Crystallography Open Database

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4063195 CIFC18 H4 As Cl F18P 21 21 218.6646; 9.6965; 25.4076
90; 90; 90
2134.65Neil Burford; Charles L. B. Macdonald; Daren J. LeBlanc; T. Stanley Cameron
Synthesis and Characterization of Bis(2,4,6-tris(trifluoromethyl)phenyl) Derivatives of Arsenic and Antimony: X-ray Crystal Structures of As(RF)2Cl, Sb(RF)2Cl, and Sb(RF)2OSO2CF3
Organometallics, 2000, 19, 152-155
4063196 CIFC18 H4 As Cl F18P 1 21/a 18.705; 30.38; 8.167
90; 91.53; 90
2159Neil Burford; Charles L. B. Macdonald; Daren J. LeBlanc; T. Stanley Cameron
Synthesis and Characterization of Bis(2,4,6-tris(trifluoromethyl)phenyl) Derivatives of Arsenic and Antimony: X-ray Crystal Structures of As(RF)2Cl, Sb(RF)2Cl, and Sb(RF)2OSO2CF3
Organometallics, 2000, 19, 152-155
4063197 CIFC18 H4 Cl F18 SbP 1 21/c 18.296; 30.43; 8.779
90; 94.03; 90
2211Neil Burford; Charles L. B. Macdonald; Daren J. LeBlanc; T. Stanley Cameron
Synthesis and Characterization of Bis(2,4,6-tris(trifluoromethyl)phenyl) Derivatives of Arsenic and Antimony: X-ray Crystal Structures of As(RF)2Cl, Sb(RF)2Cl, and Sb(RF)2OSO2CF3
Organometallics, 2000, 19, 152-155
4063198 CIFC19 H4 F21 O3 S SbP 21 21 2116.172; 17.758; 9.119
90; 90; 90
2618.8Neil Burford; Charles L. B. Macdonald; Daren J. LeBlanc; T. Stanley Cameron
Synthesis and Characterization of Bis(2,4,6-tris(trifluoromethyl)phenyl) Derivatives of Arsenic and Antimony: X-ray Crystal Structures of As(RF)2Cl, Sb(RF)2Cl, and Sb(RF)2OSO2CF3
Organometallics, 2000, 19, 152-155
4063201 CIFC58 H64 N4 Na2 O4 YbP -110.758; 10.987; 24.968
91.809; 96.237; 116.248
2621Tiffany Dube; Dominique Freckmann; Sabrina Conoci; Sandro Gambarotta; Glenn P. A. Yap
Monomeric and Octameric Divalent Ytterbium Complexes of Diphenylmethyl Dipyrrolyl Dianion
Organometallics, 2000, 19, 209-211
4063202 CIFC240 H272 Cl2 Li2 N16 O18 Yb8P -117.254; 19.145; 19.659
61.167; 84.757; 74.114
5465Tiffany Dube; Dominique Freckmann; Sabrina Conoci; Sandro Gambarotta; Glenn P. A. Yap
Monomeric and Octameric Divalent Ytterbium Complexes of Diphenylmethyl Dipyrrolyl Dianion
Organometallics, 2000, 19, 209-211
4063203 CIFC34 H38 Co2 O4P 1 21/n 19.595; 13.832; 10.998
90; 107.96; 90
1388.5Rolf Gleiter; Rolf Roers; Jörg Classen; Albrecht Jacobi; Gottfried Huttner; Thomas Oeser
Synthesis and Properties of Donor-Acceptor-Substituted Metal-Capped Fourfold-Bridged Cyclobutadienophanes
Organometallics, 2000, 19, 147-151
4063204 CIFC32 H36 Co2 O2P 1 21/c 120.022; 8.155; 16.421
90; 110.85; 90
2505.7Rolf Gleiter; Rolf Roers; Jörg Classen; Albrecht Jacobi; Gottfried Huttner; Thomas Oeser
Synthesis and Properties of Donor-Acceptor-Substituted Metal-Capped Fourfold-Bridged Cyclobutadienophanes
Organometallics, 2000, 19, 147-151
4063205 CIFC37 H46 Co2 O2P 1 21/n 114.033; 15.803; 14.497
90; 109.59; 90
3028.8Rolf Gleiter; Rolf Roers; Jörg Classen; Albrecht Jacobi; Gottfried Huttner; Thomas Oeser
Synthesis and Properties of Donor-Acceptor-Substituted Metal-Capped Fourfold-Bridged Cyclobutadienophanes
Organometallics, 2000, 19, 147-151
4063206 CIFC36 H28 Fe O5P 1 21/c 110.623; 11.739; 24.887
90; 102.28; 90
3032.4Hari K. Gupta; Nicole Rampersad; Mark Stradiotto; Michael J. McGlinchey
Rhodium Acetylacetonate and Iron Tricarbonyl Complexes of Tetracyclone and 3-Ferrocenyl-2,4,5-triphenylcyclopentadienone: An X-ray Crystallographic and NMR Study
Organometallics, 2000, 19, 184-191
4063207 CIFC36 H24 Fe2 O4P 1 21/n 110.618; 21.506; 12.99
90; 102.332; 90
2897.8Hari K. Gupta; Nicole Rampersad; Mark Stradiotto; Michael J. McGlinchey
Rhodium Acetylacetonate and Iron Tricarbonyl Complexes of Tetracyclone and 3-Ferrocenyl-2,4,5-triphenylcyclopentadienone: An X-ray Crystallographic and NMR Study
Organometallics, 2000, 19, 184-191
4063208 CIFC34 H29 O4 RhP -18.823; 12.404; 15.694
66.929; 81.291; 73.873
1516.2Hari K. Gupta; Nicole Rampersad; Mark Stradiotto; Michael J. McGlinchey
Rhodium Acetylacetonate and Iron Tricarbonyl Complexes of Tetracyclone and 3-Ferrocenyl-2,4,5-triphenylcyclopentadienone: An X-ray Crystallographic and NMR Study
Organometallics, 2000, 19, 184-191
4063209 CIFC38 H31 Fe O3 RhI 1 2/a 120.834; 12.455; 25.752
