Crystallography Open Database

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4060668 CIFC20 H42 Li N2 P S Si2P 1 21/n 111.8664; 15.2844; 14.9184
90; 99.22; 90
2670.8Stuart Blair; Keith Izod; Ross W. Harrington; William Clegg
Sterically Controlled Mono- or Dimetalation of a Thioether-Functionalized Phosphine and an Unusual Light-Induced Phosphide-Thiolate Rearrangement
Organometallics, 2003, 22, 302-308
4060669 CIFC25 H55 Li2 N4 P S Si2P -19.6026; 11.7841; 16.6685
103.822; 92.896; 107.49
1731.58Stuart Blair; Keith Izod; Ross W. Harrington; William Clegg
Sterically Controlled Mono- or Dimetalation of a Thioether-Functionalized Phosphine and an Unusual Light-Induced Phosphide-Thiolate Rearrangement
Organometallics, 2003, 22, 302-308
4060670 CIFC22 H42 Li O4 P S Si2P 21 21 218.5421; 14.8293; 22.0627
90; 90; 90
2794.8Stuart Blair; Keith Izod; Ross W. Harrington; William Clegg
Sterically Controlled Mono- or Dimetalation of a Thioether-Functionalized Phosphine and an Unusual Light-Induced Phosphide-Thiolate Rearrangement
Organometallics, 2003, 22, 302-308
4060671 CIFC18 H26 B Cl ZrP 1 21/c 118.7985; 13.8359; 13.3282
90; 92.23; 90
3464Xuenian Chen; Shengming Liu; Christine. E. Plečnik; Fu-Chen Liu; Gideon Fraenkel; Sheldon G. Shore
Cyclic Organohydroborate Complexes of Metallocenes. VII. Synthesis, Structure, and Fluxional Behavior of Cp2ZrX{(μ-H)2BC8H14} (X =H, D, Cl)
Organometallics, 2003, 22, 275-283
4060672 CIFC18 H27 B ZrP 1 21/n 111.9608; 10.2533; 13.9041
90; 102.792; 90
1662.8Xuenian Chen; Shengming Liu; Christine. E. Plečnik; Fu-Chen Liu; Gideon Fraenkel; Sheldon G. Shore
Cyclic Organohydroborate Complexes of Metallocenes. VII. Synthesis, Structure, and Fluxional Behavior of Cp2ZrX{(μ-H)2BC8H14} (X =H, D, Cl)
Organometallics, 2003, 22, 275-283
4060673 CIFC15 H23 N2 O9 ReC 1 2/c 138.655; 12.6467; 8.5136
90; 95.985; 90
4139.2Dorothy H. Gibson; Xiaolong Yin; Haiyang He; Mark S. Mashuta
Synthesis and Reactions of fac-[Re(dmbpy)(CO)3X] (dmbpy \δb 4,4'-Dimethyl-2,2'-bipyridine; X =COOH, CHO) and Their Derivatives
Organometallics, 2003, 22, 337-346
4060674 CIFC49.25 H48 Cl1.5 N6 O16.25 Re4C 1 2/c 140.977; 13.1061; 23.985
90; 123.571; 90
10732Dorothy H. Gibson; Xiaolong Yin; Haiyang He; Mark S. Mashuta
Synthesis and Reactions of fac-[Re(dmbpy)(CO)3X] (dmbpy \δb 4,4'-Dimethyl-2,2'-bipyridine; X =COOH, CHO) and Their Derivatives
Organometallics, 2003, 22, 337-346
4060675 CIFC29 H25 Cl2 N4 O3 Re SP 1 21/c 115.275; 17.059; 12.377
90; 109.805; 90
3034.2Eva Hevia; Julio Pérez; Víctor Riera; Daniel Miguel
Reactivity of the Amido Complex [Re(NHpTol)(CO)3(bipy)] toward Neutral Organic Electrophiles
Organometallics, 2003, 22, 257-263
4060676 CIFC38 H34 N3 O5 ReP -18.7734; 11.721; 16.512
101.297; 90.51; 99.202
1642.2Eva Hevia; Julio Pérez; Víctor Riera; Daniel Miguel
Reactivity of the Amido Complex [Re(NHpTol)(CO)3(bipy)] toward Neutral Organic Electrophiles
Organometallics, 2003, 22, 257-263
4060677 CIFC32 H34 N3 O8 ReP -18.895; 13.262; 15.644
65.453; 81.655; 80.031
1647.8Eva Hevia; Julio Pérez; Víctor Riera; Daniel Miguel
Reactivity of the Amido Complex [Re(NHpTol)(CO)3(bipy)] toward Neutral Organic Electrophiles
Organometallics, 2003, 22, 257-263
4060678 CIFC10 H10 Ag2 I2 N2 O0P 1 21/c 19.164; 16.819; 9.389
90; 106.311; 90
1388.8Qing-Xiang Liu; Feng-Bo Xu; Qing-Shan Li; Xian-Shun Zeng; Xue-Bin Leng; Yuan L. Chou; Zheng-Zhi Zhang
A Luminescent Silver(I) Carbene Stair Polymer
Organometallics, 2003, 22, 309-314
4060679 CIFC29 H22 Ir2 O8 W2P 1 c 19.7099; 9.9514; 14.8062
90; 105.411; 90
1379.24Nigel T. Lucas; Eleni G. A. Notaras; Marie P. Cifuentes; Mark G. Humphrey
Mixed-Metal Cluster Chemistry. 21. Synthesis and Crystallographic and Electrochemical Studies of Alkyne-Coordinated Group 6-Iridium Clusters Linked by Phenylenevinylene Groups
Organometallics, 2003, 22, 284-301
4060680 CIFC70 H38 Ir4 Mo4 O16P -19.6923; 10.4511; 18.9394
74.615; 83.982; 68.9618
1726.32Nigel T. Lucas; Eleni G. A. Notaras; Marie P. Cifuentes; Mark G. Humphrey
Mixed-Metal Cluster Chemistry. 21. Synthesis and Crystallographic and Electrochemical Studies of Alkyne-Coordinated Group 6-Iridium Clusters Linked by Phenylenevinylene Groups
Organometallics, 2003, 22, 284-301
4060681 CIFC114 H102 Ir6 Mo6 O24P -326.2521; 26.2521; 33.2008
90; 90; 120
19815.6Nigel T. Lucas; Eleni G. A. Notaras; Marie P. Cifuentes; Mark G. Humphrey
