Crystallography Open Database

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1540026 CIFC35 H23 N2 O6 P WP -18.8558; 19.929; 19.9303
61.0439; 87.8491; 84.3858
3062.77Klein, Melina; Schnakenburg, Gregor; Espinosa Ferao, Arturo; Streubel, Rainer
Rearrangement and deoxygenation of 3,3-bis(2-pyridyl)oxaphosphirane complexes.
Dalton transactions (Cambridge, England : 2003), 2016, 45, 2085-2094
1540027 CIFC23 H27 Cr N2 O6 P Si2F d d 221.2057; 52.0922; 9.9308
90; 90; 90
10970.1Klein, Melina; Schnakenburg, Gregor; Espinosa Ferao, Arturo; Streubel, Rainer
Rearrangement and deoxygenation of 3,3-bis(2-pyridyl)oxaphosphirane complexes.
Dalton transactions (Cambridge, England : 2003), 2016, 45, 2085-2094
1540028 CIFC23 H27 Cl2 N2 O5 P Si2 W ZnP -18.7858; 10.8025; 17.9022
77.25; 86.378; 66.964
1524.5Klein, Melina; Schnakenburg, Gregor; Espinosa Ferao, Arturo; Streubel, Rainer
Rearrangement and deoxygenation of 3,3-bis(2-pyridyl)oxaphosphirane complexes.
Dalton transactions (Cambridge, England : 2003), 2016, 45, 2085-2094
1540668 CIFC41 H39 Cr Fe3 O5 PC 1 2/c 120.142; 15.184; 25.001
90; 104.581; 90
7400Rabiee Kenaree, Amir; Sauvé, Ethan R; Ragogna, Paul J.; Gilroy, Joe B.
Group 6 metal pentacarbonyl complexes of air-stable primary, secondary, and tertiary ferrocenylethylphosphines.
Dalton transactions (Cambridge, England : 2003), 2016, 45, 2859-2867
1540669 CIFC41 H39 Fe3 Mo O5 PC 1 2/c 120.3; 15.312; 25.118
90; 104.367; 90
7563Rabiee Kenaree, Amir; Sauvé, Ethan R; Ragogna, Paul J.; Gilroy, Joe B.
Group 6 metal pentacarbonyl complexes of air-stable primary, secondary, and tertiary ferrocenylethylphosphines.
Dalton transactions (Cambridge, England : 2003), 2016, 45, 2859-2867
1540670 CIFC17 H15 Fe O5 P WP 1 21/c 120.416; 7.239; 25.066
90; 97.888; 90
3669Rabiee Kenaree, Amir; Sauvé, Ethan R; Ragogna, Paul J.; Gilroy, Joe B.
Group 6 metal pentacarbonyl complexes of air-stable primary, secondary, and tertiary ferrocenylethylphosphines.
Dalton transactions (Cambridge, England : 2003), 2016, 45, 2859-2867
1540671 CIFC29 H27 Fe2 O5 P WP 1 21/c 117.504; 12.9315; 12.708
90; 109.26; 90
2715.5Rabiee Kenaree, Amir; Sauvé, Ethan R; Ragogna, Paul J.; Gilroy, Joe B.
Group 6 metal pentacarbonyl complexes of air-stable primary, secondary, and tertiary ferrocenylethylphosphines.
Dalton transactions (Cambridge, England : 2003), 2016, 45, 2859-2867
1540672 CIFC41 H39 Fe3 O5 P WC 1 2/c 120.307; 15.287; 25.101
90; 104.391; 90
7548Rabiee Kenaree, Amir; Sauvé, Ethan R; Ragogna, Paul J.; Gilroy, Joe B.
Group 6 metal pentacarbonyl complexes of air-stable primary, secondary, and tertiary ferrocenylethylphosphines.
Dalton transactions (Cambridge, England : 2003), 2016, 45, 2859-2867
1540673 CIFC32 H30 Cu2 N4 O23 P2 W5F d d 219.005; 42.763; 10.6834
90; 90; 90
8682.5Ma, Hong-Xin; Du, Jing; Zhu, Zai-Ming; Lu, Ting; Su, Fang; Zhang, Lan-Cui
Controllable assembly, characterization and catalytic properties of a new Strandberg-type organophosphotungstate.
Dalton transactions (Cambridge, England : 2003), 2016, 45, 1631-1637
1540674 CIFC60 H74 Cu3 N12 O52 W12P 1 21/c 112.796; 25.625; 16.112
90; 119.955; 90
4577Ma, Hong-Xin; Du, Jing; Zhu, Zai-Ming; Lu, Ting; Su, Fang; Zhang, Lan-Cui
Controllable assembly, characterization and catalytic properties of a new Strandberg-type organophosphotungstate.
Dalton transactions (Cambridge, England : 2003), 2016, 45, 1631-1637
1540675 CIFC51 H33 Au N6 O2P -18.6926; 15.5671; 15.6537
106.257; 106.034; 95.639
1918.7Sinha, Woormileela; Sommer, Michael G.; van der Meer, Margarethe; Plebst, Sebastian; Sarkar, Biprajit; Kar, Sanjib
Structural, electrochemical and spectroelectrochemical study on the geometric and electronic structures of [(corrolato)Au(III)](n) (n = 0, +1, -1) complexes.
Dalton transactions (Cambridge, England : 2003), 2016, 45, 2914-2923
1543686 CIFC60 H106 Co3 N2 O12P -111.1262; 13.0303; 23.6869
84.976; 80.666; 80.653
3337Overgaard, Jacob; Møller, Louise H; Borup, Mette A.; Tricoire, Maxime; Walsh, James P. S.; Diehl, Marcel; Rentschler, Eva
Magnetism and variable temperature and pressure crystal structures of a linear oligonuclear cobalt bis-semiquinonate.
Dalton transactions (Cambridge, England : 2003), 2016, 45, 12924-12932
1543687 CIFC60 H106 Co3 N2 O12P -111.1253; 13.03; 23.6966
84.996; 80.775; 80.651
3339.05Overgaard, Jacob; Møller, Louise H; Borup, Mette A.; Tricoire, Maxime; Walsh, James P. S.; Diehl, Marcel; Rentschler, Eva
Magnetism and variable temperature and pressure crystal structures of a linear oligonuclear cobalt bis-semiquinonate.