90; 97.09; 90
6631.2Hari K. Gupta; Nicole Rampersad; Mark Stradiotto; Michael J. McGlinchey
Rhodium Acetylacetonate and Iron Tricarbonyl Complexes of Tetracyclone and 3-Ferrocenyl-2,4,5-triphenylcyclopentadienone: An X-ray Crystallographic and NMR Study
Organometallics, 2000, 19, 184-191
4063212 CIFC20 H38 B4 Ir2P 1 21/n 18.3011; 19.742; 14.552
90; 93.448; 90
2380.5Xinjian Lei; Maoyu Shang; Thomas P. Fehlner
Utilization of Transition-Metal Properties To Control Polyborane Formation. Synthesis of the arachno-Diiridahexaborane(12) 2,5-{Cp*IrH}2B4H8 and Its Conversion to the nido-Diiridahexaborane(10) 1,2-{Cp*Ir}2(-H)B4H7 (Cp* =5-C5Me5)
Organometallics, 2000, 19, 118-120
4063213 CIFC20 H40 B4 Ir2P 41 21 28.7599; 8.7599; 30.4203
90; 90; 90
2334.3Xinjian Lei; Maoyu Shang; Thomas P. Fehlner
Utilization of Transition-Metal Properties To Control Polyborane Formation. Synthesis of the arachno-Diiridahexaborane(12) 2,5-{Cp*IrH}2B4H8 and Its Conversion to the nido-Diiridahexaborane(10) 1,2-{Cp*Ir}2(-H)B4H7 (Cp* =5-C5Me5)
Organometallics, 2000, 19, 118-120
4077455 CIFC39 H50 Bi Cl Mo2 O6P 1 21/n 19.968; 15.862; 26.481
90; 90.56; 90
4186.8Gröer, Thomas; Scheer, Manfred
Transition-Metal-Substituted Dichlorobismuthanes as Starting Materials for Novel Bismuth−Transition-Metal Clusters†
Organometallics, 2000, 19, 3683
4077456 CIFC15 H5 Bi Co2 Fe O10P -17.216; 9.698; 15.022
81.2; 84.06; 71.59
984Gröer, Thomas; Scheer, Manfred
Transition-Metal-Substituted Dichlorobismuthanes as Starting Materials for Novel Bismuth−Transition-Metal Clusters†
Organometallics, 2000, 19, 3683
4077457 CIFC13 H2 Bi4 Cl2 Co4 O12P 1 21/m 19.796; 11.19; 12.212
90; 104.51; 90
1295.9Gröer, Thomas; Scheer, Manfred
Transition-Metal-Substituted Dichlorobismuthanes as Starting Materials for Novel Bismuth−Transition-Metal Clusters†
Organometallics, 2000, 19, 3683
4077458 CIFC39 H42 Bi2 Fe5 O13P -19.654; 9.756; 27.598
83.25; 81.25; 63.9
2303.3Gröer, Thomas; Scheer, Manfred
Transition-Metal-Substituted Dichlorobismuthanes as Starting Materials for Novel Bismuth−Transition-Metal Clusters†
Organometallics, 2000, 19, 3683
4077459 CIFC23 H21 Bi3 Fe O10 W2A b m 217.677; 13.518; 12.95
90; 90; 90
3094.5Gröer, Thomas; Scheer, Manfred
Transition-Metal-Substituted Dichlorobismuthanes as Starting Materials for Novel Bismuth−Transition-Metal Clusters†
Organometallics, 2000, 19, 3683
4077460 CIFC32 H50 Bi Cl7 Mo2 O3P 1 21/n 117.835; 13.276; 18.353
90; 112.88; 90
4003.7Gröer, Thomas; Scheer, Manfred
Transition-Metal-Substituted Dichlorobismuthanes as Starting Materials for Novel Bismuth−Transition-Metal Clusters†
Organometallics, 2000, 19, 3683
4077461 CIFC15 H15 F3 Fe2 N2 O6 SP 1 21/c 18.324; 14.841; 16.296
90; 93.01; 90
2010.4Guennou-de Cadenet, Karine; Rumin, René; Pétillon, François Y.; Muir, Kenneth W.
Carbon−Fluorine Bond Cleavages and Organoiron Ring Transformations: Reaction of a Perfluorosulfanylvinyldiiron(I) Complex with Amines
Organometallics, 2000, 19, 1912
4077462 CIFC15 H13 F3 Fe2 N2 O6 SP 1 21 18.083; 15.5721; 8.617
90; 116.66; 90
969.3Guennou-de Cadenet, Karine; Rumin, René; Pétillon, François Y.; Muir, Kenneth W.
Carbon−Fluorine Bond Cleavages and Organoiron Ring Transformations: Reaction of a Perfluorosulfanylvinyldiiron(I) Complex with Amines
Organometallics, 2000, 19, 1912
4077463 CIFC15 H15 F3 Fe2 N2 O6 SP 1 21/c 113.762; 9.9905; 15.0431
90; 93.064; 90
2065.3Guennou-de Cadenet, Karine; Rumin, René; Pétillon, François Y.; Muir, Kenneth W.
Carbon−Fluorine Bond Cleavages and Organoiron Ring Transformations: Reaction of a Perfluorosulfanylvinyldiiron(I) Complex with Amines
Organometallics, 2000, 19, 1912
4077464 CIFC29.5 H47 B9 Cl I N O P RuP 1 21/c 110.1874; 29.2144; 13.2192
90; 104.392; 90
3810.8Du, Shaowu; Ellis, Dianne D.; Jelliss, Paul A.; Kautz, Jason A.; Malget, John M.; Stone, F. Gordon A.
Studies with the Ruthenacarborane Complex [Ru(CO)(PPh3)(THF)(η5-7,8-C2B9H11)]: Reactions with Terminal Alkynes†
Organometallics, 2000, 19, 1983
4077465 CIFC29 H32 B9 O P RuP -19.4769; 10.7559; 16.4336
109.085; 94.81; 107.214
1481.6Du, Shaowu; Ellis, Dianne D.; Jelliss, Paul A.; Kautz, Jason A.; Malget, John M.; Stone, F. Gordon A.