Mixed-Metal Cluster Chemistry. 21. Synthesis and Crystallographic and Electrochemical Studies of Alkyne-Coordinated Group 6-Iridium Clusters Linked by Phenylenevinylene Groups
Organometallics, 2003, 22, 284-301
4060711 CIFC21 H44 N4 Si4R 3 c :H20.3499; 20.3499; 34.489
90; 90; 120
12368.9Shutov, Pavel L.; Sorokin, Denis A.; Karlov, Sergey S.; Harms, Klaus; Oprunenko, Yuri F.; Churakov, Andrei V.; Antipin, Mikhail Yu.; Zaitseva, Galina S.; Lorberth, Jörg
Azametallatranes of Group 14 Elements. Syntheses and X-ray Studies
Organometallics, 2003, 22, 516-522
4060712 CIFC21 H44 Ge N4 Si3R 3 c :H20.381; 20.381; 34.7323
90; 90; 120
12494.4Shutov, Pavel L.; Sorokin, Denis A.; Karlov, Sergey S.; Harms, Klaus; Oprunenko, Yuri F.; Churakov, Andrei V.; Antipin, Mikhail Yu.; Zaitseva, Galina S.; Lorberth, Jörg
Azametallatranes of Group 14 Elements. Syntheses and X-ray Studies
Organometallics, 2003, 22, 516-522
4060713 CIFC21 H44 N4 Si3 SnP -110.7581; 16.2673; 17.8259
73.644; 88.022; 72.245
2846.3Shutov, Pavel L.; Sorokin, Denis A.; Karlov, Sergey S.; Harms, Klaus; Oprunenko, Yuri F.; Churakov, Andrei V.; Antipin, Mikhail Yu.; Zaitseva, Galina S.; Lorberth, Jörg
Azametallatranes of Group 14 Elements. Syntheses and X-ray Studies
Organometallics, 2003, 22, 516-522
4060714 CIFC15 H26 Ge N4P 21 21 218.3466; 11.2962; 16.3629
90; 90; 90
1542.8Shutov, Pavel L.; Sorokin, Denis A.; Karlov, Sergey S.; Harms, Klaus; Oprunenko, Yuri F.; Churakov, Andrei V.; Antipin, Mikhail Yu.; Zaitseva, Galina S.; Lorberth, Jörg
Azametallatranes of Group 14 Elements. Syntheses and X-ray Studies
Organometallics, 2003, 22, 516-522
4060715 CIFC14 H13 Cl F6 O2 OsP -18.719; 8.774; 12.132
89.12; 76.5; 65.23
815.8Weberndörfer, Birgit; Henig, Gerhard; Hockless, David C. R.; Bennet, Martin A.; Werner, Helmut
Synthesis, Molecular Structures and Reactivity of Neutral and Cationic Areneosmium(II) Complexes with Diarylcarbenes as Ligands
Organometallics, 2003, 22, 744-758
4060716 CIFC22.5 H23 Cl3 OsC 1 2 118.282; 7.71; 15.709
90; 105.05; 90
2138.3Weberndörfer, Birgit; Henig, Gerhard; Hockless, David C. R.; Bennet, Martin A.; Werner, Helmut
Synthesis, Molecular Structures and Reactivity of Neutral and Cationic Areneosmium(II) Complexes with Diarylcarbenes as Ligands
Organometallics, 2003, 22, 744-758
4060743 CIFC65 H75 In Li2 O10 Si4P 1 n 110.74; 16.23; 21.295
90; 101.92; 90
3631.9Mrinialini G. Walawalkar
A Rare Lithium Indium Siloxane: Synthesis and Crystal Structure of [InMe{(OPh~2~Si)~2~O}~2~-μ-{Li(THF)~2~}~2~]
Organometallics, 2003, 22, 879-881
4060747 CIFC33 H35 Cl Fe2 O10 Ru2P 1 21/n 115.92; 11.83; 18.874
90; 101.139; 90
3487Masako Terada; Munetaka Akita
Formal Hydrogenation of a Permetalated Ethene, (μ4-C\δb C)Fe2Ru2(η5-C5Me5)2(CO)8(dppm), via Successive Protonation-Hydride Reduction Leading to C2Hn Cluster Compounds
Organometallics, 2003, 22, 355-364
4060748 CIFC61 H66 Fe2 O8 P2 Ru2P 1 21/n 113.687; 13.689; 30.766
90; 101.511; 90
5648Masako Terada; Munetaka Akita
Formal Hydrogenation of a Permetalated Ethene, (μ4-C\δb C)Fe2Ru2(η5-C5Me5)2(CO)8(dppm), via Successive Protonation-Hydride Reduction Leading to C2Hn Cluster Compounds
Organometallics, 2003, 22, 355-364
4060749 CIFC68 H69 B F4 Fe2 O7 P2 Ru2P -112.623; 20.931; 12.634
102.96; 93.7; 100.648
3177Masako Terada; Munetaka Akita
Formal Hydrogenation of a Permetalated Ethene, (μ4-C\δb C)Fe2Ru2(η5-C5Me5)2(CO)8(dppm), via Successive Protonation-Hydride Reduction Leading to C2Hn Cluster Compounds
Organometallics, 2003, 22, 355-364
4060750 CIFC42 H38 Fe O5 P2 Ru2P -112.213; 18.566; 9.8307
104.782; 112.424; 79.31
1982.6Masako Terada; Munetaka Akita
Formal Hydrogenation of a Permetalated Ethene, (μ4-C\δb C)Fe2Ru2(η5-C5Me5)2(CO)8(dppm), via Successive Protonation-Hydride Reduction Leading to C2Hn Cluster Compounds
Organometallics, 2003, 22, 355-364
4060751 CIFC49 H47 Fe O5 P2 Ru2P -111.3574; 19.002; 11.342
104.712; 99.917; 107.112
2180.5Masako Terada; Munetaka Akita
Formal Hydrogenation of a Permetalated Ethene, (μ4-C\δb C)Fe2Ru2(η5-C5Me5)2(CO)8(dppm), via Successive Protonation-Hydride Reduction Leading to C2Hn Cluster Compounds
Organometallics, 2003, 22, 355-364
4060752 CIFC48 H41 Cl4 Co Fe O9 P2 Ru2P 1 21/c 111.4541; 19.4961; 22.7347
90; 92.419; 90
5072.4Masako Terada; Munetaka Akita
Formal Hydrogenation of a Permetalated Ethene, (μ4-C\δb C)Fe2Ru2(η5-C5Me5)2(CO)8(dppm), via Successive Protonation-Hydride Reduction Leading to C2Hn Cluster Compounds