Dalton transactions (Cambridge, England : 2003), 2016, 45, 12924-12932
1543688 CIFC60 H106 Co3 N2 O12P -111.141; 13.0395; 23.719
84.992; 80.834; 80.683
3350.2Overgaard, Jacob; Møller, Louise H; Borup, Mette A.; Tricoire, Maxime; Walsh, James P. S.; Diehl, Marcel; Rentschler, Eva
Magnetism and variable temperature and pressure crystal structures of a linear oligonuclear cobalt bis-semiquinonate.
Dalton transactions (Cambridge, England : 2003), 2016, 45, 12924-12932
1543689 CIFC60 H106 Co3 N2 O12P -111.1496; 13.0524; 23.7319
84.994; 80.842; 80.675
3357.9Overgaard, Jacob; Møller, Louise H; Borup, Mette A.; Tricoire, Maxime; Walsh, James P. S.; Diehl, Marcel; Rentschler, Eva
Magnetism and variable temperature and pressure crystal structures of a linear oligonuclear cobalt bis-semiquinonate.
Dalton transactions (Cambridge, England : 2003), 2016, 45, 12924-12932
1543690 CIFC60 H106 Co3 N2 O12P -111.1631; 13.0585; 23.7733
84.9778; 80.6354; 80.772
3368.35Overgaard, Jacob; Møller, Louise H; Borup, Mette A.; Tricoire, Maxime; Walsh, James P. S.; Diehl, Marcel; Rentschler, Eva
Magnetism and variable temperature and pressure crystal structures of a linear oligonuclear cobalt bis-semiquinonate.
Dalton transactions (Cambridge, England : 2003), 2016, 45, 12924-12932
1543691 CIFC60 H106 Co3 N2 O12P -111.1736; 13.0734; 23.8027
85.002; 80.744; 80.73
3380.24Overgaard, Jacob; Møller, Louise H; Borup, Mette A.; Tricoire, Maxime; Walsh, James P. S.; Diehl, Marcel; Rentschler, Eva
Magnetism and variable temperature and pressure crystal structures of a linear oligonuclear cobalt bis-semiquinonate.
Dalton transactions (Cambridge, England : 2003), 2016, 45, 12924-12932
1543692 CIFC60 H106 Co3 N2 O12P -111.1802; 13.0996; 23.8188
84.9528; 80.7062; 80.7735
3391.17Overgaard, Jacob; Møller, Louise H; Borup, Mette A.; Tricoire, Maxime; Walsh, James P. S.; Diehl, Marcel; Rentschler, Eva
Magnetism and variable temperature and pressure crystal structures of a linear oligonuclear cobalt bis-semiquinonate.
Dalton transactions (Cambridge, England : 2003), 2016, 45, 12924-12932
1543693 CIFC60 H106 Co3 N2 O12P -111.1939; 13.1136; 23.7996
84.866; 80.75; 80.803
3396.5Overgaard, Jacob; Møller, Louise H; Borup, Mette A.; Tricoire, Maxime; Walsh, James P. S.; Diehl, Marcel; Rentschler, Eva
Magnetism and variable temperature and pressure crystal structures of a linear oligonuclear cobalt bis-semiquinonate.
Dalton transactions (Cambridge, England : 2003), 2016, 45, 12924-12932
1543694 CIFC60 H106 Co3 N2 O12P -111.1908; 13.1253; 23.8212
84.9081; 80.7814; 80.7381
3401.57Overgaard, Jacob; Møller, Louise H; Borup, Mette A.; Tricoire, Maxime; Walsh, James P. S.; Diehl, Marcel; Rentschler, Eva
Magnetism and variable temperature and pressure crystal structures of a linear oligonuclear cobalt bis-semiquinonate.
Dalton transactions (Cambridge, England : 2003), 2016, 45, 12924-12932
1543695 CIFC60 H106 Co3 N2 O12P -111.2147; 13.1564; 23.8767
84.904; 80.795; 80.717
3424.8Overgaard, Jacob; Møller, Louise H; Borup, Mette A.; Tricoire, Maxime; Walsh, James P. S.; Diehl, Marcel; Rentschler, Eva
Magnetism and variable temperature and pressure crystal structures of a linear oligonuclear cobalt bis-semiquinonate.
Dalton transactions (Cambridge, England : 2003), 2016, 45, 12924-12932
1543696 CIFC60 H106 Co3 N2 O12P -111.2253; 13.1918; 23.8945
84.898; 80.845; 80.685
3439.95Overgaard, Jacob; Møller, Louise H; Borup, Mette A.; Tricoire, Maxime; Walsh, James P. S.; Diehl, Marcel; Rentschler, Eva
Magnetism and variable temperature and pressure crystal structures of a linear oligonuclear cobalt bis-semiquinonate.
Dalton transactions (Cambridge, England : 2003), 2016, 45, 12924-12932
1543697 CIFC60 H106 Co3 N2 O12P -114.6567; 17.3207; 23.808
99.402; 105.188; 96.155
5682.7Overgaard, Jacob; Møller, Louise H; Borup, Mette A.; Tricoire, Maxime; Walsh, James P. S.; Diehl, Marcel; Rentschler, Eva
Magnetism and variable temperature and pressure crystal structures of a linear oligonuclear cobalt bis-semiquinonate.
Dalton transactions (Cambridge, England : 2003), 2016, 45, 12924-12932
1543698 CIFC60 H106 Co3 N2 O12P -114.527; 17.177; 23.735
99.475; 105.533; 95.668
5564.5Overgaard, Jacob; Møller, Louise H; Borup, Mette A.; Tricoire, Maxime; Walsh, James P. S.; Diehl, Marcel; Rentschler, Eva
Magnetism and variable temperature and pressure crystal structures of a linear oligonuclear cobalt bis-semiquinonate.
Dalton transactions (Cambridge, England : 2003), 2016, 45, 12924-12932
1543699 CIFC60 H106 Co3 N2 O12P -110.9575; 12.7764; 23.2676
84.691; 81.325; 80.721
3170.2Overgaard, Jacob; Møller, Louise H; Borup, Mette A.; Tricoire, Maxime; Walsh, James P. S.; Diehl, Marcel; Rentschler, Eva
Magnetism and variable temperature and pressure crystal structures of a linear oligonuclear cobalt bis-semiquinonate.