Studies with the Ruthenacarborane Complex [Ru(CO)(PPh3)(THF)(η5-7,8-C2B9H11)]: Reactions with Terminal Alkynes†
Organometallics, 2000, 19, 1983
4077466 CIFC29 H39 B9 Cl2 N O P RuP 1 21/n 110.5524; 21.874; 16.108
90; 102.821; 90
3625.4Du, Shaowu; Ellis, Dianne D.; Jelliss, Paul A.; Kautz, Jason A.; Malget, John M.; Stone, F. Gordon A.
Studies with the Ruthenacarborane Complex [Ru(CO)(PPh3)(THF)(η5-7,8-C2B9H11)]: Reactions with Terminal Alkynes†
Organometallics, 2000, 19, 1983
4077467 CIFC33 H46 B9 O P RuP b c a15.1493; 19.5483; 24.609
90; 90; 90
7287.8Du, Shaowu; Ellis, Dianne D.; Jelliss, Paul A.; Kautz, Jason A.; Malget, John M.; Stone, F. Gordon A.
Studies with the Ruthenacarborane Complex [Ru(CO)(PPh3)(THF)(η5-7,8-C2B9H11)]: Reactions with Terminal Alkynes†
Organometallics, 2000, 19, 1983
4077468 CIFC23 H28 B9 O P RuP -19.4366; 13.2239; 22.802
83.046; 79.024; 70.639
2630.2Du, Shaowu; Ellis, Dianne D.; Jelliss, Paul A.; Kautz, Jason A.; Malget, John M.; Stone, F. Gordon A.
Studies with the Ruthenacarborane Complex [Ru(CO)(PPh3)(THF)(η5-7,8-C2B9H11)]: Reactions with Terminal Alkynes†
Organometallics, 2000, 19, 1983
4077469 CIFC27 H33 O3 PP c a b12.32; 37.838; 10.216
90; 90; 90
4762Romain, Jeff K.; Ribblett, Jason W.; Byrn, Robert W.; Snyder, Richard D.; Storhoff, Bruce N.; Huffman, John C.
Synthesis and Properties of Phenyl Phosphines with Meta-Positioned Methyl Groups and the X-ray Structure of Tris(3,5-dimethyl-4-methoxyphenyl)phosphine
Organometallics, 2000, 19, 2047
4077470 CIFC26 H33 B10 Mo O4 PP -110.7962; 10.943; 13.959
107.392; 95.6; 100.476
1527.1Ellis, Dianne D.; Franken, Andreas; Jelliss, Paul A.; Stone, F. Gordon A.; Yu, Pui-Yin
Synthesis and Reactivity of Monocarbollide Carbonyl Complexes of Iron and Molybdenum with Icosahedral Frameworks†
Organometallics, 2000, 19, 1993
4077471 CIFC8 H18 B10 Fe O4P 1 21/c 117.5961; 16.6039; 16.8279
90; 102.73; 90
4795.7Ellis, Dianne D.; Franken, Andreas; Jelliss, Paul A.; Stone, F. Gordon A.; Yu, Pui-Yin
Synthesis and Reactivity of Monocarbollide Carbonyl Complexes of Iron and Molybdenum with Icosahedral Frameworks†
Organometallics, 2000, 19, 1993
4077473 CIFC28 H20 O8 Ru3P 1 21/c 114.212; 11.9479; 16.337
90; 96.911; 90
2753.9Charmant, Jonathan P. H.; Davies, Guy; King, Philip J.; Wigginton, James R.; Sappa, E.
Reactivity of a Triruthenium Acetylide Complex toward Alkynes and the Silica-Mediated Dehydration of Cluster-Bound Alkynols: X-ray Crystal Structures of the Novel Butadienyl Species [Ru3(CO)8{μ3-η8-C(But)CC(Ph)C(H)Ph}] and the Unusual Complex [Ru3(CO)5(μ-CO){μ3-η5-CC(But)- OC(Ph)2CCH}{μ3-η6-CHC(CPh2OH)COC(CPh2)CH}]
Organometallics, 2000, 19, 2330
4077474 CIFC55 H43 O9.5 Ru3P -19.8161; 12.972; 19.602
81.76; 78.649; 87.883
2421.8Charmant, Jonathan P. H.; Davies, Guy; King, Philip J.; Wigginton, James R.; Sappa, E.
Reactivity of a Triruthenium Acetylide Complex toward Alkynes and the Silica-Mediated Dehydration of Cluster-Bound Alkynols: X-ray Crystal Structures of the Novel Butadienyl Species [Ru3(CO)8{μ3-η8-C(But)CC(Ph)C(H)Ph}] and the Unusual Complex [Ru3(CO)5(μ-CO){μ3-η5-CC(But)- OC(Ph)2CCH}{μ3-η6-CHC(CPh2OH)COC(CPh2)CH}]
Organometallics, 2000, 19, 2330
4077475 CIFC59 H46 Cl2 O9 Ru3P -110.5781; 15.541; 17.914
100.436; 96; 108.794
2699.5Charmant, Jonathan P. H.; Davies, Guy; King, Philip J.; Wigginton, James R.; Sappa, E.
Reactivity of a Triruthenium Acetylide Complex toward Alkynes and the Silica-Mediated Dehydration of Cluster-Bound Alkynols: X-ray Crystal Structures of the Novel Butadienyl Species [Ru3(CO)8{μ3-η8-C(But)CC(Ph)C(H)Ph}] and the Unusual Complex [Ru3(CO)5(μ-CO){μ3-η5-CC(But)- OC(Ph)2CCH}{μ3-η6-CHC(CPh2OH)COC(CPh2)CH}]
Organometallics, 2000, 19, 2330
4077476 CIFC38 H72 O4 P2 Si4 YbP 1 21/n 112.546; 18.212; 12.838
90; 118.11; 90
2587Clegg, William; Izod, Keith; Liddle, Stephen T.; O'Shaughness, Paul; Sheffield, Joanne M.
Synthesis and Structural Characterization of the First Lanthanide(II) Cuboidal Cluster. Unexpected C−O Activation by an Unchanged Ytterbium(II) Center
Organometallics, 2000, 19, 2090
4077477 CIFC84 H164 O12 P4 Si8 Yb4I -420.323; 20.323; 12.743
90; 90; 90
5263.2Clegg, William; Izod, Keith; Liddle, Stephen T.; O'Shaughness, Paul; Sheffield, Joanne M.