Organometallics, 2003, 22, 355-364
4061826 CIFC63 H99 Ge2 Te4P -110.5768; 15.9415; 21.3704
80.087; 82.569; 85.286
3513Ramaker, Gerhard; Saak, Wolfgang; Haase, Detlev; Weidenbruch, Manfred
Reaction Modes of a Tetragermabutadiene: Cycloadditions versus Ge-Ge Bond Cleavages
Organometallics, 2003, 22, 5212-5216
4061827 CIFC60 H92 Ge2P -113.1667; 13.5646; 18.2962
98.402; 96.913; 112.121
2939.3Ramaker, Gerhard; Saak, Wolfgang; Haase, Detlev; Weidenbruch, Manfred
Reaction Modes of a Tetragermabutadiene: Cycloadditions versus Ge-Ge Bond Cleavages
Organometallics, 2003, 22, 5212-5216
4061828 CIFC93.5 H142 Ge4 OP -115.0722; 15.0795; 23.4233
98.857; 99.257; 117.922
4479.3Ramaker, Gerhard; Saak, Wolfgang; Haase, Detlev; Weidenbruch, Manfred
Reaction Modes of a Tetragermabutadiene: Cycloadditions versus Ge-Ge Bond Cleavages
Organometallics, 2003, 22, 5212-5216
4061829 CIFC60 H96 Ge2 TeC 1 2/c 122.4018; 9.728; 26.7946
90; 96.545; 90
5801.1Ramaker, Gerhard; Saak, Wolfgang; Haase, Detlev; Weidenbruch, Manfred
Reaction Modes of a Tetragermabutadiene: Cycloadditions versus Ge-Ge Bond Cleavages
Organometallics, 2003, 22, 5212-5216
4061830 CIFC80 H123 Ge3 N OP 1 21/n 111.8412; 32.2192; 21.0546
90; 101.127; 90
7881.6Ramaker, Gerhard; Saak, Wolfgang; Haase, Detlev; Weidenbruch, Manfred
Reaction Modes of a Tetragermabutadiene: Cycloadditions versus Ge-Ge Bond Cleavages
Organometallics, 2003, 22, 5212-5216
4061833 CIFC42 H49 Cl O5 P RhP 1 21/n 114.023; 12.684; 22.639
90; 104.63; 90
3896.2Selent, Detlef; Baumann, Wolfgang; Kempe, Rhett; Spannenberg, Anke; Röttger, Dirk; Wiese, Klaus-Diether; Börner, Armin
Reactions of a Hydroxy Phosphonite Ligand in the Coordination Sphere of Rhodium(I)
Organometallics, 2003, 22, 4265-4271
4061834 CIFC42 H48 O5 P RhP -112.562; 17.48; 18.107
68.86; 82.43; 89.39
3673.2Selent, Detlef; Baumann, Wolfgang; Kempe, Rhett; Spannenberg, Anke; Röttger, Dirk; Wiese, Klaus-Diether; Börner, Armin
Reactions of a Hydroxy Phosphonite Ligand in the Coordination Sphere of Rhodium(I)
Organometallics, 2003, 22, 4265-4271
4061835 CIFC42 H49 Cl O5 P RhP 4110.831; 10.831; 31.904
90; 90; 90
3742.7Selent, Detlef; Baumann, Wolfgang; Kempe, Rhett; Spannenberg, Anke; Röttger, Dirk; Wiese, Klaus-Diether; Börner, Armin
Reactions of a Hydroxy Phosphonite Ligand in the Coordination Sphere of Rhodium(I)
Organometallics, 2003, 22, 4265-4271
4061837 CIFC17 H32 Cl3 Ge2 Nb SnC 1 2/c 128.763; 8.217; 23.765
90; 119.357; 90
4895.8Nikonov, Georgii I.; Churakov, Andrei V.; Antipin, Mikhail Yu.
Bis(germyl)-Substituted Niobocenes
Organometallics, 2003, 22, 2178-2180
4061838 CIFC30 H52 N6 O2 SnP 1 21/n 123.355; 6.26; 23.778
90; 106.18; 90
3338.6Zemlyansky, Nikolay N.; Borisova, Irina V.; Kuznetsova, Marianna G.; Khrustalev, Victor N.; Ustynyuk, Yuri A.; Nechaev, Mikhael S.; Lunin, Valery V.; Barrau, Jacques; Rima, Ghassoub
New Stable Germylenes, Stannylenes, and Related Compounds. 1. Stable Germanium(II) and Tin(II) Compounds M(OCH~2~CH~2~NMe~2~)~2~ (M = Ge, Sn) with Intramolecular Coordination Metal‒Nitrogen Bonds. Synthesis and Structure
Organometallics, 2003, 22, 1675-1681
4061839 CIFC8 H20 Ge N2 O2P 21 21 2110.1606; 11.2693; 20.387
90; 90; 90
2334.3Zemlyansky, Nikolay N.; Borisova, Irina V.; Kuznetsova, Marianna G.; Khrustalev, Victor N.; Ustynyuk, Yuri A.; Nechaev, Mikhael S.; Lunin, Valery V.; Barrau, Jacques; Rima, Ghassoub
New Stable Germylenes, Stannylenes, and Related Compounds. 1. Stable Germanium(II) and Tin(II) Compounds M(OCH~2~CH~2~NMe~2~)~2~ (M = Ge, Sn) with Intramolecular Coordination Metal‒Nitrogen Bonds. Synthesis and Structure
Organometallics, 2003, 22, 1675-1681
4061840 CIFC8 H20 N2 O2 SnA e a 211.7705; 10.1142; 10.061
90; 90; 90
1197.8Zemlyansky, Nikolay N.; Borisova, Irina V.; Kuznetsova, Marianna G.; Khrustalev, Victor N.; Ustynyuk, Yuri A.; Nechaev, Mikhael S.; Lunin, Valery V.; Barrau, Jacques; Rima, Ghassoub
New Stable Germylenes, Stannylenes, and Related Compounds. 1. Stable Germanium(II) and Tin(II) Compounds M(OCH~2~CH~2~NMe~2~)~2~ (M = Ge, Sn) with Intramolecular Coordination Metal–Nitrogen Bonds. Synthesis and Structure
Organometallics, 2003, 22, 1675-1681
4061903 CIFC27 H26 B N6 O2 RhP 1 21/c 112.6077; 19.6436; 11.212
90; 105.554; 90
2675.1Ruman, Tomasz; Ciunik, Zbigniew; Trzeciak, Anna M.; Wołowiec, Stanisław; Ziółkowski, Józef J.
