Crystallography Open Database

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7237137 CIFC9 H6 N8 O8P 1 21/n 19.4365; 11.5612; 12.9442
90; 92.305; 90
1411Tang, Yongxing; He, Chunlin; Imler, Gregory H.; Parrish, Damon A.; Shreeve, Jean'ne M.
Ring closure of polynitroazoles via an N,N′-alkylene bridge: towards high thermally stable energetic compounds
Journal of Materials Chemistry A, 2018, 6, 8382
7237138 CIFC7 H6 N8 O4P 1 21/n 19.6012; 11.5875; 9.794
90; 96.837; 90
1081.87Tang, Yongxing; He, Chunlin; Imler, Gregory H.; Parrish, Damon A.; Shreeve, Jean'ne M.
Ring closure of polynitroazoles via an N,N′-alkylene bridge: towards high thermally stable energetic compounds
Journal of Materials Chemistry A, 2018, 6, 8382
7237139 CIFC6 H4 N8 O4C 1 2/c 112.326; 6.678; 12.126
90; 104.517; 90
966.3Tang, Yongxing; He, Chunlin; Imler, Gregory H.; Parrish, Damon A.; Shreeve, Jean'ne M.
Ring closure of polynitroazoles via an N,N′-alkylene bridge: towards high thermally stable energetic compounds
Journal of Materials Chemistry A, 2018, 6, 8382
7237140 CIFC28 H40 Cl2 Eu2 N2 O20I m a 29.7764; 28.1748; 7.1892
90; 90; 90
1980.25Gong, Teng; Li, Peng; Sui, Qi; Chen, Jinquan; Xu, Jianhua; Gao, En-Qing
A stable electron-deficient metal‒organic framework for colorimetric and luminescence sensing of phenols and anilines
Journal of Materials Chemistry A, 2018, 6, 9236
7237141 CIFC34 H37 Cl2 Eu2 N3 O15I m a 29.7765; 28.3415; 7.1889
90; 90; 90
1991.91Gong, Teng; Li, Peng; Sui, Qi; Chen, Jinquan; Xu, Jianhua; Gao, En-Qing
A stable electron-deficient metal‒organic framework for colorimetric and luminescence sensing of phenols and anilines
Journal of Materials Chemistry A, 2018, 6, 9236
7237142 CIFC54 H42 N15 O5 Zn2P n n a28.6596; 27.8917; 9.55
90; 90; 90
7633.9Fu, Hong-Ru; Yan, Li-Bing; Wu, Nai-Teng; Ma, Lu-Fang; Zang, Shuang-Quan
Dual-emission MOF⊃dye sensor for ratiometric fluorescence recognition of RDX and detection of a broad class of nitro-compounds
Journal of Materials Chemistry A, 2018, 6, 9183
7237143 CIFC22 H24 Cl2 N2 O5 RuP -18.4046; 10.7488; 12.1752
91.608; 95.6; 90.126
1094.21Liao, Wei-Ming; Zhang, Jian-Hua; Wang, Zheng; Yin, Shao-Yun; Pan, Mei; Wang, Hai-Ping; Su, Cheng-Yong
Post-synthetic exchange (PSE) of UiO-67 frameworks with Ru/Rh half-sandwich units for visible-light-driven H2 evolution and CO2 reduction
Journal of Materials Chemistry A, 2018, 6, 11337
7237144 CIFC44 H56 N8 O25 Rh2P 1 21 18.1896; 20.1788; 15.8594
90; 90.44; 90
2620.79Liao, Wei-Ming; Zhang, Jian-Hua; Wang, Zheng; Yin, Shao-Yun; Pan, Mei; Wang, Hai-Ping; Su, Cheng-Yong
Post-synthetic exchange (PSE) of UiO-67 frameworks with Ru/Rh half-sandwich units for visible-light-driven H2 evolution and CO2 reduction
Journal of Materials Chemistry A, 2018, 6, 11337
7237145 CIFC16 H12 F2 O2 S2P 1 21/n 15.5646; 6.9441; 18.902
90; 98.039; 90
723.22Li, Shuixing; Zhan, Lingling; Zhao, Wenchao; Zhang, Shuhua; Ali, Basharat; Fu, Zhisheng; Lau, Tsz-Ki; Lu, Xinhui; Shi, Minmin; Li, Chang-Zhi; Hou, Jianhui; Chen, Hongzheng