Dalton transactions (Cambridge, England : 2003), 2016, 45, 12924-12932
1543700 CIFC60 H106 Co3 N2 O12P -110.664; 12.768; 23.2107
84.712; 81.583; 81.279
3082.2Overgaard, Jacob; Møller, Louise H; Borup, Mette A.; Tricoire, Maxime; Walsh, James P. S.; Diehl, Marcel; Rentschler, Eva
Magnetism and variable temperature and pressure crystal structures of a linear oligonuclear cobalt bis-semiquinonate.
Dalton transactions (Cambridge, England : 2003), 2016, 45, 12924-12932
1543701 CIFC60 H106 Co3 N2 O12P -110.472; 12.763; 23.102
84.771; 81.525; 81.41
3012.2Overgaard, Jacob; Møller, Louise H; Borup, Mette A.; Tricoire, Maxime; Walsh, James P. S.; Diehl, Marcel; Rentschler, Eva
Magnetism and variable temperature and pressure crystal structures of a linear oligonuclear cobalt bis-semiquinonate.
Dalton transactions (Cambridge, England : 2003), 2016, 45, 12924-12932
1543702 CIFC60 H106 Co3 N2 O12P -111.275; 13.288; 24.031
84.662; 81.022; 80.548
3499.6Overgaard, Jacob; Møller, Louise H; Borup, Mette A.; Tricoire, Maxime; Walsh, James P. S.; Diehl, Marcel; Rentschler, Eva
Magnetism and variable temperature and pressure crystal structures of a linear oligonuclear cobalt bis-semiquinonate.
Dalton transactions (Cambridge, England : 2003), 2016, 45, 12924-12932
1544296 CIFC20 H17 N2 O5 VP 1 21/c 118.249; 5.9376; 18.227
90; 110.346; 90
1851.8Dash, Subhashree P.; Panda, Alok K.; Dhaka, Sarita; Pasayat, Sagarika; Biswas, Ashis; Maurya, Mannar R.; Majhi, Paresh Kumar; Crochet, Aurélien; Dinda, Rupam
A study of DNA/BSA interaction and catalytic potential of oxidovanadium(v) complexes with ONO donor ligands.
Dalton transactions (Cambridge, England : 2003), 2016, 45, 18292-18307
1544297 CIFC50 H42 N6 O10 V2P 4/n21.5608; 21.5608; 10.1344
90; 90; 90
4711.16Dash, Subhashree P.; Panda, Alok K.; Dhaka, Sarita; Pasayat, Sagarika; Biswas, Ashis; Maurya, Mannar R.; Majhi, Paresh Kumar; Crochet, Aurélien; Dinda, Rupam
A study of DNA/BSA interaction and catalytic potential of oxidovanadium(v) complexes with ONO donor ligands.
Dalton transactions (Cambridge, England : 2003), 2016, 45, 18292-18307
7035321 CIFC62 H73 MnP -114.1067; 14.571; 14.6081
105.957; 94.745; 118.726
2448.1Heinl, Sebastian; Balázs, Gábor; Bodensteiner, Michael; Scheer, Manfred
Synthesis and characterization of manganese triple-decker complexes.
Dalton transactions (Cambridge, England : 2003), 2016, 45, 1962-1966
7035322 CIFC152 H178 Mn2 P4.7P 1 21/m 117.118; 23.57334; 17.22285
90; 110.997; 90
6488.42Heinl, Sebastian; Balázs, Gábor; Bodensteiner, Michael; Scheer, Manfred
Synthesis and characterization of manganese triple-decker complexes.
Dalton transactions (Cambridge, England : 2003), 2016, 45, 1962-1966
7035367 CIFC28 H34 Co Mo O5 PP 1 21/c 110.8541; 23.402; 14.4578
90; 129.149; 90
2848Alvarez, Belén; Alvarez, M. Angeles; García, M Esther; Ruiz, Miguel A.
P-S bond cleavage in reactions of thiophosphinidene-bridged dimolybdenum complexes with [Co2(CO)8] to give phosphinidene-bridged heterometallic derivatives.
Dalton transactions (Cambridge, England : 2003), 2016, 45, 1937-1952
7035368 CIFC32 H34 Co3 Mo O9 PP 1 21/m 19.9372; 15.6891; 10.8895
90; 95.98; 90
1688.5Alvarez, Belén; Alvarez, M. Angeles; García, M Esther; Ruiz, Miguel A.
P-S bond cleavage in reactions of thiophosphinidene-bridged dimolybdenum complexes with [Co2(CO)8] to give phosphinidene-bridged heterometallic derivatives.
Dalton transactions (Cambridge, England : 2003), 2016, 45, 1937-1952
7035369 CIFC39 H48 Co2 Mo2 N O6 P SP 1 21/c 112.392; 20.019; 18.798
90; 120.701; 90
4010Alvarez, Belén; Alvarez, M. Angeles; García, M Esther; Ruiz, Miguel A.
P-S bond cleavage in reactions of thiophosphinidene-bridged dimolybdenum complexes with [Co2(CO)8] to give phosphinidene-bridged heterometallic derivatives.
Dalton transactions (Cambridge, England : 2003), 2016, 45, 1937-1952
7035370 CIFC35 H43 Co3 Mo N O7 P SP 1 21/c 116.0551; 12.1292; 20.0465
90; 94.039; 90
3894.1Alvarez, Belén; Alvarez, M. Angeles; García, M Esther; Ruiz, Miguel A.
P-S bond cleavage in reactions of thiophosphinidene-bridged dimolybdenum complexes with [Co2(CO)8] to give phosphinidene-bridged heterometallic derivatives.
Dalton transactions (Cambridge, England : 2003), 2016, 45, 1937-1952
7035371 CIFC34 H39 Co2 Mo2 O6 P SP 21 21 2110.7899; 11.8705; 31.0457
90; 90; 90
3976.38Alvarez, Belén; Alvarez, M. Angeles; García, M Esther; Ruiz, Miguel A.
P-S bond cleavage in reactions of thiophosphinidene-bridged dimolybdenum complexes with [Co2(CO)8] to give phosphinidene-bridged heterometallic derivatives.
Dalton transactions (Cambridge, England : 2003), 2016, 45, 1937-1952
7035372 CIFC67 H56 B Co3 F24 Mo N O7 P SP n a 2126.9844; 17.4241; 15.8536
90; 90; 90
7454.03Alvarez, Belén; Alvarez, M. Angeles; García, M Esther; Ruiz, Miguel A.
P-S bond cleavage in reactions of thiophosphinidene-bridged dimolybdenum complexes with [Co2(CO)8] to give phosphinidene-bridged heterometallic derivatives.