Complexes of Heteroscorpionate Trispyrazolylborate Ligands. Part X. Structures and Fluxional Behavior of Rhodium(I) Complexes with Heteroscorpionate Trispyrazolylborate Ligands, Tp”Rh(LL); (LL) = (CO)2 or (COD)
Organometallics, 2003, 22, 1072-1080
4061909 CIFC18 H18 Cl4 Ge N2 SP n m a14.9919; 15.4408; 9.2238
90; 90; 90
2135.2Saur, Isabelle; Rima, Ghassoub; Gornitzka, Heinz; Miqueu, Karinne; Barrau, Jacques
Heteronuclear Multiple Bonding between Heavier Group 14 and 16 Elements. A New Class of Germylated Compounds, the Germanethiocarbamyl and Germaneselenocarbamyl Chlorides L^2^(Cl)GeY (Y = S, Se)
Organometallics, 2003, 22, 1106-1109
4061910 CIFC18 H18 Cl4 Ge N2 SeP n m a15.1574; 15.554; 9.1975
90; 90; 90
2168.4Saur, Isabelle; Rima, Ghassoub; Gornitzka, Heinz; Miqueu, Karinne; Barrau, Jacques
Heteronuclear Multiple Bonding between Heavier Group 14 and 16 Elements. A New Class of Germylated Compounds, the Germanethiocarbamyl and Germaneselenocarbamyl Chlorides L^2^(Cl)GeY (Y = S, Se)
Organometallics, 2003, 22, 1106-1109
4061917 CIFC10 H19 Mo N3 O2 P2P 1 21/n 17.723; 14.189; 14.656
90; 101.2; 90
1575.5Pérez, Julio; Riera, Víctor; Rodríguez, Amor; López, Ramón; Sordo, Tomás L.; García-Granda, Santiago; García-Rodríguez, Esther; Galindo, Agustín
Structural divergence in the products of the reaction of [MoCl(allyl)(CO)2(dmpm)] with nucleophiles.
Organometallics, 2003, 22, 1540-1545
4061920 CIFC30 H22 Fe N O5 P WP 21 21 2111.316; 13.8693; 19.933
90; 90; 90
3128.4Thanh Thien Co; Seung Whan Paek; Sang Chul Shim; Chan Sik Cho; Tae-Jeong Kim; Dong Woong Choi; Sang Ook Kang; Jong Hwa Jeong
1,2-Ferrocenediylazaphosphinines: An Unusual Coordination Behavior and Application to Allylic Alkylation
Organometallics, 2003, 22, 1475
4061921 CIFC29 H27 B F4 Fe N O P PdP n a 2114.4365; 11.2483; 16.9363
90; 90; 90
2750.2Thanh Thien Co; Seung Whan Paek; Sang Chul Shim; Chan Sik Cho; Tae-Jeong Kim; Dong Woong Choi; Sang Ook Kang; Jong Hwa Jeong
1,2-Ferrocenediylazaphosphinines: An Unusual Coordination Behavior and Application to Allylic Alkylation
Organometallics, 2003, 22, 1475
4061922 CIFC22 H17 Cr2 O6 P SP n a 2119.6999; 9.6164; 11.5827
90; 90; 90
2194.3Weng, Zhiqiang; Leong, Weng Kee; Vittal, Jagadese J.; Goh, Lai Yoong
Complexes from Ring Opening of Lawesson's Reagent and Phosphorus-Phosphorus Coupling
Organometallics, 2003, 22, 1645-1656
4061931 CIFC60 H65 B F24 O2 P2 RuP 1 21/c 118.667; 19.062; 18.852
90; 99.55; 90
6615Aneetha, Halikhedkar; Jiménez-Tenorio, Manuel; Puerta, M. Carmen; Valerga, Pedro; Mereiter, Kurt
Structure and Dynamics of Half-Sandwich Ruthenium(IV) Alkynyl Hydrido Complexes
Organometallics, 2003, 22, 2001-2013
4061932 CIFC75 H83 B F24 O2 P2 RuP -112.986; 14.483; 22.235
71.25; 79.88; 89.36
3893.7Aneetha, Halikhedkar; Jiménez-Tenorio, Manuel; Puerta, M. Carmen; Valerga, Pedro; Mereiter, Kurt
Structure and Dynamics of Half-Sandwich Ruthenium(IV) Alkynyl Hydrido Complexes
Organometallics, 2003, 22, 2001-2013
4061933 CIFC61 H71 B F24 P2 Ru SiP -114.695; 14.764; 17.085
103.21; 107.61; 93
3409.9Aneetha, Halikhedkar; Jiménez-Tenorio, Manuel; Puerta, M. Carmen; Valerga, Pedro; Mereiter, Kurt
Structure and Dynamics of Half-Sandwich Ruthenium(IV) Alkynyl Hydrido Complexes
Organometallics, 2003, 22, 2001-2013
4061936 CIFC38 H58 Cl N4 O3 YbP 21 21 2110.141; 16.929; 22.632
90; 90; 90
3885.4Roesky, Peter W.; Bürgstein, Markus R.
Chiral Bridged Aminotroponiminate Complexes of the heavy Lanthanides
Organometallics, 2003, 22, 1372-1375
4061937 CIFC38 H58 Cl Lu N4 O3P 21 21 2110.09; 16.9; 22.53
90; 90; 90
3841.8Roesky, Peter W.; Bürgstein, Markus R.