Revealing the effects of molecular packing on the performances of polymer solar cells based on A‒D‒C‒D‒A type non-fullerene acceptors
Journal of Materials Chemistry A, 2018, 6, 12132
7237146 CIFC8 H22 B12 Cu I12 N6C 1 2/m 116.9343; 12.3926; 11.305
90; 120.836; 90
2037.1Chinnam, Ajay Kumar; Petrutik, Natan; Wang, Kangcai; Shlomovich, Avital; Shamis, Olga; Tov, Daniel Shem; Sućeska, Muhamed; Yan, Qi-Long; Dobrovetsky, Roman; Gozin, Michael
Effects of closo-icosahedral periodoborane salts on hypergolic reactions of 70% H2O2 with energetic ionic liquids
Journal of Materials Chemistry A, 2018, 6, 19989
7237147 CIFC30 H44 B12 Fe2 I12 N2P -110.9499; 12.057; 12.3471
61.337; 69.03; 81.237
1335.24Chinnam, Ajay Kumar; Petrutik, Natan; Wang, Kangcai; Shlomovich, Avital; Shamis, Olga; Tov, Daniel Shem; Sućeska, Muhamed; Yan, Qi-Long; Dobrovetsky, Roman; Gozin, Michael
Effects of closo-icosahedral periodoborane salts on hypergolic reactions of 70% H2O2 with energetic ionic liquids
Journal of Materials Chemistry A, 2018, 6, 19989
7237148 CIFC84 H66 In3 N O25P 63/m c m15.306; 15.306; 28.885
90; 90; 120
5860.4Liu, Xinyao; Liu, Bing; Li, Guanghua; Liu, Yunling
Two anthracene-based metal‒organic frameworks for highly effective photodegradation and luminescent detection in water
Journal of Materials Chemistry A, 2018, 6, 17177
7237149 CIFC217 H237 Eu6 N19 O53F m -3 m33.816; 33.816; 33.816
90; 90; 90
38669Liu, Xinyao; Liu, Bing; Li, Guanghua; Liu, Yunling
Two anthracene-based metal‒organic frameworks for highly effective photodegradation and luminescent detection in water
Journal of Materials Chemistry A, 2018, 6, 17177
7237150 CIFC10 H14 Cu N2 O6C 1 2/c 124.153; 13.12; 8.6
90; 92.537; 90
2722.6Cepeda, Javier; Pérez-Mendoza, Manuel; Calahorro, Antonio J.; Casati, Nicola; Seco, José Manuel; Aragones-Anglada, Marta; Moghadam, Peyman Z.; Fairen-Jimenez, David; Rodríguez-Diéguez, Antonio
Modulation of pore shape and adsorption selectivity by ligand functionalization in a series of “rob”-like flexible metal‒organic frameworks
Journal of Materials Chemistry A, 2018, 6, 17409
7237151 CIFC13 H19 Cu N2 O6C 1 2/c 127.253; 13.608; 9.146
90; 92.81; 90
3387.8Cepeda, Javier; Pérez-Mendoza, Manuel; Calahorro, Antonio J.; Casati, Nicola; Seco, José Manuel; Aragones-Anglada, Marta; Moghadam, Peyman Z.; Fairen-Jimenez, David; Rodríguez-Diéguez, Antonio
Modulation of pore shape and adsorption selectivity by ligand functionalization in a series of “rob”-like flexible metal‒organic frameworks
Journal of Materials Chemistry A, 2018, 6, 17409
7237152 CIFC24 H36 Cu2 N4 O13C 1 2/c 127.019; 13.506; 8.921
90; 94.792; 90
3244Cepeda, Javier; Pérez-Mendoza, Manuel; Calahorro, Antonio J.; Casati, Nicola; Seco, José Manuel; Aragones-Anglada, Marta; Moghadam, Peyman Z.; Fairen-Jimenez, David; Rodríguez-Diéguez, Antonio
Modulation of pore shape and adsorption selectivity by ligand functionalization in a series of “rob”-like flexible metal‒organic frameworks
Journal of Materials Chemistry A, 2018, 6, 17409
7237153 CIFC22 H28 Cu2 N4 O13C 1 2/c 126.9173; 12.987; 8.574