Dalton transactions (Cambridge, England : 2003), 2016, 45, 1937-1952
7035419 CIFC12 H36 Cl2 N4 P2 Si5P 1 21 110.418; 10.3333; 12.9878
90; 90.739; 90
1398.05Holthausen, M. H.; Weigand, J. J.
Formation of the spirocyclic, Si-centered cage cations [ClP(NSiMe3)2Si(NSiMe3)2P5](+) and [P5(NSiMe3)2Si(NSiMe3)2P5](2.).
Dalton transactions (Cambridge, England : 2003), 2016, 45, 1953-1961
7035420 CIFC12 H36 Cl11 Ga3 N4 P10 Si5P 1 21/c 113.7339; 25.0441; 14.6026
90; 92.797; 90
5016.6Holthausen, M. H.; Weigand, J. J.
Formation of the spirocyclic, Si-centered cage cations [ClP(NSiMe3)2Si(NSiMe3)2P5](+) and [P5(NSiMe3)2Si(NSiMe3)2P5](2.).
Dalton transactions (Cambridge, England : 2003), 2016, 45, 1953-1961
7035421 CIFC12 H36 Cl14 Ga4 N4 P10 Si5P -19.9999; 23.7473; 26.3333
63.844; 79.463; 86.969
5515.64Holthausen, M. H.; Weigand, J. J.
Formation of the spirocyclic, Si-centered cage cations [ClP(NSiMe3)2Si(NSiMe3)2P5](+) and [P5(NSiMe3)2Si(NSiMe3)2P5](2.).
Dalton transactions (Cambridge, England : 2003), 2016, 45, 1953-1961
7035422 CIFC18 H41 Cl5 F Ga N4 P6 Si5P 1 21/c 19.7057; 18.1074; 23.8559
90; 93.677; 90
4183.92Holthausen, M. H.; Weigand, J. J.
Formation of the spirocyclic, Si-centered cage cations [ClP(NSiMe3)2Si(NSiMe3)2P5](+) and [P5(NSiMe3)2Si(NSiMe3)2P5](2.).
Dalton transactions (Cambridge, England : 2003), 2016, 45, 1953-1961
7035586 CIFC27 H39 N2 PP n m a11.8631; 20.2676; 10.9214
90; 90; 90
2625.9Bispinghoff, Mark; Tondreau, Aaron M.; Grützmacher, Hansjörg; Faradji, Charly A.; Pringle, Paul G.
Carbene insertion into a P-H bond: parent phosphinidene-carbene adducts from PH3 and bis(phosphinidene)mercury complexes.
Dalton transactions (Cambridge, England : 2003), 2016, 45, 5999-6003
7035587 CIFC27 H41 N2 PP b c a12.1771; 16.0504; 26.4131
90; 90; 90
5162.37Bispinghoff, Mark; Tondreau, Aaron M.; Grützmacher, Hansjörg; Faradji, Charly A.; Pringle, Paul G.
Carbene insertion into a P-H bond: parent phosphinidene-carbene adducts from PH3 and bis(phosphinidene)mercury complexes.
Dalton transactions (Cambridge, England : 2003), 2016, 45, 5999-6003
7035588 CIFC54 H68 Hg N4 P2P -110.4911; 11.1172; 12.5446
103.202; 112.596; 95.847
1285.49Bispinghoff, Mark; Tondreau, Aaron M.; Grützmacher, Hansjörg; Faradji, Charly A.; Pringle, Paul G.
Carbene insertion into a P-H bond: parent phosphinidene-carbene adducts from PH3 and bis(phosphinidene)mercury complexes.
Dalton transactions (Cambridge, England : 2003), 2016, 45, 5999-6003
7035589 CIFC54 H76 Hg N4 P2P -110.7696; 11.016; 12.2625
103.816; 110.797; 96.922
1286.44Bispinghoff, Mark; Tondreau, Aaron M.; Grützmacher, Hansjörg; Faradji, Charly A.; Pringle, Paul G.
Carbene insertion into a P-H bond: parent phosphinidene-carbene adducts from PH3 and bis(phosphinidene)mercury complexes.
Dalton transactions (Cambridge, England : 2003), 2016, 45, 5999-6003
7035598 CIFC47 H55 Cl2 N3 O ZnP 19.5162; 9.5686; 13.6954
108.253; 92.6578; 112.893
1070.67Myers, Thomas W.; Sherbow, Tobias J.; Fettinger, James C.; Berben, Louise A.
Synthesis and characterization of bis(imino)pyridine complexes of divalent Mg and Zn.
Dalton transactions (Cambridge, England : 2003), 2016, 45, 5989-5998
7035599 CIFC47 H57 Cl N3 O ZnP b c a21.2904; 17.616; 22.126
90; 90; 90
8298.4Myers, Thomas W.; Sherbow, Tobias J.; Fettinger, James C.; Berben, Louise A.
Synthesis and characterization of bis(imino)pyridine complexes of divalent Mg and Zn.
Dalton transactions (Cambridge, England : 2003), 2016, 45, 5989-5998
7035600 CIFC56 H72 Cl N4 O2 ZnP b c a16.3329; 23.2052; 26.7476
90; 90; 90
10137.6Myers, Thomas W.; Sherbow, Tobias J.; Fettinger, James C.; Berben, Louise A.
Synthesis and characterization of bis(imino)pyridine complexes of divalent Mg and Zn.
Dalton transactions (Cambridge, England : 2003), 2016, 45, 5989-5998
7035601 CIFC51 H63 Al Cl2 N3 O2P -19.5271; 11.8468; 21.7771
103.835; 100.793; 91.694
2337.23Myers, Thomas W.; Sherbow, Tobias J.; Fettinger, James C.; Berben, Louise A.
Synthesis and characterization of bis(imino)pyridine complexes of divalent Mg and Zn.
Dalton transactions (Cambridge, England : 2003), 2016, 45, 5989-5998
7035602 CIFC166 H248 Cl4 Mg6 N12 O7C 1 2/c 123.515; 15.5547; 43.771
90; 97.11; 90
15887Myers, Thomas W.; Sherbow, Tobias J.; Fettinger, James C.; Berben, Louise A.
Synthesis and characterization of bis(imino)pyridine complexes of divalent Mg and Zn.