Chiral Bridged Aminotroponiminate Complexes of the heavy Lanthanides
Organometallics, 2003, 22, 1372-1375
4061974 CIFC44 H76 N2 P2 RuP -110.7406; 14.063; 15.132
73.759; 85.968; 73.722
2106.3Borowski, Andrzej F.; Sabo-Etienne, Sylviane; Donnadieu, Bruno; Chaudret, Bruno
Reactivity of the Bis(dihydrogen) Complex [RuH~2~(η^2^-H~2~)~2~(PCy~3~)~2~] towards N-Heteroaromatic Compounds. Regioselective Hydrogenation of Acridine to 1,2,3,4,5,6,7,8-Octahydroacridine
Organometallics, 2003, 22, 1630-1637
4061975 CIFC6.5 H8.5 N0.5P 1 21/n 19.252; 6.487; 9.726
90; 116.71; 90
521.44Borowski, Andrzej F.; Sabo-Etienne, Sylviane; Donnadieu, Bruno; Chaudret, Bruno
Reactivity of the Bis(dihydrogen) Complex [RuH~2~(η^2^-H~2~)~2~(PCy~3~)~2~] towards N-Heteroaromatic Compounds. Regioselective Hydrogenation of Acridine to 1,2,3,4,5,6,7,8-Octahydroacridine
Organometallics, 2003, 22, 1630-1637
4061993 CIFC32 H36 Li O2 PP 1 21/c 117.13; 13.084; 12.611
90; 105.464; 90
2724.2Moores, Audrey; Ricard, Louis; Le Floch, Pascal; Mézailles, Nicolas
First X-Ray Crystal Study and DFT Calculations of Anionic λ^4-Phosphinines
Organometallics, 2003, 22, 1960
4061994 CIFC46 H64 Li N2 O7 PP 1 21/c 113.4078; 13.1088; 24.7527
90; 98.698; 90
4300.5Moores, Audrey; Ricard, Louis; Le Floch, Pascal; Mézailles, Nicolas
First X-Ray Crystal Study and DFT Calculations of Anionic λ^4-Phosphinines
Organometallics, 2003, 22, 1960
4061995 CIFC40 H64 Li O4 P Si2P 21 21 2110.842; 18.047; 21.942
90; 90; 90
4293Moores, Audrey; Ricard, Louis; Le Floch, Pascal; Mézailles, Nicolas
First X-Ray Crystal Study and DFT Calculations of Anionic λ^4-Phosphinines
Organometallics, 2003, 22, 1960
4061996 CIFC45 H74 Li N2 O6 P Si2P -113.0957; 13.9957; 14.0048
80.129; 67.195; 86.609
2331.09Moores, Audrey; Ricard, Louis; Le Floch, Pascal; Mézailles, Nicolas
First X-Ray Crystal Study and DFT Calculations of Anionic λ^4-Phosphinines
Organometallics, 2003, 22, 1960
4062023 CIFC23 H39 N3 RuC 1 2/c 129.03; 9.726; 19.438
90; 116.96; 90
4891Masafumi Hirano; Rie Asakawa; Chifumi Nagata; Takashi Miyasaka; Nobuyuki Komine; Sanshiro Komiya
Ligand Displacement Reaction of Ru(η^4^-1,5-COD)(η^6^-1,3,5-COT) with Lewis Bases
Organometallics, 2003, 22, 2378
4062030 CIFC20 H30 MgP 1 21/c 19.9027; 12.7901; 23.028
90; 90.578; 90
2916.4Vollet, Jean; Baum, Elke; Schnöckel, Hansgeorg
Bis(pentamethylcyclopentadienyl)magnesium: Unexpected Determination of the Until Now Unknown Molecular Structure of the Crystalline Compound
Organometallics, 2003, 22, 2525-2527
4062055 CIFC38 H30 Cl Ir O2 P2P -110.44; 10.653; 15.247
95.336; 104.181; 104.852
1567Garralda, María A.; Hernández, Ricardo; Ibarlucea, Lourdes; Pinilla, Elena; Torres, M. Rosario
Synthesis and Characterization of Hydridoirida-β-diketones Formed by the Reaction of [{Ir(Cod)Cl}2] (Cod = 1,5-cyclooctadiene) with o-(Diphenylphosphino)benzaldehyde
Organometallics, 2003, 22, 3600-3603
4062056 CIFC38 H30 Cl3 Ir O2 P2 SnP -111.5703; 11.817; 14.5214
84.886; 78.361; 70.663
1834.39Garralda, María A.; Hernández, Ricardo; Ibarlucea, Lourdes; Pinilla, Elena; Torres, M. Rosario
Synthesis and Characterization of Hydridoirida-β-diketones Formed by the Reaction of [{Ir(Cod)Cl}2] (Cod = 1,5-cyclooctadiene) with o-(Diphenylphosphino)benzaldehyde
Organometallics, 2003, 22, 3600-3603
4062057 CIFC38 H30 Cl Ir O9 P2P 1 21/c 19.5945; 23.0849; 18.915
90; 96.13; 90
4165.5Garralda, María A.; Hernández, Ricardo; Ibarlucea, Lourdes; Pinilla, Elena; Torres, M. Rosario
Synthesis and Characterization of Hydridoirida-β-diketones Formed by the Reaction of [{Ir(Cod)Cl}2] (Cod = 1,5-cyclooctadiene) with o-(Diphenylphosphino)benzaldehyde
Organometallics, 2003, 22, 3600-3603
4062058 CIFC43 H37 Cl Ir N O7 P2P -111.2711; 13.0553; 14.2463
81.179; 89.476; 74.322
1993.3Garralda, María A.; Hernández, Ricardo; Ibarlucea, Lourdes; Pinilla, Elena; Torres, M. Rosario
Synthesis and Characterization of Hydridoirida-β-diketones Formed by the Reaction of [{Ir(Cod)Cl}2] (Cod = 1,5-cyclooctadiene) with o-(Diphenylphosphino)benzaldehyde
Organometallics, 2003, 22, 3600-3603
4062059 CIFC57 H47 Cl3 Ir O6 P3P 1 21/c 114.5904; 17.4378; 20.5125
90; 102.911; 90
5086.9Garralda, María A.; Hernández, Ricardo; Ibarlucea, Lourdes; Pinilla, Elena; Torres, M. Rosario
Synthesis and Characterization of Hydridoirida-β-diketones Formed by the Reaction of [{Ir(Cod)Cl}2] (Cod = 1,5-cyclooctadiene) with o-(Diphenylphosphino)benzaldehyde