90; 104.82; 90
2897.5Cepeda, Javier; Pérez-Mendoza, Manuel; Calahorro, Antonio J.; Casati, Nicola; Seco, José Manuel; Aragones-Anglada, Marta; Moghadam, Peyman Z.; Fairen-Jimenez, David; Rodríguez-Diéguez, Antonio
Modulation of pore shape and adsorption selectivity by ligand functionalization in a series of “rob”-like flexible metal‒organic frameworks
Journal of Materials Chemistry A, 2018, 6, 17409
7237154 CIFC48 H36 Cu4 N12 O12P 326.0992; 26.0992; 9.2584
90; 90; 120
5461.61Li, Ziyin; Ye, Yingxiang; Yao, Zizhu; Guo, Junzhi; Lin, Quanjie; Zhang, Jindan; Zhang, Zhangjing; Wei, Fangfang; Xiang, Shengchang
An antiferromagnetic metalloring pyrazolate (Pz) framework with [Cu12(μ2-OH)12(Pz)12] nodes for separation of C2H2/CH4 mixture
Journal of Materials Chemistry A, 2018, 6, 19681
7237155 CIFC8 N14 O20P 1 21/n 19.7746; 10.4557; 19.049
90; 91.034; 90
1946.5Dalinger, Igor L.; Suponitsky, Kyrill Yu.; Shkineva, Tatyana K.; Lempert, David B.; Sheremetev, Aleksei B.
Bipyrazole bearing ten nitro groups ‒ a novel highly dense oxidizer for forward-looking rocket propulsions
Journal of Materials Chemistry A, 2018, 6, 14780
7237156 CIFC8 N14 O20P 1 21/n 19.9011; 10.5386; 19.291
90; 91.071; 90
2012.5Dalinger, Igor L.; Suponitsky, Kyrill Yu.; Shkineva, Tatyana K.; Lempert, David B.; Sheremetev, Aleksei B.
Bipyrazole bearing ten nitro groups ‒ a novel highly dense oxidizer for forward-looking rocket propulsions
Journal of Materials Chemistry A, 2018, 6, 14780
7237157 CIFC2 H12 Ag2 N8 O8I 4/m11.6936; 11.6936; 8.833
90; 90; 90
1207.83Yin, Ping; Yu, Qiong; Dharavath, Srinivas; Shreeve, Jean'ne M.
Taming of tetranitroethane: a promising precursor for high performance energetic ingredients
Journal of Materials Chemistry A, 2018, 6, 15815
7237158 CIFC2 H9 N5 O7P -13.7131; 9.097; 12.626
108.745; 96.5; 98.409
393.6Yin, Ping; Yu, Qiong; Dharavath, Srinivas; Shreeve, Jean'ne M.
Taming of tetranitroethane: a promising precursor for high performance energetic ingredients
Journal of Materials Chemistry A, 2018, 6, 15815
7237159 CIFC4 H15 N9 O12P -18.1131; 8.6292; 11.1334
106.97; 93.53; 105.554
709.89Yin, Ping; Yu, Qiong; Dharavath, Srinivas; Shreeve, Jean'ne M.
Taming of tetranitroethane: a promising precursor for high performance energetic ingredients
Journal of Materials Chemistry A, 2018, 6, 15815
7237160 CIFC2 H8 N6 O8P 1 21/n 19.2546; 7.8; 13.1353
90; 107.923; 90
902.17Yin, Ping; Yu, Qiong; Dharavath, Srinivas; Shreeve, Jean'ne M.
Taming of tetranitroethane: a promising precursor for high performance energetic ingredients
Journal of Materials Chemistry A, 2018, 6, 15815
7237161 CIFC36 H76 Cl4 Co6 N18 P6 S8C m c e23.1218; 10.7247; 24.0502
90; 90; 90
5963.8Freeman, Matthew B.; Wang, Le; Jones, Daniel S.; Bejger, Christopher M.
A cobalt sulfide cluster-based catholyte for aqueous flow battery applications
Journal of Materials Chemistry A, 2018, 6, 21927
7237162 CIFC5 H8 N10 O8C 1 2/c 118.9552; 11.1084; 14.2841
90; 126.184; 90
2427.6He, Chunlin; Imler, Gregory H.; Parrish, Damon A.; Shreeve, Jean'ne M.