Dalton transactions (Cambridge, England : 2003), 2016, 45, 5989-5998
7035603 CIFC41 H59 Mg N3 O2F d d 232.0684; 34.4149; 17.4423
90; 90; 90
19249.9Myers, Thomas W.; Sherbow, Tobias J.; Fettinger, James C.; Berben, Louise A.
Synthesis and characterization of bis(imino)pyridine complexes of divalent Mg and Zn.
Dalton transactions (Cambridge, England : 2003), 2016, 45, 5989-5998
7035812 CIFC17 H20 Cl3 N2 P PtP 1 21/n 110.6985; 17.0969; 10.7451
90; 91.79; 90
1964.4Haldón, Estela; Kozma, Ágnes; Tinnermann, Hendrik; Gu, Lianghu; Goddard, Richard; Alcarazo, Manuel
Synthesis and reactivity of α-cationic phosphines: the effect of imidazolinium and amidinium substituents.
Dalton transactions (Cambridge, England : 2003), 2016, 45, 1872-1876
7035813 CIFC17 H32 B F4 N2 PP 1 21/n 112.3705; 22.6919; 15.1987
90; 113.624; 90
3908.9Haldón, Estela; Kozma, Ágnes; Tinnermann, Hendrik; Gu, Lianghu; Goddard, Richard; Alcarazo, Manuel
Synthesis and reactivity of α-cationic phosphines: the effect of imidazolinium and amidinium substituents.
Dalton transactions (Cambridge, England : 2003), 2016, 45, 1872-1876
7035814 CIFC19 H35 Au Cl F6 N3 P SbP -18.4612; 8.9156; 19.0961
83.9995; 81.0351; 64.596
1284.2Haldón, Estela; Kozma, Ágnes; Tinnermann, Hendrik; Gu, Lianghu; Goddard, Richard; Alcarazo, Manuel
Synthesis and reactivity of α-cationic phosphines: the effect of imidazolinium and amidinium substituents.
Dalton transactions (Cambridge, England : 2003), 2016, 45, 1872-1876
7035815 CIFC17 H32 F6 N2 P SbP -115.028; 15.072; 15.43
75.926; 82.983; 74.157
3255.4Haldón, Estela; Kozma, Ágnes; Tinnermann, Hendrik; Gu, Lianghu; Goddard, Richard; Alcarazo, Manuel
Synthesis and reactivity of α-cationic phosphines: the effect of imidazolinium and amidinium substituents.
Dalton transactions (Cambridge, England : 2003), 2016, 45, 1872-1876
7035816 CIFC35 H42 Au2 Cl4 F12 N4 P2 Sb2P -111.9015; 13.6615; 16.414
88.305; 69.996; 88.438
2506.3Haldón, Estela; Kozma, Ágnes; Tinnermann, Hendrik; Gu, Lianghu; Goddard, Richard; Alcarazo, Manuel
Synthesis and reactivity of α-cationic phosphines: the effect of imidazolinium and amidinium substituents.
Dalton transactions (Cambridge, England : 2003), 2016, 45, 1872-1876
7035817 CIFC23 H30 Au Cl F6 N2 P SbP 1 21/n 115.8215; 10.3524; 18.0617
90; 115.205; 90
2676.7Haldón, Estela; Kozma, Ágnes; Tinnermann, Hendrik; Gu, Lianghu; Goddard, Richard; Alcarazo, Manuel
Synthesis and reactivity of α-cationic phosphines: the effect of imidazolinium and amidinium substituents.
Dalton transactions (Cambridge, England : 2003), 2016, 45, 1872-1876
7035818 CIFC25 H34 Cl7 N2 P PtP 21 21 218.878; 15.409; 22.384
90; 90; 90
3062Haldón, Estela; Kozma, Ágnes; Tinnermann, Hendrik; Gu, Lianghu; Goddard, Richard; Alcarazo, Manuel
Synthesis and reactivity of α-cationic phosphines: the effect of imidazolinium and amidinium substituents.
Dalton transactions (Cambridge, England : 2003), 2016, 45, 1872-1876
7035819 CIFC28 H45 F12 N4 P Sb2P -110.2341; 11.9121; 14.5106
82.3872; 82.2212; 87.2389
1736.43Haldón, Estela; Kozma, Ágnes; Tinnermann, Hendrik; Gu, Lianghu; Goddard, Richard; Alcarazo, Manuel
Synthesis and reactivity of α-cationic phosphines: the effect of imidazolinium and amidinium substituents.
Dalton transactions (Cambridge, England : 2003), 2016, 45, 1872-1876
7035820 CIFC17 H20 F6 N2 P SbP 1 21/c 17.5835; 11.105; 23.5818
90; 94.658; 90
1979.38Haldón, Estela; Kozma, Ágnes; Tinnermann, Hendrik; Gu, Lianghu; Goddard, Richard; Alcarazo, Manuel
Synthesis and reactivity of α-cationic phosphines: the effect of imidazolinium and amidinium substituents.
Dalton transactions (Cambridge, England : 2003), 2016, 45, 1872-1876
7035822 CIFC40 H76 Ge K2 N3 O12 P7 Si2P -113.081; 15.6526; 15.7164
87.749; 72.748; 77.053
2993.78Quintero, Gabriela Espinoza; Paterson-Taylor, Isabelle; Rees, Nicholas H.; Goicoechea, Jose M.
Heptaphosphide cluster anions bearing group 14 element amide functionalities.
Dalton transactions (Cambridge, England : 2003), 2016, 45, 1930-1936
7035823 CIFC40 H76 K2 N3 O12 P7 Si2 SnP -113.1078; 15.7005; 15.9468
88.958; 72.667; 77.311
3052.35Quintero, Gabriela Espinoza; Paterson-Taylor, Isabelle; Rees, Nicholas H.; Goicoechea, Jose M.
Heptaphosphide cluster anions bearing group 14 element amide functionalities.
Dalton transactions (Cambridge, England : 2003), 2016, 45, 1930-1936
7035975 CIFC24 H9 B F18P -17.2951; 10.6358; 15.9794
85.95; 86.582; 74.846
1192.64Blagg, Robin J.; Lawrence, Elliot J.; Resner, Katie; Oganesyan, Vasily S.; Herrington, Thomas J.; Ashley, Andrew E.; Wildgoose, Gregory G.
Exploring structural and electronic effects in three isomers of tris{bis(trifluoromethyl)phenyl}borane: towards the combined electrochemical-frustrated Lewis pair activation of H2.