Organometallics, 2003, 22, 3600-3603
4062065 CIFC34 H72 K La O1.5 Si6P -19.873; 12.97; 19.496
76.66; 77.94; 88.78
2374.6Woodman, Timothy J.; Schormann, Mark; Bochmann, Manfred
Synthesis, Characterisation and Reactivity of {Ansa-bis(allyl)}lanthanide Complexes, a new Class of Single-Component Methylmethacrylate Polymerization Catalysts
Organometallics, 2003, 22, 2938-2943
4062066 CIFC44 H100 Li O4 Si6 SmP 1 2/n 112.511; 12.243; 19.609
90; 95.79; 90
2988.2Woodman, Timothy J.; Schormann, Mark; Bochmann, Manfred
Synthesis, Characterisation and Reactivity of {Ansa-bis(allyl)}lanthanide Complexes, a new Class of Single-Component Methylmethacrylate Polymerization Catalysts
Organometallics, 2003, 22, 2938-2943
4062085 CIFC47 H60 B F15 Si6 ZrP -112.805; 13.873; 17.953
79.763; 81.826; 62.677
2781.6Choukroun, Robert; Wolff, Fabien; Lorber, Christian; Donnadieu, Bruno
C-H Activation of the Trimethylsilyl-Substituted Cyclopentadienyl Ligand in the "Cation-like" Complex [Cp'''~2~ZrMe][Me(B(C~6~F~5~)~3~] (Cp''' = η^5^-C~5~H~2~-1,2,4-(SiMe~3~)~3~)
Organometallics, 2003, 22, 2245-2248
4062086 CIFC36 H54 Ru3P c c n18.44; 22.5372; 15.9042
90; 90; 90
6609.7Akiko Inagaki; Toshiro Takao; Makoto Moriya; Hiroharu Suzuki
Thermal Skeletal Rearrangement of a nido-Ruthenacyclopentadiene Complex Involving Reversible Rapture and Formation of a Ruthenium-Ruthenium Bond
Organometallics, 2003, 22, 2196-2198
4062087 CIFC35 H52 Ru3P 1 21/c 110.949; 17.795; 17.362
90; 107.795; 90
3221.1Akiko Inagaki; Toshiro Takao; Makoto Moriya; Hiroharu Suzuki
Thermal Skeletal Rearrangement of a nido-Ruthenacyclopentadiene Complex Involving Reversible Rapture and Formation of a Ruthenium-Ruthenium Bond
Organometallics, 2003, 22, 2196-2198
4062088 CIFC116 H140 Li2 O8 Y2C 1 c 110.5879; 32.1072; 14.2001
90; 92.745; 90
4821.8Kirillov, Evgueni; Toupet, Loic; Lehmann, Christian W.; Razavi, Abbas; Kahlal, Samia; Saillard, Jean-Yves; Carpentier, Jean-François
[(Cp-CMe~2~-Flu)~2~Ln]^-^[Li(ether)n]^+^ (Ln = Y, La): Complexes with Unusual Coordination Modes of the Fluorenyl Ligand and the First Examples of Bis-Ansa Lanthanidocenes
Organometallics, 2003, 22, 4038-4046
4062089 CIFC58 H70 Li O4 YP c a 2119.1523; 10.1817; 24.7512
90; 90; 90
4826.6Kirillov, Evgueni; Toupet, Loic; Lehmann, Christian W.; Razavi, Abbas; Kahlal, Samia; Saillard, Jean-Yves; Carpentier, Jean-François
[(Cp-CMe~2~-Flu)~2~Ln]^-^[Li(ether)n]^+^ (Ln = Y, La): Complexes with Unusual Coordination Modes of the Fluorenyl Ligand and the First Examples of Bis-Ansa Lanthanidocenes
Organometallics, 2003, 22, 4038-4046
4062090 CIFC60 H75 Li O4.5 YP -112.599; 13.398; 17.133
67.74; 70.54; 74.977
2494.2Kirillov, Evgueni; Toupet, Loic; Lehmann, Christian W.; Razavi, Abbas; Kahlal, Samia; Saillard, Jean-Yves; Carpentier, Jean-François
[(Cp-CMe~2~-Flu)~2~Ln]^-^[Li(ether)n]^+^ (Ln = Y, La): Complexes with Unusual Coordination Modes of the Fluorenyl Ligand and the First Examples of Bis-Ansa Lanthanidocenes
Organometallics, 2003, 22, 4038-4046
4062096 CIFC30 H10 B F15 O2 TiP 1 21/n 117.0009; 10.3704; 15.9342
90; 102.085; 90
2747Choukroun, Robert; Lorber, Christian; Lepetit, Christine; Donnadieu, Bruno
Reactivity of [Cp~2~Ti(CO)~2~] and B(C~6~F~5~)^3^: Formation of the Acylborane Complexes [Cp2Ti(CO)(η^2^-OCB(C~6~F~5~)~3~)] and [Cp~2~Ti(THF)(η^2^-OCB(C~6~F~5~)~3~)]
Organometallics, 2003, 22, 1995-1997
4062097 CIFC33 H18 B F15 O2 TiP 1 21/c 19.1752; 21.0776; 15.6338
90; 93.386; 90
3018.2Choukroun, Robert; Lorber, Christian; Lepetit, Christine; Donnadieu, Bruno
Reactivity of [Cp~2~Ti(CO)~2~] and B(C~6~F~5~)^3^: Formation of the Acylborane Complexes [Cp2Ti(CO)(η^2^-OCB(C~6~F~5~)~3~)] and [Cp~2~Ti(THF)(η^2^-OCB(C~6~F~5~)~3~)]
Organometallics, 2003, 22, 1995-1997
4062098 CIFC10 H18 Ge P2C 1 2/c 131.926; 6.0639; 21.46
90; 113.481; 90
3810.6Francis, Matthew D.; Hitchcock, Peter B.
Studies of the 24-Electronnido-5-Vertex Clusters [M(η^4^-P~2~C~2~Bu^t^~2~)] (M = Ge, Pb, Sn): Synthesis and Characterization of [M(η^4^-P~2~C~2~Bu^t^~2~)] (M = Ge, Pb), [Sn(η^4^-P~2~C~2~Bu^t^~2~){W(CO)~5~}~n~] (n= 1, 2), and [I~2~GeP~2~C~2~Bu^t^~2~] and the Mössbauer Spectrum of [Sn(η^4^-P~2~C~2~Bu^t^~2~)]}
Organometallics, 2003, 22, 2891-2896
4062099 CIFC10 H18 P2 PbC 1 2/c 119.824; 6.0564; 10.6501
90; 96.014; 90
1271.64Francis, Matthew D.; Hitchcock, Peter B.