Synthesis and Structural Characterization of the First Lanthanide(II) Cuboidal Cluster. Unexpected C−O Activation by an Unchanged Ytterbium(II) Center
Organometallics, 2000, 19, 2090
4077478 CIFC27 H55 Al N3 PP -110.5525; 10.8527; 15.0268
95.024; 105.047; 111.37
1515.6Schulz, S.; Raab, M.; Nieger, M.; Niecke, E.
Syntheses and X-ray Structures of Novel Main Group Bis(dialkylamino)phosphinimides†
Organometallics, 2000, 19, 2616
4077479 CIFC36 H73 Al N3 PP 1 21/c 111.7878; 35.4013; 18.3712
90; 91.813; 90
7662.5Schulz, S.; Raab, M.; Nieger, M.; Niecke, E.
Syntheses and X-ray Structures of Novel Main Group Bis(dialkylamino)phosphinimides†
Organometallics, 2000, 19, 2616
4077480 CIFC52 H102 Al2 N6 P2P -19.0387; 11.3829; 14.5238
97.738; 106.838; 101.366
1372.61Schulz, S.; Raab, M.; Nieger, M.; Niecke, E.
Syntheses and X-ray Structures of Novel Main Group Bis(dialkylamino)phosphinimides†
Organometallics, 2000, 19, 2616
4077481 CIFC60 H120 Al2 N6 O P2P -19.6873; 12.82; 14.2885
98.725; 105.978; 106.748
1581.3Schulz, S.; Raab, M.; Nieger, M.; Niecke, E.
Syntheses and X-ray Structures of Novel Main Group Bis(dialkylamino)phosphinimides†
Organometallics, 2000, 19, 2616
4077482 CIFC16 H24 Cl2 Cu2P -15.273; 7.62; 10.972
83.21; 89; 82.02
433.53Gröger, Gunther; Behrens, Ulrich; Olbrich, Falk
Monomeric and Dimeric Cyclooctyne-Stabilized Complexes of Copper(I)1
Organometallics, 2000, 19, 3354
4077483 CIFC16 H24 Br2 Cu2P 1 21/c 14.789; 7.837; 23.697
90; 92.52; 90
888.5Gröger, Gunther; Behrens, Ulrich; Olbrich, Falk
Monomeric and Dimeric Cyclooctyne-Stabilized Complexes of Copper(I)1
Organometallics, 2000, 19, 3354
4077484 CIFC16 H24 Cu2 I2P -14.981; 9.192; 10.763
85.39; 80.17; 81.45
479.4Gröger, Gunther; Behrens, Ulrich; Olbrich, Falk
Monomeric and Dimeric Cyclooctyne-Stabilized Complexes of Copper(I)1
Organometallics, 2000, 19, 3354
4077485 CIFC16 H24 Cl CuP 1 21/c 113.1012; 15.9906; 15.1661
90; 106.166; 90
3051.61Gröger, Gunther; Behrens, Ulrich; Olbrich, Falk
Monomeric and Dimeric Cyclooctyne-Stabilized Complexes of Copper(I)1
Organometallics, 2000, 19, 3354
4077486 CIFC16 H24 Br CuP b c a14.79; 9.315; 22.093
90; 90; 90
3044Gröger, Gunther; Behrens, Ulrich; Olbrich, Falk
Monomeric and Dimeric Cyclooctyne-Stabilized Complexes of Copper(I)1
Organometallics, 2000, 19, 3354
4077487 CIFC16 H24 Cu IP b c a15.109; 9.3298; 22.6794
90; 90; 90
3196.98Gröger, Gunther; Behrens, Ulrich; Olbrich, Falk
Monomeric and Dimeric Cyclooctyne-Stabilized Complexes of Copper(I)1
Organometallics, 2000, 19, 3354
4077488 CIFC18 H28 Br2 Cu2 SP 1 21/c 113.405; 11.605; 14.831
90; 110.06; 90
2167.2Gröger, Gunther; Behrens, Ulrich; Olbrich, Falk
Monomeric and Dimeric Cyclooctyne-Stabilized Complexes of Copper(I)1
Organometallics, 2000, 19, 3354
4077489 CIFC34 H44 N2F d d 216.319; 49.65; 7.487
90; 90; 90
6066.3Nückel, Stefan; Burger, Peter
Transition Metal Complexes with Sterically Demanding Ligands. 2.1Meisenheimer Complex Formation and Deprotonation Reactions of a Sterically Demanding Aromatic Diimine†
Organometallics, 2000, 19, 3305
4077490 CIFC44 H69 Li N4P -19.163; 10.253; 23.038
88.71; 80.04; 81.62
2109Nückel, Stefan; Burger, Peter
Transition Metal Complexes with Sterically Demanding Ligands. 2.1Meisenheimer Complex Formation and Deprotonation Reactions of a Sterically Demanding Aromatic Diimine†
Organometallics, 2000, 19, 3305
4077491 CIFC48 H77 Li2 N2 O1.5P 1 21/c 112.979; 15.703; 22.942
90; 94.61; 90
4660.7Nückel, Stefan; Burger, Peter
Transition Metal Complexes with Sterically Demanding Ligands. 2.1Meisenheimer Complex Formation and Deprotonation Reactions of a Sterically Demanding Aromatic Diimine†
Organometallics, 2000, 19, 3305
4077492 CIFC42 H62 Li2 N2 O4I 1 2/a 114.356; 14.888; 19.76
90; 99; 90
4171.4Nückel, Stefan; Burger, Peter
Transition Metal Complexes with Sterically Demanding Ligands. 2.1Meisenheimer Complex Formation and Deprotonation Reactions of a Sterically Demanding Aromatic Diimine†
Organometallics, 2000, 19, 3305
4077493 CIFC42 H67 Cl3 N4 O4 P2 RuP 21 21 2112.762; 16.3; 24.71
90; 90; 90
5140Mosquera, Marta E. G.; Ruiz, Javier; Riera, Víctor; Garcia-Granda, Santiago; Salvadó, Miguel A.