Dalton transactions (Cambridge, England : 2003), 2016, 45, 6023-6031
7035986 CIFC10 H17 O2 P SP 21 21 218.7682; 9.0948; 14.4718
90; 90; 90
1154.05Möller, Tobias; Wonneberger, Peter; Sárosi, Menyhárt B; Coburger, Peter; Hey-Hawkins, Evamarie
P-chiral 1-phosphanorbornenes: from asymmetric phospha-Diels-Alder reactions towards ligand design and functionalisation.
Dalton transactions (Cambridge, England : 2003), 2016, 45, 1904-1917
7035987 CIFC10 H17 O2 P SC 1 2 114.991; 7.3994; 10.5296
90; 93.746; 90
1165.49Möller, Tobias; Wonneberger, Peter; Sárosi, Menyhárt B; Coburger, Peter; Hey-Hawkins, Evamarie
P-chiral 1-phosphanorbornenes: from asymmetric phospha-Diels-Alder reactions towards ligand design and functionalisation.
Dalton transactions (Cambridge, England : 2003), 2016, 45, 1904-1917
7035988 CIFC16 H21 O2 P SP 1 21 18.196; 8.334; 11.144
90; 92.054; 90
760.7Möller, Tobias; Wonneberger, Peter; Sárosi, Menyhárt B; Coburger, Peter; Hey-Hawkins, Evamarie
P-chiral 1-phosphanorbornenes: from asymmetric phospha-Diels-Alder reactions towards ligand design and functionalisation.
Dalton transactions (Cambridge, England : 2003), 2016, 45, 1904-1917
7035989 CIFC16 H21 O2 P SP 21 21 218.41; 12.953; 13.799
90; 90; 90
1503.2Möller, Tobias; Wonneberger, Peter; Sárosi, Menyhárt B; Coburger, Peter; Hey-Hawkins, Evamarie
P-chiral 1-phosphanorbornenes: from asymmetric phospha-Diels-Alder reactions towards ligand design and functionalisation.
Dalton transactions (Cambridge, England : 2003), 2016, 45, 1904-1917
7035990 CIFC16 H21 O2 P SP 21 21 219.123; 11.681; 14.355
90; 90; 90
1529.8Möller, Tobias; Wonneberger, Peter; Sárosi, Menyhárt B; Coburger, Peter; Hey-Hawkins, Evamarie
P-chiral 1-phosphanorbornenes: from asymmetric phospha-Diels-Alder reactions towards ligand design and functionalisation.
Dalton transactions (Cambridge, England : 2003), 2016, 45, 1904-1917
7035991 CIFC22 H26 O2 P2 S2C 1 2 129.199; 9.1211; 18.0309
90; 112.228; 90
4445.3Möller, Tobias; Wonneberger, Peter; Sárosi, Menyhárt B; Coburger, Peter; Hey-Hawkins, Evamarie
P-chiral 1-phosphanorbornenes: from asymmetric phospha-Diels-Alder reactions towards ligand design and functionalisation.
Dalton transactions (Cambridge, England : 2003), 2016, 45, 1904-1917
7035992 CIFC28 H38 O2 P2 S2P 21 21 218.4597; 14.4132; 23.4346
90; 90; 90
2857.41Möller, Tobias; Wonneberger, Peter; Sárosi, Menyhárt B; Coburger, Peter; Hey-Hawkins, Evamarie
P-chiral 1-phosphanorbornenes: from asymmetric phospha-Diels-Alder reactions towards ligand design and functionalisation.
Dalton transactions (Cambridge, England : 2003), 2016, 45, 1904-1917
7035993 CIFC22 H29 B O P2 SP 21 21 219.0643; 9.105; 25.6653
90; 90; 90
2118.17Möller, Tobias; Wonneberger, Peter; Sárosi, Menyhárt B; Coburger, Peter; Hey-Hawkins, Evamarie
P-chiral 1-phosphanorbornenes: from asymmetric phospha-Diels-Alder reactions towards ligand design and functionalisation.
Dalton transactions (Cambridge, England : 2003), 2016, 45, 1904-1917
7035994 CIFC25 H34 N O3 P SP 21 21 2112.0155; 12.2658; 16.7128
90; 90; 90
2463.13Möller, Tobias; Wonneberger, Peter; Sárosi, Menyhárt B; Coburger, Peter; Hey-Hawkins, Evamarie
P-chiral 1-phosphanorbornenes: from asymmetric phospha-Diels-Alder reactions towards ligand design and functionalisation.
Dalton transactions (Cambridge, England : 2003), 2016, 45, 1904-1917
7036005 CIFC22 H39 Cl2 N2 O P PdP 1 21 18.2299; 16.7796; 9.6743
90; 103.954; 90
1296.54Marchenko, Anatoliy; Koidan, Georgyi; Hurieva, Anastasiya; Vlasenko, Yurii; Kostyuk, Aleksandr; Biffis, Andrea
Palladium(ii) complexes with chelating N-phosphanyl acyclic diaminocarbenes: synthesis, characterization and catalytic performance in Suzuki couplings.
Dalton transactions (Cambridge, England : 2003), 2016, 45, 1967-1975
7036006 CIFC21 H37 Cl2 N2 P PdP 21 21 2110.1264; 13.7129; 17.5394
90; 90; 90
2435.6Marchenko, Anatoliy; Koidan, Georgyi; Hurieva, Anastasiya; Vlasenko, Yurii; Kostyuk, Aleksandr; Biffis, Andrea
Palladium(ii) complexes with chelating N-phosphanyl acyclic diaminocarbenes: synthesis, characterization and catalytic performance in Suzuki couplings.
Dalton transactions (Cambridge, England : 2003), 2016, 45, 1967-1975
7036007 CIFC22 H39 Cl2 N2 P PdP 21 21 2110.2491; 12.2572; 19.524
90; 90; 90
2452.7Marchenko, Anatoliy; Koidan, Georgyi; Hurieva, Anastasiya; Vlasenko, Yurii; Kostyuk, Aleksandr; Biffis, Andrea
Palladium(ii) complexes with chelating N-phosphanyl acyclic diaminocarbenes: synthesis, characterization and catalytic performance in Suzuki couplings.