Studies of the 24-Electronnido-5-Vertex Clusters [M(η^4^-P~2~C~2~Bu^t^~2~)] (M = Ge, Pb, Sn): Synthesis and Characterization of [M(η^4^-P~2~C~2~Bu^t^~2~)] (M = Ge, Pb), [Sn(η^4^-P~2~C~2~Bu^t^~2~){W(CO)~5~}~n~] (n= 1, 2), and [I~2~GeP~2~C~2~Bu^t^~2~] and the Mössbauer Spectrum of [Sn(η^4^-P~2~C~2~Bu^t^~2~)]}
Organometallics, 2003, 22, 2891-2896
4062100 CIFC10 H18 Ge I2 P2P 1 21/n 18.9736; 19.2898; 9.9627
90; 101.919; 90
1687.35Francis, Matthew D.; Hitchcock, Peter B.
Studies of the 24-Electronnido-5-Vertex Clusters [M(η^4^-P~2~C~2~Bu^t^~2~)] (M = Ge, Pb, Sn): Synthesis and Characterization of [M(η^4^-P~2~C~2~Bu^t^~2~)] (M = Ge, Pb), [Sn(η^4^-P~2~C~2~Bu^t^~2~){W(CO)~5~}~n~] (n= 1, 2), and [I~2~GeP~2~C~2~Bu^t^~2~] and the Mössbauer Spectrum of [Sn(η^4^-P~2~C~2~Bu^t^~2~)]}
Organometallics, 2003, 22, 2891-2896
4062110 CIFC20 H22 Cl2 N2 TiP -17.211; 10.872; 14.069
98.41; 102.31; 106.73
1006.4Martins, Ana M.; Ascenso, José R.; de Azevedo, Cristina G.; Dias, Alberto R.; Duarte, M. Teresa; da Silva, João F.; Veiros, Luís F.; Rodrigues, Sandra S.
Insertion of Isocyanides into Group 4 Metal-Carbon and Metal-Nitrogen Bonds. Syntheses and DFT Calculations
Organometallics, 2003, 22, 4218-4228
4062111 CIFC62 H74 Cl2 N8 Zr2P 1 21 112.505; 15.839; 17.342
90; 90.113; 90
3434.9Martins, Ana M.; Ascenso, José R.; de Azevedo, Cristina G.; Dias, Alberto R.; Duarte, M. Teresa; da Silva, João F.; Veiros, Luís F.; Rodrigues, Sandra S.
Insertion of Isocyanides into Group 4 Metal-Carbon and Metal-Nitrogen Bonds. Syntheses and DFT Calculations
Organometallics, 2003, 22, 4218-4228
4062120 CIFC17 H8 Cl Ir N2 O5 WP 21 21 217.337; 17.05; 6.905
90; 90; 90
2041.1Pizzotti, Maddalena; Ugo, Renato; Dragonetti, Claudia; Annoni, Elisabetta; Demartin, Francesco; Mussini, Patrizia
Unexpected Formation of a Weak Metal-Metal Bond: Synthesis, Electronic Properties, and Second-Order NLO Responses of Push-Pull Late-Early Heteronuclear Bimetallic Complexes with W(CO)~3~(1,10-phenanthroline) Acting as a Donor Ligand
Organometallics, 2003, 22, 4001-4011
4062121 CIFC18 H8 Cl2 N2 O6 Os WP -17.3963; 11.3377; 12.3266
83.58; 88.5; 82
1017.1Pizzotti, Maddalena; Ugo, Renato; Dragonetti, Claudia; Annoni, Elisabetta; Demartin, Francesco; Mussini, Patrizia
Unexpected Formation of a Weak Metal-Metal Bond: Synthesis, Electronic Properties, and Second-Order NLO Responses of Push-Pull Late-Early Heteronuclear Bimetallic Complexes with W(CO)~3~(1,10-phenanthroline) Acting as a Donor Ligand
Organometallics, 2003, 22, 4001-4011
4062124 CIFC42 H84 Ge2 O2 Si8P 1 21/c 113.5817; 19.9366; 22.2808
90; 105.339; 90
5818.1Sweeder, Ryan D.; Gdula, Robyn L.; Ludwig, Bonnie J.; Banaszak Holl, Mark M.; Kampf, Jeff W.
Germylene Reactions with Quinones Shed Light on Germylene Phenone Equilibria
Organometallics, 2003, 22, 3222-3229
4062125 CIFC38 H86 Ge2 O2 Si8P -111.7386; 14.3887; 17.836
105.651; 95.873; 111.857
2622.1Sweeder, Ryan D.; Gdula, Robyn L.; Ludwig, Bonnie J.; Banaszak Holl, Mark M.; Kampf, Jeff W.
Germylene Reactions with Quinones Shed Light on Germylene Phenone Equilibria
Organometallics, 2003, 22, 3222-3229
4062126 CIFC44 H88 Ge2 O2 Si8C 1 2/c 129.688; 8.9521; 21.891
90; 94.9; 90
5796.7Sweeder, Ryan D.; Gdula, Robyn L.; Ludwig, Bonnie J.; Banaszak Holl, Mark M.; Kampf, Jeff W.
Germylene Reactions with Quinones Shed Light on Germylene Phenone Equilibria
Organometallics, 2003, 22, 3222-3229
4062127 CIFC22 H46 Ge N2 O2 Si4P -110.106; 11.2113; 13.9057
73.961; 85.505; 76.761
1473.8Sweeder, Ryan D.; Gdula, Robyn L.; Ludwig, Bonnie J.; Banaszak Holl, Mark M.; Kampf, Jeff W.