Complexes of Ruthenium(II) with Unsymmetrical Diphosphines and Diphosphinomethanides. A Way to Synthesize Chiral Metallodiphosphines
Organometallics, 2000, 19, 5533
4077494 CIFC36 H34 Cl7 Fe N2 P PdP 1 21 19.7555; 20.737; 10.4
90; 107.837; 90
2002.8Woo, Tom K.; Pioda, Giorgio; Rothlisberger, Ursula; Togni, Antonio
Chiral Palladium(II)−Bis(trichlorosilyl) Complexes. Synthesis, Structure, and Combined QM/MM Computational Studies
Organometallics, 2000, 19, 2144
4077495 CIFC35 H33 Cl8 Fe N2 P Pd Si2P 3217.966; 17.966; 10.785
90; 90; 120
3015Woo, Tom K.; Pioda, Giorgio; Rothlisberger, Ursula; Togni, Antonio
Chiral Palladium(II)−Bis(trichlorosilyl) Complexes. Synthesis, Structure, and Combined QM/MM Computational Studies
Organometallics, 2000, 19, 2144
4077496 CIFC36 H35 Cl6 Fe N2 P Pd Si2P 1 21 110.551; 16.746; 11.634
90; 105.28; 90
1982.9Woo, Tom K.; Pioda, Giorgio; Rothlisberger, Ursula; Togni, Antonio
Chiral Palladium(II)−Bis(trichlorosilyl) Complexes. Synthesis, Structure, and Combined QM/MM Computational Studies
Organometallics, 2000, 19, 2144
4077497 CIFC22 H12 B F10 TiP -112.648; 15.678; 11.565
109.373; 110.63; 90.69
2003Chase, Preston A.; Piers, Warren E.; Parvez, Masood
Reactions of Bis(pentafluorophenyl)borane with Titanocene Dialkyls: Synthesis and Structure of Cp2Ti[η2-H2B(C6F5)2]
Organometallics, 2000, 19, 2040
4077498 CIFC73 H42 Cl2 F20 P4 Pt4P -112.5653; 17.516; 17.705
68.232; 80.442; 81.676
3553.9Alonso, Ester; Forniés, Juan; Fortuño, Consuelo; Martín, Antonio; Orpen, A. Guy
Polynuclear Homo- or Heterometallic Palladium(II)−Platinum(II) Pentafluorophenyl Complexes Containing Bridging Diphenylphosphido Ligands. 8.†Syntheses and Reactivity of the Tetranuclear [Pt4(μ2-PPh2)3{μ3-PPh(1,2-η2-Ph)-κ3P}(C6F5)4] Cluster
Organometallics, 2000, 19, 2690
4077499 CIFC88 H60 F20 N2 O2 P4 Pt4P -114.129; 15.133; 21.407
86.17; 75.52; 83.13
4397Alonso, Ester; Forniés, Juan; Fortuño, Consuelo; Martín, Antonio; Orpen, A. Guy
Polynuclear Homo- or Heterometallic Palladium(II)−Platinum(II) Pentafluorophenyl Complexes Containing Bridging Diphenylphosphido Ligands. 8.†Syntheses and Reactivity of the Tetranuclear [Pt4(μ2-PPh2)3{μ3-PPh(1,2-η2-Ph)-κ3P}(C6F5)4] Cluster
Organometallics, 2000, 19, 2690
4077500 CIFC96 H132 Ag6 N2 Pt2P -110.892; 11.861; 12.778
73.858; 77.346; 87.235
1547.05Ara, Irene; Forniés, Juan; Gómez, Julio; Lalinde, Elena; Moreno, M. Teresa
Versatile Behavior of [Pt2Ag4(C⋮C-t-Bu)8]: Synthesis, Structures, and Properties of [{Pt2Ag4(C⋮C-t-Bu)8}{Ag(bipy)}]4+and an Unprecedented Chain Polymeric Cocrystallization Adduct with a 2,2‘-bipy Ligand
Organometallics, 2000, 19, 3137
4077501 CIFC88 H104 Ag8 Cl4 N8 O16 Pt2C 1 2/c 114.929; 22.985; 29.596
90; 91.72; 90
10151.1Ara, Irene; Forniés, Juan; Gómez, Julio; Lalinde, Elena; Moreno, M. Teresa
Versatile Behavior of [Pt2Ag4(C⋮C-t-Bu)8]: Synthesis, Structures, and Properties of [{Pt2Ag4(C⋮C-t-Bu)8}{Ag(bipy)}]4+and an Unprecedented Chain Polymeric Cocrystallization Adduct with a 2,2‘-bipy Ligand
Organometallics, 2000, 19, 3137
4077502 CIFC42 H53 Cl2 Hf N3 P2 Si2P 1 21/m 110.4367; 20.164; 10.573
90; 100.243; 90
2189.6Kamalesh Babu, Ruppa P.; McDonald, Robert; Cavell, Ronald G.
Nucleophilic Reactivity of the Multiply Bonded Carbon Center in Group 4−Pincer Bis(iminophosphorano)methanediide Complexes
Organometallics, 2000, 19, 3462
4077503 CIFC38 H47 Cl2 Hf N3 P2 Si2P n a 2122.7155; 14.2639; 12.4956
90; 90; 90
4048.7Kamalesh Babu, Ruppa P.; McDonald, Robert; Cavell, Ronald G.
Nucleophilic Reactivity of the Multiply Bonded Carbon Center in Group 4−Pincer Bis(iminophosphorano)methanediide Complexes
Organometallics, 2000, 19, 3462
4077504 CIFC58.5 H80 Cl2 N4 O P2 Si2 ZrP 1 21/n 111.5636; 18.4194; 28.0498
90; 94.0569; 90
5959.5Kamalesh Babu, Ruppa P.; McDonald, Robert; Cavell, Ronald G.
Nucleophilic Reactivity of the Multiply Bonded Carbon Center in Group 4−Pincer Bis(iminophosphorano)methanediide Complexes
Organometallics, 2000, 19, 3462
4077505 CIFC99 H162 Ce2 K O6 Si6P 1 21/c 114.404; 12.704; 29.271
90; 92.97; 90
5349Gun'ko, Yurii K.; Hitchcock, Peter B.; Lappert, Michael F.