Dalton transactions (Cambridge, England : 2003), 2016, 45, 1967-1975
7036008 CIFC28 H45 Cl2 F3 N5 P PdP 21 21 2112.6614; 15.7007; 16.89
90; 90; 90
3357.61Marchenko, Anatoliy; Koidan, Georgyi; Hurieva, Anastasiya; Vlasenko, Yurii; Kostyuk, Aleksandr; Biffis, Andrea
Palladium(ii) complexes with chelating N-phosphanyl acyclic diaminocarbenes: synthesis, characterization and catalytic performance in Suzuki couplings.
Dalton transactions (Cambridge, England : 2003), 2016, 45, 1967-1975
7036009 CIFC23 H40.5 Cl2 N2.5 O P PdP 1 21/n 115.5317; 10.2561; 33.1968
90; 92.109; 90
5284.49Marchenko, Anatoliy; Koidan, Georgyi; Hurieva, Anastasiya; Vlasenko, Yurii; Kostyuk, Aleksandr; Biffis, Andrea
Palladium(ii) complexes with chelating N-phosphanyl acyclic diaminocarbenes: synthesis, characterization and catalytic performance in Suzuki couplings.
Dalton transactions (Cambridge, England : 2003), 2016, 45, 1967-1975
7036034 CIFC48 H50 K N2 PP 1 21/n 113.9771; 20.921; 14.6037
90; 108.648; 90
4046.2Hinz, Alexander; Rothe, Julia; Schulz, Axel; Villinger, Alexander
Reduction of dichloro(diaza-phospha)stibanes - isolation of a donor-stabilized distibenium dication.
Dalton transactions (Cambridge, England : 2003), 2016, 45, 6044-6052
7036035 CIFC48 H50 Cl2 N2 P SbP 1 21/n 112.0987; 22.5405; 16.4923
90; 106.879; 90
4303.9Hinz, Alexander; Rothe, Julia; Schulz, Axel; Villinger, Alexander
Reduction of dichloro(diaza-phospha)stibanes - isolation of a donor-stabilized distibenium dication.
Dalton transactions (Cambridge, England : 2003), 2016, 45, 6044-6052
7036036 CIFC48 H50 Cl5 Ga N2 P SbP 1 21/c 131.5546; 16.15; 19.5721
90; 106.735; 90
9551.6Hinz, Alexander; Rothe, Julia; Schulz, Axel; Villinger, Alexander
Reduction of dichloro(diaza-phospha)stibanes - isolation of a donor-stabilized distibenium dication.
Dalton transactions (Cambridge, England : 2003), 2016, 45, 6044-6052
7036037 CIFC52 H58 Cl Mg N2 O PP 1 21/c 112.8983; 15.7209; 22.3241
90; 95.003; 90
4509.5Hinz, Alexander; Rothe, Julia; Schulz, Axel; Villinger, Alexander
Reduction of dichloro(diaza-phospha)stibanes - isolation of a donor-stabilized distibenium dication.
Dalton transactions (Cambridge, England : 2003), 2016, 45, 6044-6052
7036038 CIFC62 H60 N2 P SbC 1 c 118.1642; 11.4249; 23.9813
90; 99.487; 90
4908.6Hinz, Alexander; Rothe, Julia; Schulz, Axel; Villinger, Alexander
Reduction of dichloro(diaza-phospha)stibanes - isolation of a donor-stabilized distibenium dication.
Dalton transactions (Cambridge, England : 2003), 2016, 45, 6044-6052
7036039 CIFC96 H100 N4 P2 Sb2P n n n15.3403; 15.7088; 16.8844
90; 90; 90
4068.8Hinz, Alexander; Rothe, Julia; Schulz, Axel; Villinger, Alexander
Reduction of dichloro(diaza-phospha)stibanes - isolation of a donor-stabilized distibenium dication.
Dalton transactions (Cambridge, England : 2003), 2016, 45, 6044-6052
7036089 CIFC32 H76 Cl2 Mg2 N2 O2 Si4P 1 21/n 19.5683; 11.3302; 21.3284
90; 99.871; 90
2278Goodwin, Conrad A. P.; Smith, Alex; Ortu, Fabrizio; Vitorica-Yrezabal, Iñigo J; Mills, David P.
Salt metathesis versus protonolysis routes for the synthesis of silylamide Hauser base (R2NMgX; X = halogen) and amido-Grignard (R2NMgR) complexes.
Dalton transactions (Cambridge, England : 2003), 2016, 45, 6004-6014
7036090 CIFC38 H88 Cl2 Mg2 N2 O2 Si4P -19.7845; 11.0265; 12.2422
86.179; 88.328; 67.12
1214.2Goodwin, Conrad A. P.; Smith, Alex; Ortu, Fabrizio; Vitorica-Yrezabal, Iñigo J; Mills, David P.
Salt metathesis versus protonolysis routes for the synthesis of silylamide Hauser base (R2NMgX; X = halogen) and amido-Grignard (R2NMgR) complexes.
Dalton transactions (Cambridge, England : 2003), 2016, 45, 6004-6014
7036091 CIFC44 H100 Cl2 Mg2 N2 O2 Si4P 1 21/n 110.7375; 12.4913; 20.6451
90; 100.832; 90
2719.69Goodwin, Conrad A. P.; Smith, Alex; Ortu, Fabrizio; Vitorica-Yrezabal, Iñigo J; Mills, David P.
Salt metathesis versus protonolysis routes for the synthesis of silylamide Hauser base (R2NMgX; X = halogen) and amido-Grignard (R2NMgR) complexes.
Dalton transactions (Cambridge, England : 2003), 2016, 45, 6004-6014
7036092 CIFC32 H76 N2 Na2 O2 Si4P 1 21/c 115.833; 11.7764; 22.7974
90; 93.418; 90
4243.1Goodwin, Conrad A. P.; Smith, Alex; Ortu, Fabrizio; Vitorica-Yrezabal, Iñigo J; Mills, David P.
Salt metathesis versus protonolysis routes for the synthesis of silylamide Hauser base (R2NMgX; X = halogen) and amido-Grignard (R2NMgR) complexes.
Dalton transactions (Cambridge, England : 2003), 2016, 45, 6004-6014
7036093 CIFC20 H50 N Na O4 Si2P 1 21/n 110.8063; 16.759; 15.6804
90; 91.571; 90
2838.7Goodwin, Conrad A. P.; Smith, Alex; Ortu, Fabrizio; Vitorica-Yrezabal, Iñigo J; Mills, David P.
Salt metathesis versus protonolysis routes for the synthesis of silylamide Hauser base (R2NMgX; X = halogen) and amido-Grignard (R2NMgR) complexes.