Germylene Reactions with Quinones Shed Light on Germylene Phenone Equilibria
Organometallics, 2003, 22, 3222-3229
4062130 CIFC46 H74 N6 ZrP 21 21 212.399; 19.467; 9.607
90; 90; 90
2318.9Benetollo, Franco; Carta, Giovanni; Cavinato, Gianni; Crociani, Laura; Paolucci, Gino; Rossetto, Gilberto; Veronese, Francesco; Zanella, Pierino
New η^2^-formamidinyl Zr Complexes: Synthesis, Characterization and Catalytic activity
Organometallics, 2003, 22, 3985-3990
4062134 CIFC30 H23 Cl3 Mo N2 O3P 21 21 2119.693; 10.35; 13.524
90; 90; 90
2756.5Morales, Dolores; Navarro Clemente, M. Elena; Pérez, Julio; Riera, Lucía; Riera, Víctor; Miguel, Daniel
Reactivity of [MCl(η^3^-allyl)(1,10-phenanthroline)(CO)2] (M = Mo, W) Complexes toward Enolate Anions
Organometallics, 2003, 22, 4124-4128
4062135 CIFC20 H17 Mo N3 O2I 41/a :221.663; 21.663; 15.609
90; 90; 90
7325.1Morales, Dolores; Navarro Clemente, M. Elena; Pérez, Julio; Riera, Lucía; Riera, Víctor; Miguel, Daniel
Reactivity of [MCl(η^3^-allyl)(1,10-phenanthroline)(CO)2] (M = Mo, W) Complexes toward Enolate Anions
Organometallics, 2003, 22, 4124-4128
4062139 CIFC66 H62 Cl2 Fe P4 PdP 1 21/c 113.682; 21.928; 27.427
90; 97.865; 90
8151Hierso, Jean-Cyrille; Fihri, Aziz; Amardeil, Régine; Meunier, Philippe; Doucet, Henri; Santelli, Maurice; Donnadieu, Bruno
A Palladium-Ferrocenyl Tetraphosphine System as Catalyst for Suzuki Cross-Coupling and Heck Vinylation of Aryl Halides: Dynamic Behavior of the Palladium/Phosphine Species.
Organometallics, 2003, 22, 4490-4499
4062140 CIFC68 H64 Cl10 Fe P4 Pd2P 1 21/n 114.288; 22.874; 21.427
90; 105.951; 90
6733Hierso, Jean-Cyrille; Fihri, Aziz; Amardeil, Régine; Meunier, Philippe; Doucet, Henri; Santelli, Maurice; Donnadieu, Bruno
A Palladium-Ferrocenyl Tetraphosphine System as Catalyst for Suzuki Cross-Coupling and Heck Vinylation of Aryl Halides: Dynamic Behavior of the Palladium/Phosphine Species.
Organometallics, 2003, 22, 4490-4499
4062158 CIFC49 H53 GaP -110.392; 11.269; 17.06
87.299; 80.598; 82.705
1954.4Wehmschulte, Rudolf J.; Steele, Jared M.; Khan, Masood A.
Diterphenylgallium Alkyls and Hydride: Synthesis, Characterization, and Reactivity
Organometallics, 2003, 22, 4678-4684
4062159 CIFC55 H66 GaP -111.755; 12.046; 18.668
95.977; 104.66; 114.229
2266.5Wehmschulte, Rudolf J.; Steele, Jared M.; Khan, Masood A.
Diterphenylgallium Alkyls and Hydride: Synthesis, Characterization, and Reactivity
Organometallics, 2003, 22, 4678-4684
4062160 CIFC48 H51 Ga O0.3F d d 220.7761; 42.558; 8.3874
90; 90; 90
7416.1Wehmschulte, Rudolf J.; Steele, Jared M.; Khan, Masood A.
Diterphenylgallium Alkyls and Hydride: Synthesis, Characterization, and Reactivity
Organometallics, 2003, 22, 4678-4684
4062161 CIFC48 H52 Cl2 Ga2 O2P b c a18.1341; 20.0259; 23.747
90; 90; 90
8623.8Wehmschulte, Rudolf J.; Steele, Jared M.; Khan, Masood A.
Diterphenylgallium Alkyls and Hydride: Synthesis, Characterization, and Reactivity
Organometallics, 2003, 22, 4678-4684
4062162 CIFC50 H58 Ga2 O2P 1 21/c 121.965; 9.087; 24.186
90; 114.337; 90
4398.3Wehmschulte, Rudolf J.; Steele, Jared M.; Khan, Masood A.
Diterphenylgallium Alkyls and Hydride: Synthesis, Characterization, and Reactivity
Organometallics, 2003, 22, 4678-4684
4062163 CIFC48 H51 Ga O0.7P 21 21 2111.8097; 15.7004; 20.7826
90; 90; 90
3853.4Wehmschulte, Rudolf J.; Steele, Jared M.; Khan, Masood A.
Diterphenylgallium Alkyls and Hydride: Synthesis, Characterization, and Reactivity
Organometallics, 2003, 22, 4678-4684
4062164 CIFC21 H16 Cl F6 N4 O Os PC 1 2/c 115.518; 13.419; 12.663
90; 111.07; 90
2460.6Gobetto, Roberto; Nervi, Carlo; Romanin, Barbara; Salassa, Luca; Milanesio, Marco; Croce, Gianluca
X-ray Structures and Complete NMR Assignment by DFT Calculations of [Os(bpy)~2~(CO)Cl]PF~6~ and [Os(bpy)~2~(CO)H]PF~6~ Complexes
Organometallics, 2003, 22, 4012-4019
4062165 CIFC21 H17 F6 N4 O Os PP -18.704; 9.959; 13.113
91.9; 97.53; 93.08
1124.3Gobetto, Roberto; Nervi, Carlo; Romanin, Barbara; Salassa, Luca; Milanesio, Marco; Croce, Gianluca
X-ray Structures and Complete NMR Assignment by DFT Calculations of [Os(bpy)~2~(CO)Cl]PF~6~ and [Os(bpy)~2~(CO)H]PF~6~ Complexes
Organometallics, 2003, 22, 4012-4019
4062168 CIFC35 H22 Co4 O10 P2P -110.2475; 11.6675; 16.3918
74.426; 89.208; 72.497
1795.7Choualeb, Aldjia; Braunstein, Pierre; Rosé, Jacky; Bouaoud, Salah-Eddine; Welter, Richard
Reactions of Diphosphine-Stabilized Tetracobalt Carbonyl Clusters with -Si(OR)~3~-Functionalized Alkynes
Organometallics, 2003, 22, 4405-4417
4062169 CIFC41 H28 Co4 O8 P2P -111.139; 11.258; 17.036
83.81; 77.82; 65.28
1896.5Choualeb, Aldjia; Braunstein, Pierre; Rosé, Jacky; Bouaoud, Salah-Eddine; Welter, Richard
Reactions of Diphosphine-Stabilized Tetracobalt Carbonyl Clusters with -Si(OR)~3~-Functionalized Alkynes
Organometallics, 2003, 22, 4405-4417

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