Nonclassical Organolanthanoid Metal Chemistry: [K([18]-crown-6)(η2-PhMe)2]X (X = [(LnCpt3)2(μ-H)], [(LnCp‘ ‘2)2(μ-η6:η6-PhMe)]) from [LnCpx3], K, and [18]-crown-6 in Toluene (Ln = La, Ce; Cpt= η5-C5H4SiMe2But; Cp‘ ‘ = η5-C5H3(SiMe3)2-1,3)
Organometallics, 2000, 19, 2832
4077506 CIFC16 H18 Cl N3 O PdP b c a17.88; 11.301; 16.378
90; 90; 90
3309Aresta, Michele; Giannoccaro, Potenzo; Tommasi, Immacolata; Dibenedetto, Angela; Manotti Lanfredi, Anna Maria; Ugozzoli, Franco
Synthesis and Solid State and Solution Characterization of Mono- and Di-(η1-C) Carbamoyl−Palladium Complexes. New Efficient Palladium-Catalyzed Routes to Carbamoyl Chlorides: Key Intermediates to Isocyanates, Carbamic Esters, and Ureas
Organometallics, 2000, 19, 3879
4077507 CIFC22 H28 N4 O2 PdP n a 2116.089; 16.576; 8.216
90; 90; 90
2191.1Aresta, Michele; Giannoccaro, Potenzo; Tommasi, Immacolata; Dibenedetto, Angela; Manotti Lanfredi, Anna Maria; Ugozzoli, Franco
Synthesis and Solid State and Solution Characterization of Mono- and Di-(η1-C) Carbamoyl−Palladium Complexes. New Efficient Palladium-Catalyzed Routes to Carbamoyl Chlorides: Key Intermediates to Isocyanates, Carbamic Esters, and Ureas
Organometallics, 2000, 19, 3879
4077508 CIFC15 H6 Fe4 O12 S4P -19.3683; 9.5511; 15.6898
75.976; 80.678; 71.735
1287.8Song, Li-Cheng; Hu, Qing-Mei; Fan, Hong-Tao; Sun, Bao-Wei; Tang, Ming-Yi; Chen, Yu; Sun, Yi; Sun, Cui-Xiang; Wu, Qiang-Jin
Synthesis and Characterization of Double- and Triple-Butterfly Fe/S Cluster Complexes Obtained from the Novel Butterfly Cluster Anions {(μ-RS)(μ-CO)[Fe2(CO)6]2(μ4-S)}-and (μ-RS)(μ-S-)[Fe2(CO)6]3(μ4-S)2. Crystal Structures of (μ-MeS)(μ-PhNHCS)[Fe2(CO)6]2(μ4-S), (μ-MeS)(μ-MeSCS)[Fe2(CO)6]2(μ4-S), and (μ-PhCH2S)2[Fe2(CO)6]3(μ4-S)2
Organometallics, 2000, 19, 3909
4077509 CIFC28 H63 B F4 O4 Os2 P2P 1 21/n 115.371; 11.934; 19.36
90; 90; 90
3551.4Esteruelas, Miguel A.; García-Yebra, Cristina; Oliván, Montserrat; Oñate, Enrique
Reaction of a Cationic Osmium(IV) Dihydride with Ethylene: Formation and Structure of the Novel Tetraethylene Dimer Complex [{(PiPr3)(η2-C2H4)2Os}2(μ-OH)2(μ-O2CCH3)]BF4
Organometallics, 2000, 19, 3260-3262
4077510 CIFC26 H27 Br3 Hg1.5 O2 P PtI 1 2/a 121.787; 8.178; 32.205
90; 97.23; 90
5692Ara, Irene; Falvello, Larry R.; Forniés, Juan; Sicilia, Violeta; Villarroya, Pablo
Reactivity of [M(C∧P)(acac-O,O‘)] [M = Pt, Pd; C∧P = CH2-C6H4-P(o-tolyl)2-κC,P; acac = 2,4-pentanedionato] toward HgX2(X = Br, I, CH3COO, CF3COO). New Polynuclear Complexes Containing Pt−Hg Bonds. Molecular Structures of [{Pt(C∧P)(acac-O,O‘)- HgBr(μ-Br)}2(μ-HgBr2)], an Unprecedented Square-Planar Bromomercurate Complex, and [{Pt(C∧P)(μ-O2CCH3)2Hg(μ3-acac2‒κC3,O)Hg(O2CCH3-κO)}· CHCl3]2, the First Complex Containing Asymmetric Dimercurated Acetylacetone
Organometallics, 2000, 19, 3091
4077511 CIFC33 H36 Cl3 Hg2 O8 P PtP -110.488; 13.158; 15.821
77.15; 75.74; 68.39
1946.2Ara, Irene; Falvello, Larry R.; Forniés, Juan; Sicilia, Violeta; Villarroya, Pablo
Reactivity of [M(C∧P)(acac-O,O‘)] [M = Pt, Pd; C∧P = CH2-C6H4-P(o-tolyl)2-κC,P; acac = 2,4-pentanedionato] toward HgX2(X = Br, I, CH3COO, CF3COO). New Polynuclear Complexes Containing Pt−Hg Bonds. Molecular Structures of [{Pt(C∧P)(acac-O,O‘)- HgBr(μ-Br)}2(μ-HgBr2)], an Unprecedented Square-Planar Bromomercurate Complex, and [{Pt(C∧P)(μ-O2CCH3)2Hg(μ3-acac2‒κC3,O)Hg(O2CCH3-κO)}· CHCl3]2, the First Complex Containing Asymmetric Dimercurated Acetylacetone
Organometallics, 2000, 19, 3091
4077512 CIFC42 H46 N2 P2 RuP 1 21 18.9595; 17.7941; 12.1757
90; 103.688; 90
1886Abdur-Rashid, Kamaluddin; Lough, Alan J.; Morris, Robert H.