Energetic salts of 4-nitramino-3-(5-dinitromethyl-1,2,4-oxadiazolyl)-furazan: powerful alliance towards good thermal stability and high performance
Journal of Materials Chemistry A, 2018, 6, 16833
7237163 CIFC96 H48 Cl2 Cu4.5 N40 O0.5P 1 2/m 116.9552; 19.4089; 18.5986
90; 99.771; 90
6031.7Wang, Zheng; Zhang, Jian-Hua; Jiang, Ji-Jun; Wang, Hai-Ping; Wei, Zhang-Wen; Zhu, Xunjin; Pan, Mei; Su, Cheng-Yong
A stable metal cluster-metalloporphyrin MOF with high capacity for cationic dye removal
Journal of Materials Chemistry A, 2018, 6, 17698
7237164 CIFC28 H18 B F5 N2 O4P -19.4718; 9.4932; 13.4657
91.53; 91.845; 108.004
1150.06Li, Tian-yi; Benduhn, Johannes; Li, Yue; Jaiser, Frank; Spoltore, Donato; Zeika, Olaf; Ma, Zaifei; Neher, Dieter; Vandewal, Koen; Leo, Karl
Boron dipyrromethene (BODIPY) with meso-perfluorinated alkyl substituents as near infrared donors in organic solar cells
Journal of Materials Chemistry A, 2018, 6, 18583
7237165 CIFC29 H18 B F7 N2 O4P -17.6728; 12.677; 13.41465
102.618; 90.338; 100.899
1248.82Li, Tian-yi; Benduhn, Johannes; Li, Yue; Jaiser, Frank; Spoltore, Donato; Zeika, Olaf; Ma, Zaifei; Neher, Dieter; Vandewal, Koen; Leo, Karl
Boron dipyrromethene (BODIPY) with meso-perfluorinated alkyl substituents as near infrared donors in organic solar cells
Journal of Materials Chemistry A, 2018, 6, 18583
7237166 CIFC30 H18 B F9 N2 O4P -111.7774; 15.2002; 17.0421
93.918; 105.682; 97.023
2898.8Li, Tian-yi; Benduhn, Johannes; Li, Yue; Jaiser, Frank; Spoltore, Donato; Zeika, Olaf; Ma, Zaifei; Neher, Dieter; Vandewal, Koen; Leo, Karl
Boron dipyrromethene (BODIPY) with meso-perfluorinated alkyl substituents as near infrared donors in organic solar cells
Journal of Materials Chemistry A, 2018, 6, 18583
7237167 CIFC4 H16 Cl2 Cu N20 O10P 42/n :210.3883; 10.3883; 10.0967
90; 90; 90
1089.6Szimhardt, Norbert; Wurzenberger, Maximilian H. H.; Zeisel, Lukas; Gruhne, Michael S.; Lommel, Marcus; Stierstorfer, Jörg
Maximization of the energy capability level in transition metal complexes through application of 1-amino- and 2-amino-5H-tetrazole ligands
Journal of Materials Chemistry A, 2018, 6, 16257
7237168 CIFC6 H18 Cl2 Cu N30 O8P -321.8207; 21.8207; 6.9043
90; 90; 120
2847Szimhardt, Norbert; Wurzenberger, Maximilian H. H.; Zeisel, Lukas; Gruhne, Michael S.; Lommel, Marcus; Stierstorfer, Jörg
Maximization of the energy capability level in transition metal complexes through application of 1-amino- and 2-amino-5H-tetrazole ligands
Journal of Materials Chemistry A, 2018, 6, 16257
7237169 CIFC4 H16 Cl2 Mn N20 O10P -17.898; 9.618; 15.771
78.554; 76.267; 73.23
1103.34Szimhardt, Norbert; Wurzenberger, Maximilian H. H.; Zeisel, Lukas; Gruhne, Michael S.; Lommel, Marcus; Stierstorfer, Jörg
Maximization of the energy capability level in transition metal complexes through application of 1-amino- and 2-amino-5H-tetrazole ligands
Journal of Materials Chemistry A, 2018, 6, 16257
7237170 CIFC H3 N5P 21 21 215.0889; 6.5662; 11.1652
90; 90; 90
373.08Szimhardt, Norbert; Wurzenberger, Maximilian H. H.; Zeisel, Lukas; Gruhne, Michael S.; Lommel, Marcus; Stierstorfer, Jörg
Maximization of the energy capability level in transition metal complexes through application of 1-amino- and 2-amino-5H-tetrazole ligands
