 91.232
2857.9Adams, Richard D.; Kan, Yuwei; Zhang, Qiang
Osmium‒Germanium and Osmium‒Germanium‒Gold Carbonyl Cluster Complexes: Syntheses, Structures, Bonding, and Reactivity
Organometallics, 2012, 31, 8639
4079763 CIFC25 H43 Ca I O4.5C 1 2/c 117.588; 18.907; 16.774
90; 90.123; 90
5577.95Köhler, Mathias; Langer, Jens; Görls, Helmar; Westerhausen, Matthias
Synthesis and Molecular Structures of Meta-Substituted Arylcalcium Iodides
Organometallics, 2012, 31, 8647
4079764 CIFC24 H41 Ca I O4P 1 21/c 113.3143; 12.0557; 16.2773
90; 91.975; 90
2611.2Köhler, Mathias; Langer, Jens; Görls, Helmar; Westerhausen, Matthias
Synthesis and Molecular Structures of Meta-Substituted Arylcalcium Iodides
Organometallics, 2012, 31, 8647

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