Ruthenium Dihydride RuH2(PPh3)2((R,R)-cyclohexyldiamine) and Ruthenium Monohydride RuHCl(PPh3)2((R,R)-cyclohexyldiamine): Active Catalyst and Catalyst Precursor for the Hydrogenation of Ketones and Imines
Organometallics, 2000, 19, 2655
4077513 CIFC36 H68 O16 Ti2P 1 21 19.6698; 24.129; 10.2718
90; 90.724; 90
2396.5You, Jing-Song; Shao, Ming-Yuan; Gau, Han-Mou
Enantioselective Addition of Diethylzinc to Aldehydes Catalyzed by Titanium(IV) Complexes of Diol Derivatives ofd-Mannitol and the Spectroscopic Study of the Catalytic System
Organometallics, 2000, 19, 3368
4077514 CIFC26 H42 F6 Fe P4P 1 n 113.584; 13.527; 17.136
90; 109.18; 90
2974Edwards, Peter G.; Whatton, Mark L.; Haigh, Robert
A New Nine-Membered Triphosphorus Macrocycle
Organometallics, 2000, 19, 2652
4077515 CIFC42.5 H42 Cl4 Os P2P 1 21/c 112.9208; 20.381; 16.6709
90; 104.406; 90
4252.1Wen, Ting Bin; Yang, Sheng-Yong; Zhou, Zhong Yuan; Lin, Zhenyang; Lau, Chak-Po; Jia, Guochen
Unexpected Formation of Osmium Carbyne and Vinylidene Complexes from the Reaction of OsCl2(PPh3)3with HC⋮CCMe3
Organometallics, 2000, 19, 3757
4077516 CIFC54 H59 Cl Os P2P -112.3785; 13.8032; 17.2639
78.28; 70.488; 65.374
2520.4Wen, Ting Bin; Yang, Sheng-Yong; Zhou, Zhong Yuan; Lin, Zhenyang; Lau, Chak-Po; Jia, Guochen
Unexpected Formation of Osmium Carbyne and Vinylidene Complexes from the Reaction of OsCl2(PPh3)3with HC⋮CCMe3
Organometallics, 2000, 19, 3757
4077517 CIFC58 H59 F3 N5 O7 P3 Ru S2P 1 21/c 113.154; 15.008; 29.868
90; 90.84; 90
5896Bianchini, Claudio; Dal Santo, Vladimiro; Meli, Andrea; Oberhauser, Werner; Psaro, Rinaldo; Vizza, Francesco
Preparation, Characterization, and Performance of the Supported Hydrogen-Bonded Ruthenium Catalyst [(sulphos)Ru(NCMe)3](OSO2CF3)/SiO2. Comparisons with Analogous Homogeneous and Aqueous-Biphase Catalytic Systems in the Hydrogenation of Benzylideneacetone and Benzonitrile
Organometallics, 2000, 19, 2433
4077518 CIFC44 H43 Fe N O2 P2P -112.131; 12.19; 15.223
95.11; 105.91; 116.59
1876.3Denis, Raphaël; Toupet, Loïc; Paul, Frédéric; Lapinte, Claude
Electron-Rich Piano-Stool Iron σ-Acetylides Bearing a Functional Aryl Group. Synthesis and Characterization of Iron(II) and Iron(III) Complexes†
Organometallics, 2000, 19, 4240
4077519 CIFC49 H56 Fe P2P 1 21/n 113.806; 22.282; 14.392
90; 107.316; 90
4226.7Denis, Raphaël; Toupet, Loïc; Paul, Frédéric; Lapinte, Claude
Electron-Rich Piano-Stool Iron σ-Acetylides Bearing a Functional Aryl Group. Synthesis and Characterization of Iron(II) and Iron(III) Complexes†
Organometallics, 2000, 19, 4240
4077520 CIFC18 H22 Cl2 Mo2P 1 21/c 110.636; 7.635; 11.912
90; 111.454; 90
900.3Le Grognec, Erwan; Poli, Rinaldo; Richard, Philippe
Dialkyl(butadiene)cyclopentadienylmolybdenum(III) Complexes. Synthesis, Characterization, and Reactivity
Organometallics, 2000, 19, 3842
4077521 CIFC13 H21 MoP 1 21/c 115.092; 7.458; 22.186
90; 91.248; 90
2496.6Le Grognec, Erwan; Poli, Rinaldo; Richard, Philippe
Dialkyl(butadiene)cyclopentadienylmolybdenum(III) Complexes. Synthesis, Characterization, and Reactivity
Organometallics, 2000, 19, 3842
4077522 CIFC15 H15 F6 Mo O4P b c a14.566; 14.717; 16.7
90; 90; 90
3579.9Le Grognec, Erwan; Poli, Rinaldo; Richard, Philippe
Dialkyl(butadiene)cyclopentadienylmolybdenum(III) Complexes. Synthesis, Characterization, and Reactivity
Organometallics, 2000, 19, 3842
4077523 CIFC11 H15 Br0.77 Cl0.23 MoP b c m8.703; 19.521; 12.441
90; 90; 90
2113.62Le Grognec, Erwan; Poli, Rinaldo; Richard, Philippe
Dialkyl(butadiene)cyclopentadienylmolybdenum(III) Complexes. Synthesis, Characterization, and Reactivity
Organometallics, 2000, 19, 3842
4077524 CIFC16 H47 Al N4 Si4P c c n11.95; 12.387; 19.381
90; 90; 90
2868.9Uhl, Werner; Molter, Jens; Neumüller, Bernhard
tert-Butylaluminum Bis[1,2-bis(trimethylsilyl)hydrazide]: The First Alkylaluminum Dihydrazide
Organometallics, 2000, 19, 4422
4077525 CIFC20 H15 As O10 W2P 1 21/n 115.387; 18.193; 17.997
90; 103.34; 90
4902.1Johnson, Brian P.; Schiffer, Michael; Scheer, Manfred
Novel Approach to Intermediates Containing a Tungsten−Arsenic Triple Bond†
Organometallics, 2000, 19, 3404
4077526 CIFC12 H15 As3 O2 WP n m a8.545; 13.506; 13.253
90; 90; 90
1529.5Johnson, Brian P.; Schiffer, Michael; Scheer, Manfred
Novel Approach to Intermediates Containing a Tungsten−Arsenic Triple Bond†
Organometallics, 2000, 19, 3404
4077527 CIFC26 H30 As4 O6 W4P 1 21/n 110.18; 16.34; 19.866