Journal of Materials Chemistry A, 2018, 6, 16257
7237171 CIFC5 H17 Cl2 Fe N25 O9P -19.477; 9.9109; 15.4054
75.695; 89.058; 63.694
1249.66Szimhardt, Norbert; Wurzenberger, Maximilian H. H.; Zeisel, Lukas; Gruhne, Michael S.; Lommel, Marcus; Stierstorfer, Jörg
Maximization of the energy capability level in transition metal complexes through application of 1-amino- and 2-amino-5H-tetrazole ligands
Journal of Materials Chemistry A, 2018, 6, 16257
7237172 CIFC2 H6 Cl2 Cu N10P 1 21/c 16.8468; 3.6679; 18.5122
90; 91.579; 90
464.73Szimhardt, Norbert; Wurzenberger, Maximilian H. H.; Zeisel, Lukas; Gruhne, Michael S.; Lommel, Marcus; Stierstorfer, Jörg
Maximization of the energy capability level in transition metal complexes through application of 1-amino- and 2-amino-5H-tetrazole ligands
Journal of Materials Chemistry A, 2018, 6, 16257
7237173 CIFC8 H24 Cl2 N40 O8 ZnP -18.5016; 10.8035; 19.2662
79.175; 86.1; 86.315
1731.63Szimhardt, Norbert; Wurzenberger, Maximilian H. H.; Zeisel, Lukas; Gruhne, Michael S.; Lommel, Marcus; Stierstorfer, Jörg
Maximization of the energy capability level in transition metal complexes through application of 1-amino- and 2-amino-5H-tetrazole ligands
Journal of Materials Chemistry A, 2018, 6, 16257
7237174 CIFC6 H18 Cl2 Fe N30 O8P -318.8934; 18.8934; 6.983
90; 90; 120
2158.7Szimhardt, Norbert; Wurzenberger, Maximilian H. H.; Zeisel, Lukas; Gruhne, Michael S.; Lommel, Marcus; Stierstorfer, Jörg
Maximization of the energy capability level in transition metal complexes through application of 1-amino- and 2-amino-5H-tetrazole ligands
Journal of Materials Chemistry A, 2018, 6, 16257
7237175 CIFC8 H24 Cl2 Fe N40 O8P -18.515; 10.83; 19.305
79.072; 86.098; 86.476
1741.78Szimhardt, Norbert; Wurzenberger, Maximilian H. H.; Zeisel, Lukas; Gruhne, Michael S.; Lommel, Marcus; Stierstorfer, Jörg
Maximization of the energy capability level in transition metal complexes through application of 1-amino- and 2-amino-5H-tetrazole ligands
Journal of Materials Chemistry A, 2018, 6, 16257
7237176 CIFC6 H18 N32 O6 ZnP 1 21/n 19.4477; 7.9116; 17.279
90; 90.61; 90
1291.5Szimhardt, Norbert; Wurzenberger, Maximilian H. H.; Zeisel, Lukas; Gruhne, Michael S.; Lommel, Marcus; Stierstorfer, Jörg
Maximization of the energy capability level in transition metal complexes through application of 1-amino- and 2-amino-5H-tetrazole ligands
Journal of Materials Chemistry A, 2018, 6, 16257
7237177 CIFC H4 Cl N5 O4P 1 21/n 15.5236; 8.3025; 13.6929
90; 90.247; 90
627.95Szimhardt, Norbert; Wurzenberger, Maximilian H. H.; Zeisel, Lukas; Gruhne, Michael S.; Lommel, Marcus; Stierstorfer, Jörg
Maximization of the energy capability level in transition metal complexes through application of 1-amino- and 2-amino-5H-tetrazole ligands
Journal of Materials Chemistry A, 2018, 6, 16257
7237178 CIFC6 H18 Cl2 N30 O8 ZnP -318.908; 18.908; 6.992
90; 90; 120
2164.8Szimhardt, Norbert; Wurzenberger, Maximilian H. H.; Zeisel, Lukas; Gruhne, Michael S.; Lommel, Marcus; Stierstorfer, Jörg
Maximization of the energy capability level in transition metal complexes through application of 1-amino- and 2-amino-5H-tetrazole ligands
Journal of Materials Chemistry A, 2018, 6, 16257