Dalton transactions (Cambridge, England : 2003), 2016, 45, 6004-6014
7036094 CIFC24 H60 K2 N2 Si4P -18.4218; 9.6732; 11.33
90.787; 98.14; 110.583
853.37Goodwin, Conrad A. P.; Smith, Alex; Ortu, Fabrizio; Vitorica-Yrezabal, Iñigo J; Mills, David P.
Salt metathesis versus protonolysis routes for the synthesis of silylamide Hauser base (R2NMgX; X = halogen) and amido-Grignard (R2NMgR) complexes.
Dalton transactions (Cambridge, England : 2003), 2016, 45, 6004-6014
7036095 CIFC26 H66 Mg2 N2 Si4P -17.7791; 9.64; 13.4373
94.746; 94.148; 109.082
943.74Goodwin, Conrad A. P.; Smith, Alex; Ortu, Fabrizio; Vitorica-Yrezabal, Iñigo J; Mills, David P.
Salt metathesis versus protonolysis routes for the synthesis of silylamide Hauser base (R2NMgX; X = halogen) and amido-Grignard (R2NMgR) complexes.
Dalton transactions (Cambridge, England : 2003), 2016, 45, 6004-6014
7036096 CIFC17 H43 Mg N O2 Si2P -17.7728; 9.8848; 16.9636
87.573; 79.144; 70.342
1205.12Goodwin, Conrad A. P.; Smith, Alex; Ortu, Fabrizio; Vitorica-Yrezabal, Iñigo J; Mills, David P.
Salt metathesis versus protonolysis routes for the synthesis of silylamide Hauser base (R2NMgX; X = halogen) and amido-Grignard (R2NMgR) complexes.
Dalton transactions (Cambridge, England : 2003), 2016, 45, 6004-6014
7036097 CIFC32 H78 Mg2 N2 Si4P -18.3413; 9.1521; 14.4572
76.25; 80.293; 84.415
1054.8Goodwin, Conrad A. P.; Smith, Alex; Ortu, Fabrizio; Vitorica-Yrezabal, Iñigo J; Mills, David P.
Salt metathesis versus protonolysis routes for the synthesis of silylamide Hauser base (R2NMgX; X = halogen) and amido-Grignard (R2NMgR) complexes.
Dalton transactions (Cambridge, England : 2003), 2016, 45, 6004-6014
7036098 CIFC38 H90 Mg2 N2 Si4P -19.0592; 10.5786; 14.0661
104.507; 94.56; 114.542
1161.1Goodwin, Conrad A. P.; Smith, Alex; Ortu, Fabrizio; Vitorica-Yrezabal, Iñigo J; Mills, David P.
Salt metathesis versus protonolysis routes for the synthesis of silylamide Hauser base (R2NMgX; X = halogen) and amido-Grignard (R2NMgR) complexes.
Dalton transactions (Cambridge, England : 2003), 2016, 45, 6004-6014
7036099 CIFC32 H76 I2 Mg2 N2 O2 Si4C 1 2/c 131.4565; 10.5855; 14.2235
90; 105.608; 90
4561.5Goodwin, Conrad A. P.; Smith, Alex; Ortu, Fabrizio; Vitorica-Yrezabal, Iñigo J; Mills, David P.
Salt metathesis versus protonolysis routes for the synthesis of silylamide Hauser base (R2NMgX; X = halogen) and amido-Grignard (R2NMgR) complexes.
Dalton transactions (Cambridge, England : 2003), 2016, 45, 6004-6014
7036100 CIFC42 H94 Mg2 N2 Si4C 1 2/c 125.268; 16.935; 13.2403
90; 117.029; 90
5046.9Goodwin, Conrad A. P.; Smith, Alex; Ortu, Fabrizio; Vitorica-Yrezabal, Iñigo J; Mills, David P.
Salt metathesis versus protonolysis routes for the synthesis of silylamide Hauser base (R2NMgX; X = halogen) and amido-Grignard (R2NMgR) complexes.
Dalton transactions (Cambridge, England : 2003), 2016, 45, 6004-6014
7036133 CIFC18 H60 As2 Ce2 N12 S8C 1 2/c 138.818; 12.013; 20.7022
90; 121.797; 90
8205Zhao, Rong-Qing; Liu, Xing; Zhou, Jian; Xiao, Hong-Ping; Zou, Hua-Hong; Fu, Lianshe; Tang, Qiuling; Tan, Xiao-Feng
The first examples of 1-D organic hybrid lanthanoid thioarsenates based on two [As(V)S4](3-) linkage modes.
Dalton transactions (Cambridge, England : 2003), 2016, 45, 6015-6022
7036134 CIFC18 H60 As2 N12 Pr2 S8C 1 2/c 138.7385; 11.9989; 20.67
90; 121.749; 90
8170.12Zhao, Rong-Qing; Liu, Xing; Zhou, Jian; Xiao, Hong-Ping; Zou, Hua-Hong; Fu, Lianshe; Tang, Qiuling; Tan, Xiao-Feng
The first examples of 1-D organic hybrid lanthanoid thioarsenates based on two [As(V)S4](3-) linkage modes.
Dalton transactions (Cambridge, England : 2003), 2016, 45, 6015-6022
7036135 CIFC18 H60 As2 N12 Nd2 S8C 1 2/c 138.7276; 11.9905; 20.6659
90; 121.798; 90
8156.2Zhao, Rong-Qing; Liu, Xing; Zhou, Jian; Xiao, Hong-Ping; Zou, Hua-Hong; Fu, Lianshe; Tang, Qiuling; Tan, Xiao-Feng
The first examples of 1-D organic hybrid lanthanoid thioarsenates based on two [As(V)S4](3-) linkage modes.
Dalton transactions (Cambridge, England : 2003), 2016, 45, 6015-6022
7036136 CIFC18 H60 As2 N12 S8 Sm2C 1 2/c 138.7381; 11.9872; 20.5952
90; 121.791; 90
8128.8Zhao, Rong-Qing; Liu, Xing; Zhou, Jian; Xiao, Hong-Ping; Zou, Hua-Hong; Fu, Lianshe; Tang, Qiuling; Tan, Xiao-Feng
The first examples of 1-D organic hybrid lanthanoid thioarsenates based on two [As(V)S4](3-) linkage modes.
Dalton transactions (Cambridge, England : 2003), 2016, 45, 6015-6022

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