90; 97.73; 90
3274.5Johnson, Brian P.; Schiffer, Michael; Scheer, Manfred
Novel Approach to Intermediates Containing a Tungsten−Arsenic Triple Bond†
Organometallics, 2000, 19, 3404
4077528 CIFC34.5 H34 As4 O11 W5P 1 21/c 117.402; 14.307; 18.855
90; 116.15; 90
4213.8Johnson, Brian P.; Schiffer, Michael; Scheer, Manfred
Novel Approach to Intermediates Containing a Tungsten−Arsenic Triple Bond†
Organometallics, 2000, 19, 3404
4077529 CIFC10 H21 F3 O6 Os P2 SP 1 21/n 18.742; 23.683; 10.049
90; 106.87; 90
1990.98Bellachioma, Gianfranco; Cardaci, Giuseppe; Macchioni, Alceo; Valentini, Francesco; Zuccaccia, Cristiano; Foresti, Elisabetta; Sabatino, Piera
Cationic Osmium(II) Acetyl Complexes Bearing Pyrazolylmethane Ligands: Intramolecular and Interionic Structure and Isolation of an Intermediate Containing the “Os−I−Ag” Moiety
Organometallics, 2000, 19, 4320
4077530 CIFC21 H21 Mo N O5C 1 2 127.088; 9.909; 14.865
90; 102.82; 90
3890.5van Staveren, Dave R.; Weyhermüller, Thomas; Metzler-Nolte, Nils
The Mo(η-allyl)(CO)2Moiety as a Robust Marker Group in Bioorganometallic Chemistry. Unusual Crystal Structure of the Phenylalanine Derivative Mo(C5H4-CO-Phe-OMe)(η-allyl)(CO)2
Organometallics, 2000, 19, 3730
4077531 CIFC84 H156 Ca4 O12 P4 Si8I -420.4587; 20.4587; 12.6985
90; 90; 90
5315.1Izod, Keith; Clegg, William; Liddle, Stephen T.
Parallels between the Chemistry of Calcium(II) and Ytterbium(II). Synthesis and Crystal Structure of a Calcium Alkoxo-Phosphide Cuboidal Complex
Organometallics, 2000, 19, 3640
4077532 CIFC22 H23 F9 N4 O6 PtP -19.2707; 12.818; 13.9085
112.734; 94.479; 110.266
1386.43Baar, Cliff R.; Jennings, Michael C.; Vittal, Jagadese J.; Puddephatt, Richard J.
Activation of Imines by Platinum(II) To Give Aminoalkyl Complexes: Scope and Limitations of the Reaction
Organometallics, 2000, 19, 4150
4077533 CIFC17 H25 Cl3 N4 O PtP 1 21/c 19.3415; 10.5506; 22.3484
90; 97.89; 90
2181.77Baar, Cliff R.; Jennings, Michael C.; Vittal, Jagadese J.; Puddephatt, Richard J.
Activation of Imines by Platinum(II) To Give Aminoalkyl Complexes: Scope and Limitations of the Reaction
Organometallics, 2000, 19, 4150
4077534 CIFC26 H25 F3 N4 O2 PtC 1 2/c 121.7762; 12.9791; 19.4521
90; 115.272; 90
4971.7Baar, Cliff R.; Jennings, Michael C.; Vittal, Jagadese J.; Puddephatt, Richard J.
Activation of Imines by Platinum(II) To Give Aminoalkyl Complexes: Scope and Limitations of the Reaction
Organometallics, 2000, 19, 4150
4077535 CIFC18 H28 Cl2 N4 O PtP 1 21/c 19.0613; 21.64; 11.0531
90; 98.409; 90
2144.06Baar, Cliff R.; Jennings, Michael C.; Vittal, Jagadese J.; Puddephatt, Richard J.
Activation of Imines by Platinum(II) To Give Aminoalkyl Complexes: Scope and Limitations of the Reaction
Organometallics, 2000, 19, 4150
4077536 CIFC10 H12 Fe N2P -17.3909; 10.357; 11.6657
88.13; 77.995; 88.089
872.66Shafir, Alexandr; Power, Maurice P.; Whitener, Glenn D.; Arnold, John
Synthesis, Structure, and Properties of 1,1‘-Diamino- and 1,1‘-Diazidoferrocene
Organometallics, 2000, 19, 3978
4077537 CIFC10 H8 Fe N6P b c a9.0587; 9.0587; 50.2953
90; 90; 90
4127.23Shafir, Alexandr; Power, Maurice P.; Whitener, Glenn D.; Arnold, John
Synthesis, Structure, and Properties of 1,1‘-Diamino- and 1,1‘-Diazidoferrocene
Organometallics, 2000, 19, 3978
4077538 CIFC23 H11 N O10 Os3C 1 2/c 123.472; 11.12; 20.593
90; 106.98; 90
5141Cabeza, Javier A.; del Río, Ignacio; Grepioni, Fabrizia; Riera, Víctor
Approaches to Triosmium Carbonyl Cluster Compounds Derived from Benzophenone Imine. Characterization of Terminal Imino, Bridging Amido, and Orthometalated Imino Derivatives
Organometallics, 2000, 19, 4643
4077539 CIFC41 H28 N2 O9 Os3P -111.029; 12.278; 15.922
101.681; 106.035; 94.08
2010.7Cabeza, Javier A.; del Río, Ignacio; Grepioni, Fabrizia; Riera, Víctor
Approaches to Triosmium Carbonyl Cluster Compounds Derived from Benzophenone Imine. Characterization of Terminal Imino, Bridging Amido, and Orthometalated Imino Derivatives
Organometallics, 2000, 19, 4643
4077540 CIFC23 H11 N O10 Os3P 1 21/n 113; 12.548; 16.36
90; 108.97; 90
2524Cabeza, Javier A.; del Río, Ignacio; Grepioni, Fabrizia; Riera, Víctor
Approaches to Triosmium Carbonyl Cluster Compounds Derived from Benzophenone Imine. Characterization of Terminal Imino, Bridging Amido, and Orthometalated Imino Derivatives
Organometallics, 2000, 19, 4643

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