7237179 CIFC6 H18 Cl2 Cu N30 O6P 1 21/n 19.6517; 7.888; 17.1904
90; 93.923; 90
1305.68Szimhardt, Norbert; Wurzenberger, Maximilian H. H.; Zeisel, Lukas; Gruhne, Michael S.; Lommel, Marcus; Stierstorfer, Jörg
Maximization of the energy capability level in transition metal complexes through application of 1-amino- and 2-amino-5H-tetrazole ligands
Journal of Materials Chemistry A, 2018, 6, 16257
7237180 CIFC8 H24 Cl2 Cu N40 O8P -110.3015; 10.866; 16.4236
80.433; 73.574; 80.646
1725.8Szimhardt, Norbert; Wurzenberger, Maximilian H. H.; Zeisel, Lukas; Gruhne, Michael S.; Lommel, Marcus; Stierstorfer, Jörg
Maximization of the energy capability level in transition metal complexes through application of 1-amino- and 2-amino-5H-tetrazole ligands
Journal of Materials Chemistry A, 2018, 6, 16257
7237181 CIFC2 H6 Cu N12 O6P 1 21/n 17.9953; 8.9746; 8.0033
90; 107.469; 90
547.79Szimhardt, Norbert; Wurzenberger, Maximilian H. H.; Zeisel, Lukas; Gruhne, Michael S.; Lommel, Marcus; Stierstorfer, Jörg
Maximization of the energy capability level in transition metal complexes through application of 1-amino- and 2-amino-5H-tetrazole ligands
Journal of Materials Chemistry A, 2018, 6, 16257
7237182 CIFC3 H9 Cu N17 O6C 1 c 115.301; 6.684; 15.203
90; 106.027; 90
1494.4Szimhardt, Norbert; Wurzenberger, Maximilian H. H.; Zeisel, Lukas; Gruhne, Michael S.; Lommel, Marcus; Stierstorfer, Jörg
Maximization of the energy capability level in transition metal complexes through application of 1-amino- and 2-amino-5H-tetrazole ligands
Journal of Materials Chemistry A, 2018, 6, 16257
7237183 CIFC2 H6 Cl2 Cu N10P 1 21/n 17.4976; 12.2023; 10.3115
90; 91.719; 90
942.95Szimhardt, Norbert; Wurzenberger, Maximilian H. H.; Zeisel, Lukas; Gruhne, Michael S.; Lommel, Marcus; Stierstorfer, Jörg
Maximization of the energy capability level in transition metal complexes through application of 1-amino- and 2-amino-5H-tetrazole ligands
Journal of Materials Chemistry A, 2018, 6, 16257
7237184 CIFC5 H17 Cl2 N25 O9 ZnP -19.4977; 9.9017; 15.3665
75.918; 89.336; 63.584
1247.54Szimhardt, Norbert; Wurzenberger, Maximilian H. H.; Zeisel, Lukas; Gruhne, Michael S.; Lommel, Marcus; Stierstorfer, Jörg
Maximization of the energy capability level in transition metal complexes through application of 1-amino- and 2-amino-5H-tetrazole ligands
Journal of Materials Chemistry A, 2018, 6, 16257
7237185 CIFC14 H22 Mn N16 O24P 1 21/c 114.8973; 5.0185; 20.4159
90; 103.628; 90
1483.36Szimhardt, Norbert; Wurzenberger, Maximilian H. H.; Zeisel, Lukas; Gruhne, Michael S.; Lommel, Marcus; Stierstorfer, Jörg
Maximization of the energy capability level in transition metal complexes through application of 1-amino- and 2-amino-5H-tetrazole ligands
Journal of Materials Chemistry A, 2018, 6, 16257
7237186 CIFC14 H22 Mn N16 O22P 1 21/c 114.704; 5.049; 20.468
90; 103.858; 90
1475.32Szimhardt, Norbert; Wurzenberger, Maximilian H. H.; Zeisel, Lukas; Gruhne, Michael S.; Lommel, Marcus; Stierstorfer, Jörg
Maximization of the energy capability level in transition metal complexes through application of 1-amino- and 2-amino-5H-tetrazole ligands
Journal of Materials Chemistry A, 2018, 6, 16257

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